Eco-Friendly Lead-Free Metal Halide Perovskites: Progress and Prospects in Multifunctional Applications
Journal of Alloys and Compounds,
Journal Year:
2025,
Volume and Issue:
unknown, P. 180365 - 180365
Published: April 1, 2025
Language: Английский
Organic–Inorganic Hybrid Halide X-ray Scintillator with High Antiwater Stability
Yuyin Wang,
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Ying Feng,
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Xiaotong Liu
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et al.
Inorganic Chemistry,
Journal Year:
2024,
Volume and Issue:
63(35), P. 16224 - 16232
Published: Aug. 16, 2024
In
recent
years,
low-dimensional
organic–inorganic
hybrid
metal
halides
have
garnered
significant
attention
for
optoelectronic
applications
due
to
their
exceptional
photophysical
properties,
despite
persistent
challenge
of
low
stability.
Addressing
this
challenge,
our
study
introduces
1-[5-(trifluoromethyl)pyridin-2-yl]piperazinium
(TFPP)
as
a
cation,
harvesting
novel
one-dimensional
cadmium-based
halide
semiconductor
(TFPP)CdCl4,
which
exhibits
intense
blue-light
emission
upon
UV
excitation.
Additionally,
(TFPP)CdCl4
demonstrates
high
scintillation
performance
under
X-ray
excitation,
producing
16600
±
500
photons
MeV–1
and
achieving
detection
limit
0.891
μGyair
s–1.
Notably,
showcases
remarkable
stability
against
water,
light
sources,
heating,
corrosive
environments,
positioning
it
promising
candidate
applications.
Through
blend
experimental
techniques
theoretical
analyses,
including
density
functional
theory
calculations,
we
elucidate
the
unique
properties
structural
(TFPP)CdCl4.
These
findings
significantly
contribute
understanding
semiconductors,
offering
valuable
insights
into
potential
application
in
advanced
devices
paving
way
further
research
field.
Language: Английский
Unique Optoelectronic Properties and Applications of Lead‐Free Perovskites and Derivatives
Advanced Photonics Research,
Journal Year:
2024,
Volume and Issue:
unknown
Published: July 10, 2024
The
pursuit
of
lead‐free
alternatives
to
lead
halide
perovskites
has
gained
significant
momentum
due
the
environmental
concerns
associated
with
toxicity.
adverse
effects
on
human
health
and
environment
have
prompted
a
shift
toward
developing
sustainable
eco‐friendly
perovskite
materials
for
various
optoelectronic
devices.
This
is
particularly
vital
in
emerging
technologies
where
play
crucial
role,
such
as
solar
cells,
X‐ray
detectors,
photodetectors,
light‐emitting
diodes
(LEDs),
etc.
Consequently,
it
paramount
understand
fundamental
properties,
synthesis
methods,
structural
characteristics
perovskites.
review
aims
provide
comprehensive
analysis
intricate
relationship
between
structures
properties
perovskites,
shedding
light
their
applications
across
diverse
fields.
focus
environmentally
benign,
high‐performing,
underscores
urgency
significance
research
efforts
driving
development
efficient
technologies.
Language: Английский