Hydrates of N-((10-Chloroanthracen-9-yl)methyl)-3-(1H-imidazol-1-yl)propan-1-ammonium Cobalt(II), Copper(II), and Zinc(II) 2,6-Pyridinedicarboxylate: Reversible Crystallization DOI Creative Commons
Abhay Pratap Singh, J.B. Baruah

ACS Omega, Journal Year: 2024, Volume and Issue: 9(48), P. 47848 - 47856

Published: Nov. 19, 2024

In a quest to explore interconvertible assemblies of hydrates cobalt(II), copper(II), and zinc(II) 2,6-pyridinedicarboxylate (26-pdc), complexes having cation chloro-substituted analogue N-{(10-chloroanthracen-9-yl)methyl}-3-(1H-imidazol-1-yl)propan-1-amine were investigated. the case cobalt copper complexes, crystallized stable hydrate less methanol guided by concentration-dependent crystallizations. The unit-cells crystals two each belong P1̅ space group but have different stoichiometries as well large differences in packing. These could be reversibly predictable manner. unit-cell volumes complex four-times smaller than that respective form (C2/c group), whereas similar had two-times volume form. cations forms assembled together formed zigzag ladder-like chains. spaces present between chains filled with clusters face stacked anions. transformation required bottom-up building process starting from hydrates. Fluorescence spectroscopic studies showed possibility zinc-complex solution, crystallization yielded only

Language: Английский

Fluorescent sensor based on an anthracene functionalized pillar[5]arene for efficient detection of Vc in real sample and cell DOI

Wen-Li Guan,

Qing‐Ling Su,

Yue Hu

et al.

Journal of Molecular Structure, Journal Year: 2025, Volume and Issue: unknown, P. 141614 - 141614

Published: Feb. 1, 2025

Language: Английский

Citations

0
A novel salicylaldehyde Schiff-base-functionalized 1,8-naphthalimide luminophore with controllable aggregation/solid/film fluorescence and reversible acid/base stimuli-responsive film fluorescence DOI

Mingguang Zhu,

Jinghui Zeng, Xinyu Ye

et al.

Journal of Molecular Structure, Journal Year: 2025, Volume and Issue: unknown, P. 141888 - 141888

Published: Feb. 1, 2025

Language: Английский

Citations

0
Hydrates of N-((10-Chloroanthracen-9-yl)methyl)-3-(1H-imidazol-1-yl)propan-1-ammonium Cobalt(II), Copper(II), and Zinc(II) 2,6-Pyridinedicarboxylate: Reversible Crystallization DOI Creative Commons
Abhay Pratap Singh, J.B. Baruah

ACS Omega, Journal Year: 2024, Volume and Issue: 9(48), P. 47848 - 47856

Published: Nov. 19, 2024

In a quest to explore interconvertible assemblies of hydrates cobalt(II), copper(II), and zinc(II) 2,6-pyridinedicarboxylate (26-pdc), complexes having cation chloro-substituted analogue N-{(10-chloroanthracen-9-yl)methyl}-3-(1H-imidazol-1-yl)propan-1-amine were investigated. the case cobalt copper complexes, crystallized stable hydrate less methanol guided by concentration-dependent crystallizations. The unit-cells crystals two each belong P1̅ space group but have different stoichiometries as well large differences in packing. These could be reversibly predictable manner. unit-cell volumes complex four-times smaller than that respective form (C2/c group), whereas similar had two-times volume form. cations forms assembled together formed zigzag ladder-like chains. spaces present between chains filled with clusters face stacked anions. transformation required bottom-up building process starting from hydrates. Fluorescence spectroscopic studies showed possibility zinc-complex solution, crystallization yielded only

Language: Английский

Citations

0