The Journal of Organic Chemistry,
Journal Year:
2021,
Volume and Issue:
86(3), P. 2117 - 2134
Published: Jan. 19, 2021
It
has
been
found
that
the
final
products
of
reaction
sulfonyl
chlorides
and
tertiary
amines
in
presence
cadmium
sulfide
nanoparticles
under
visible
light
irradiation
are
highly
dependent
on
applied
conditions.
Interestingly,
with
change
a
condition,
different
pathways
were
conducted
(visible-light-induced
N-dealkylation
or
sp3
sp2
C–H
activation)
lead
to
such
as
secondary
various
compounds.
Remarkably,
all
these
reactions
performed
an
air
atmosphere
without
any
additive
oxidant
benign
solvents
solvent-free
During
this
study,
CdS
affordable,
heterogeneous,
recyclable
photocatalysts
designed,
successfully
synthesized,
fully
characterized
for
protocols.
studies,
intermediates
resulting
from
oxidation
trapped
during
photoinduced
electron
transfer
(PET)
process.
The
was
carried
out
efficiently
variety
substrates
give
corresponding
at
relatively
short
times
good
excellent
yields
parallel
use
renewable
energy
source.
Most
processes
novel
superior
terms
cost-effectiveness,
safety,
simplicity
published
reports.
RSC Advances,
Journal Year:
2021,
Volume and Issue:
11(16), P. 9130 - 9221
Published: Jan. 1, 2021
This
review
provides
a
unique
and
comprehensive
overview
of
sodium
sulfinates
for
synthesizing
many
valuable
sulfur-containing
compounds,
such
as
thiosulfonates,
sulfonamides,
sulfides,
sulfones,
allyl
vinyl
sulfones
β-keto
sulfones.
Green Chemistry,
Journal Year:
2023,
Volume and Issue:
25(10), P. 4122 - 4128
Published: Jan. 1, 2023
A
visible
light-initiated
manganese-catalyzed
radical
hydrosulfonylation
of
a
wide
range
structurally
diverse
alkenes
using
commercially
available
and
relatively
cheap
sulfonyl
chlorides
as
sources
is
described.
RSC Advances,
Journal Year:
2024,
Volume and Issue:
14(9), P. 5817 - 5845
Published: Jan. 1, 2024
A
variety
of
bioactive
compounds
can
be
synthesized
via
C–C
and
C–X
(X
=
O/S/N/Se/Cl/Br)
bond
formation
using
an
efficient
catalytic
system
I
2
/DMSO.
This
review
highlights
the
progress
identifies
potential
paths
for
future
research
in
this
field.
Organic & Biomolecular Chemistry,
Journal Year:
2020,
Volume and Issue:
18(43), P. 8771 - 8792
Published: Jan. 1, 2020
In
organic
synthesis,
transition-metal
and
photoredox-catalysis-based
reaction
systems
are
emerging
trends
for
the
construction
of
C-S
bonds.
Many
review
articles
have
recently
appeared
in
this
field;
however,
we
present
herein
an
overview
metal-free
coupling
reactions
using
thiols
or
disulfides
as
sulfur
surrogates.
The
oxidants
considered
include
peroxides,
tert-butyl
nitrite
(TBN),
DDQ,
iodine
reagents,
molecular
oxygen.
addition,
selective
electrochemical
oxidative
transformations
also
covered
with
mechanistic
details.
Organic Letters,
Journal Year:
2022,
Volume and Issue:
24(16), P. 3014 - 3018
Published: April 14, 2022
1-Acryloyl-2-cyanoindoles
were
found
to
be
novel
and
efficient
skeletons
in
visible-light-induced
persulfate-promoted
cascade
cyclization
reactions.
With
this
transition-metal-free
photocatalytic
procedure,
various
sulfonated/thiocyanated
pyrrolo[1,2-a]indolediones
synthesized
from
1-acryloyl-2-cyanoindoles
with
sulfonyl
hydrazides/NH4SCN
at
room
temperature
under
mild
reaction
conditions.
ChemSusChem,
Journal Year:
2022,
Volume and Issue:
15(7)
Published: Feb. 17, 2022
Abstract
Electrosynthesis
has
recently
attracted
more
and
attention
due
to
its
great
potential
replace
chemical
oxidants
or
reductants
in
molecule‐electrode
electron
transfer.
Sulfonyl
compounds
such
as
sulfonyl
hydrazides,
sulfinic
acids
(and
their
salts),
halides
have
been
discovered
practical
precursors
of
several
radicals.
As
electrochemical
redox
reactions
can
provide
green
efficient
pathways
for
the
activation
compounds,
studies
electrosynthesis
rapidly
increased.
Several
types
radicals
be
generated
from
anodic
oxidation
cathodic
reduction
initiate
fluoroalkylation,
benzenesulfonylation,
cyclization
rearrangement.
In
this
Review,
we
summarize
developments
involving
mainly
last
decade.
Organic Chemistry Frontiers,
Journal Year:
2023,
Volume and Issue:
10(19), P. 4972 - 5027
Published: Jan. 1, 2023
This
review
comprehensively
summarizes
the
dichalcogenative
functionalization
of
unsaturated
compounds
over
past
decade.
The
scopes,
limitations
and
detailed
reaction
mechanisms
are
also
discussed.
