Synthesis and Characterizations of DOPO Substituted Polyesters DOI

Damla Cansu Sefa,

Fadime Karaer Özmen, Mustafa Erdem Üreyen

et al.

ChemistrySelect, Journal Year: 2025, Volume and Issue: 10(20)

Published: May 1, 2025

Abstract Growing environmental and health concerns regarding the use of halogenated flame retardants have led to an increased interest in phosphorus‐based alternatives, which are recognized for their environmentally friendly properties. In this study, phosphorus‐functional monomers, obtained via phospho‐Michael addition DOPO unsaturated compounds such as maleic anhydride itaconic acid, were incorporated into polyester matrices impart intrinsic retardancy through covalent integration polymeric network. The influence terephthalic acid on thermal behavior these polyesters is also explored. A range analytical techniques employed inform including 1 H 31 P NMR spectroscopy, FTIR, viscosity evaluation, inductively coupled plasma optical emission spectrometry (ICP‐OES). Thermogravimetric analysis combination with evolved gas used assess stability both nitrogen air environments. Furthermore, microscale combustion calorimetry examine flammability characteristics. For cone tests, samples applied onto glass fibers evaluate flame‐retardant efficacy, smoke generation, overall fire safety performance.

Language: Английский

Metal–Organic Framework-Based Composites for Dual Functionalities: Advances in Microwave Absorption and Flame Retardancy DOI Open Access
Jinhu Hu,

Jialin Jiang,

Qianlong Li

et al.

Journal of Composites Science, Journal Year: 2025, Volume and Issue: 9(3), P. 121 - 121

Published: March 6, 2025

With the rapid expansion of electronic information technology and rising material safety needs, creation composite materials that perform both electromagnetic microwave absorption (EMA) flame retardancy has arisen as a science research hotspot. Metal–organic frameworks (MOFs) have great potential for developing novel multifunctional due to their unique structural characteristics customizable functions. This work presents comprehensive assessment most recent findings on MOF-based EMA-flame retardant dual-functional composites. The fundamental mechanisms EMA are covered, including dielectric loss, magnetic condensed-phase gas-phase mechanisms. development composites based Fe-MOF, Co-MOF, Ni-MOF, polymetallic MOF in terms is highlighted. These offer exceptional performance strong effects thanks designs component regulations. In addition, some infrared stealth, thermal insulation, hydrophobic, mechanical qualities. Ultimately, problems possibilities reviewed, giving valuable references new materials.

Language: Английский

Citations

1
Introduction of Phosphorous to Metal-Organic Frameworks for Fire-Safe Polymers: From Synthesis to Application DOI Creative Commons

Jianwei Yuan,

Ye‐Tang Pan, Yichao Lin

et al.

Polymer science & technology., Journal Year: 2025, Volume and Issue: unknown

Published: April 9, 2025

Language: Английский

Citations

1
Electrostatic self-assembly of red phosphorus@MgAl-layered double hydroxide for improved flame retardancy in epoxy resin DOI

Yongkang Zhou,

Ting Xiang,

Lifen Xiao

et al.

Nano-Structures & Nano-Objects, Journal Year: 2025, Volume and Issue: 42, P. 101482 - 101482

Published: May 1, 2025

Language: Английский

Citations

0
Synthesis and Characterizations of DOPO Substituted Polyesters DOI

Damla Cansu Sefa,

Fadime Karaer Özmen, Mustafa Erdem Üreyen

et al.

ChemistrySelect, Journal Year: 2025, Volume and Issue: 10(20)

Published: May 1, 2025

Abstract Growing environmental and health concerns regarding the use of halogenated flame retardants have led to an increased interest in phosphorus‐based alternatives, which are recognized for their environmentally friendly properties. In this study, phosphorus‐functional monomers, obtained via phospho‐Michael addition DOPO unsaturated compounds such as maleic anhydride itaconic acid, were incorporated into polyester matrices impart intrinsic retardancy through covalent integration polymeric network. The influence terephthalic acid on thermal behavior these polyesters is also explored. A range analytical techniques employed inform including 1 H 31 P NMR spectroscopy, FTIR, viscosity evaluation, inductively coupled plasma optical emission spectrometry (ICP‐OES). Thermogravimetric analysis combination with evolved gas used assess stability both nitrogen air environments. Furthermore, microscale combustion calorimetry examine flammability characteristics. For cone tests, samples applied onto glass fibers evaluate flame‐retardant efficacy, smoke generation, overall fire safety performance.

Language: Английский

Citations

0