Effect of Substituents in Governing the Homolytic Gas-Phase P–H Bond Dissociation Enthalpies of Phosphine-type Oxides (R1R2P(=O)H) DOI
Robert J. O’Reilly, Mannix P. Balanay

Chemical Data Collections, Journal Year: 2024, Volume and Issue: unknown, P. 101164 - 101164

Published: Sept. 1, 2024

Language: Английский

Tributylphosphine Oxide as a Powerful Synergist for Kinetic Hydrate Inhibitors DOI Creative Commons
Malcolm A. Kelland, Janronel Pomicpic

Energy & Fuels, Journal Year: 2025, Volume and Issue: unknown

Published: March 21, 2025

Language: Английский

Citations

0
Exploring the Stability of Primary Phosphine Oxides: Correlations with Primary Phosphines Air‐Stability? DOI Creative Commons
Filip Horký,

Clemens Bruhn,

Rudolf Pietschnig

et al.

European Journal of Inorganic Chemistry, Journal Year: 2024, Volume and Issue: unknown

Published: Aug. 14, 2024

Abstract To better understand the stability of isolable primary phosphine oxides, new members this family were synthesized through oxidation corresponding phosphines. Specifically, previously reported air‐stable phosphines ( R )‐2‐phosphanyl‐2’‐methoxy‐1,1’‐binaphthyl, 9,10‐dihydro‐9,10‐etheno‐anthracen‐9‐yl phosphine, and 3‐phosphino‐2‐naphthol treated with hydrogen peroxide or meta ‐chloroperoxybenzoic acid to yield oxides. The compounds characterized using NMR, MS, EA, X‐ray crystallography. oxides further investigated in thermal disproportionation, studied as ligands half‐sandwich Ru(II) complexes bearing an auxiliary η 6 ‐ p ‐cymene ligand.

Language: Английский

Citations

1
Effect of Substituents in Governing the Homolytic Gas-Phase P–H Bond Dissociation Enthalpies of Phosphine-type Oxides (R1R2P(=O)H) DOI
Robert J. O’Reilly, Mannix P. Balanay

Chemical Data Collections, Journal Year: 2024, Volume and Issue: unknown, P. 101164 - 101164

Published: Sept. 1, 2024

Language: Английский

Citations

0