Highly Efficient and Thermally Stable NIR‐Emitting Phosphor with Largely Tunable Peak Wavelength and Bandwidth Toward NIR Spectroscopy Applications
Laser & Photonics Review,
Journal Year:
2025,
Volume and Issue:
unknown
Published: Feb. 21, 2025
Abstract
Developing
tunable
broadband
near‐infrared
(NIR)
fluorescent
materials
with
outstanding
luminescence
properties
and
superior
thermal
robustness
remains
a
significant
challenge
for
next‐generation
intelligent
NIR
light
sources.
Herein,
high‐performance
large‐scale
NIR‐emitting
garnet‐type
phosphor,
SrLu
2
Al
3
ScSiO
12
:Cr
3+
(SLASSO:Cr
),
is
presented.
Upon
450
nm
blue
excitation,
SLASSO:1%Cr
phosphor
yields
emission
full
width
at
half
maximum
of
108
prominent
sharp
peak
694
superimposed
on
radiation,
which
attributed
to
the
co‐occupation
Cr
ions
dominant
[AlO
6
]
octahedral
site
(Cr1
site)
subordinate
[ScO
(Cr2
site).
Remarkably,
as
⁺
content
increases,
red‐shift
in
wavelength
spanning
from
785
bandwidth
broadening
89
152
are
observed,
stems
weakening
crystal
field
strength
energy
redistribution
within
Cr1
Cr2
centers
regulated
by
formation
local
‐Cr
ion
pairs.
Notably,
optimal
sample
boasts
an
excellent
internal
quantum
efficiency
89.4%
exceptional
stability
(97.6%@423
K).
Additionally,
fabricated
phosphor‐converted
light‐emitting
diode
devices
demonstrate
promising
multi‐functional
applications,
including
plant
cultivation,
night
vision,
bioimaging
non‐destructive
detection.
Language: Английский
Lattice constraint induced Cr4+ selective substitution for broadband NIR-Ⅱ emitting in composition detection application
Yang Xu,
No information about this author
Bin Sun,
No information about this author
Meng Zhang
No information about this author
et al.
Ceramics International,
Journal Year:
2025,
Volume and Issue:
unknown
Published: Feb. 1, 2025
Language: Английский
NIR laser irradiation of Er0.5Yb2.5Al5O12 single crystal: photoluminescence from ultraviolet to NIR-II
Wenxia Wu,
No information about this author
Yan Hao,
No information about this author
Zhaoyue Wang
No information about this author
et al.
CrystEngComm,
Journal Year:
2025,
Volume and Issue:
unknown
Published: Jan. 1, 2025
Under
excitation
at
980
nm,
Er
3+
and
Yb
co-doped
into
a
single
crystal
may
emit
light
from
ultraviolet
to
NIR-II,
fulfilling
the
application
requirements
for
solid-state
lasers
covering
wide
wavelength
range.
Language: Английский