Recent Advances in Nonprecious Metal Catalysis DOI
Archita Sripada, Eugene Chong, Hao Wu

et al.

Organic Process Research & Development, Journal Year: 2024, Volume and Issue: 28(9), P. 3524 - 3544

Published: Aug. 9, 2024

Developing catalytic reactions using nonprecious-metal to achieve various synthetic transformations remains a valuable pursuit the scientific community. As part of continuing review series that is published within precompetitive chemistry alliance between AbbVie, Boehringer Ingelheim and Pfizer, this article underscores wide-ranging uses Cu-, Co-, Fe-, Ni-catalysis. The significant uptick in NPMC-related publications signifies escalating curiosity among researchers investigate advance capabilities these metals.

Language: Английский

High conductive and dimensional stability proton exchange membranes with an all-carbon main chain and densely sulfonated structure DOI

Jiayu Guan,

Xi Sun, Huiting Yu

et al.

Journal of Membrane Science, Journal Year: 2024, Volume and Issue: 700, P. 122664 - 122664

Published: March 26, 2024

Language: Английский

Citations

8
Ferric Nitrate as a Bifunctional Catalyst for Dehydration and Oxidative Cleavage-Esterification of Tertiary Alcohols DOI

Ruixia Sun,

Fukai Xie,

Qiang Zhang

et al.

The Journal of Organic Chemistry, Journal Year: 2025, Volume and Issue: 90(6), P. 2214 - 2229

Published: Jan. 30, 2025

The selective oxidative cleavage and functionalization of C(OH)–C bonds in tertiary alcohols harbor immense feasibility organic synthesis enable the production high value-added chemicals from renewable biomass. However, it remains a challenge, owing to inherent kinetic inertness thermodynamic stability lack Cα–H. Taking huge potential challenge bond activation into consideration, herein, we show first example an inexpensive bifunctional ferric nitrate catalyst for catalytic direct oxidation structurally distinct esters with environmentally benign molecular oxygen as oxidant MeOH solvent, without assistance any additives. Detailed mechanistic studies reveal that this tandem process is initiated by synergistic effects iron ion ion, which serve Lewis acids dehydrating nitrogen dioxide radical precursor inducing cleavage, respectively.

Language: Английский

Citations

0
Recent Advances in Nonprecious Metal Catalysis DOI
Archita Sripada, Eugene Chong, Hao Wu

et al.

Organic Process Research & Development, Journal Year: 2024, Volume and Issue: 28(9), P. 3524 - 3544

Published: Aug. 9, 2024

Developing catalytic reactions using nonprecious-metal to achieve various synthetic transformations remains a valuable pursuit the scientific community. As part of continuing review series that is published within precompetitive chemistry alliance between AbbVie, Boehringer Ingelheim and Pfizer, this article underscores wide-ranging uses Cu-, Co-, Fe-, Ni-catalysis. The significant uptick in NPMC-related publications signifies escalating curiosity among researchers investigate advance capabilities these metals.

Language: Английский

Citations

1