Functional MOF-Based Materials for Environmental and Biomedical Applications: A Critical Review DOI Creative Commons

Maria-Anna Gatou,

Ioanna-Aglaia Vagena,

Nefeli Lаgopati

et al.

Nanomaterials, Journal Year: 2023, Volume and Issue: 13(15), P. 2224 - 2224

Published: July 31, 2023

Over the last ten years, there has been a growing interest in metal–organic frameworks (MOFs), which are unique category of porous materials that combine organic and inorganic components. MOFs have garnered significant attention due to their highly favorable characteristics, such as environmentally friendly nature, enhanced surface area pore volume, hierarchical arrangements, adjustable properties, well versatile applications fields chemical engineering, science, environmental biomedical sectors. This article centers on examining advancements using for remediation purposes. Additionally, it discusses latest developments employing potential tools disease diagnosis drug delivery across various ailments, including cancer, diabetes, neurological disorders, ocular diseases. Firstly, concise overview MOF evolution synthetic techniques employed creating provided, presenting advantages limitations. Subsequently, challenges, avenues, perspectives future utilization respective application domains addressed. Lastly, comprehensive comparison presently these is conducted.

Language: Английский

Multistructured Electrospun Nanofibers for Air Filtration: A Review DOI
Tao Lu, Jiaxin Cui, Qingli Qu

et al.

ACS Applied Materials & Interfaces, Journal Year: 2021, Volume and Issue: 13(20), P. 23293 - 23313

Published: May 11, 2021

Air filtration materials (AFMs) have gradually become a research hotspot on account of the increasing attention paid to global air quality problem. However, most AFMs cannot balance contradiction between high efficiency and low pressure drop. Electrospinning nanofibers large surface area volume ratio, an adjustable porous structure, simple preparation process that make them appropriate candidate for materials. Therefore, electrospun attracted increased in applications. In this paper, first, methods high-performance membranes (EAFMs) typical structures principles fibers are reviewed. Second, progress EAFMs with multistructures, including nanoprotrusion, wrinkled, porous, branched, hollow, core–shell, ribbon, beaded, nets application these summarized. Finally, challenges fabrication EAFMs, limitations their use, trends future developments presented.

Language: Английский

Citations

351

Electrospinning of Metal–Organic Frameworks for Energy and Environmental Applications DOI Creative Commons
Yibo Dou, Wenjing Zhang, Andreas Kaiser

et al.

Advanced Science, Journal Year: 2019, Volume and Issue: 7(3)

Published: Dec. 11, 2019

Abstract Herein, recent developments of metal–organic frameworks (MOFs) structured into nanofibers by electrospinning are summarized, including the fabrication, post‐treatment via pyrolysis, properties, and use resulting MOF nanofiber architectures. The fabrication architectures described systematically two routes: i) direct MOF‐polymer composites, ii) surface decoration structures with MOFs. unique properties performance different types their derivatives explained in respect to energy environmental applications, air filtration, water treatment, gas storage separation, electrochemical conversion storage, heterogeneous catalysis. Finally, challenges nanofibers, limitations for use, trends future presented.

Language: Английский

Citations

289

Cellulose–metal organic frameworks (CelloMOFs) hybrid materials and their multifaceted Applications: A review DOI Creative Commons
Hani Nasser Abdelhamid, Aji P. Mathew

Coordination Chemistry Reviews, Journal Year: 2021, Volume and Issue: 451, P. 214263 - 214263

Published: Oct. 22, 2021

Cellulose–MOFs (CelloMOFs) are attractive hybrid materials that make available a range of hitherto unattainable properties by conjugating cellulosic with metal–organic frameworks (MOFs). CelloMOFs have demonstrated great potential to be applied in several fields such as water remediation, air purification, gas storage, sensing/biosensing, and biomedicine. can act an efficient adsorbent remove emerging contaminants metals, dyes, drugs, antibiotics, pesticides, oils via adsorption. They also used catalysts for catalytic degradation, reduction, oxidation organic pollutants. been filters purification removing greenhouse gases carbon dioxide (CO2), volatile compounds (VOCs), particulate matter (PMs). Biomedical applications antibacterial, drug delivery, biosensing were reported materials. This review summarized the synthesis, characterization, cellulose-MOFs It covered broad overview status combination cellulose micron nanoscale MOFs. At end review, challenges outlook regarding discussed. Hopefully, this will useful guide researchers scientists who looking quick access relevant references about their applications.

Language: Английский

Citations

271

Electrospinning of nanofibres DOI
Dongxiao Ji,

Yagai Lin,

Xinyue Guo

et al.

Nature Reviews Methods Primers, Journal Year: 2024, Volume and Issue: 4(1)

Published: Jan. 4, 2024

Language: Английский

Citations

216

Wide Voltage Aqueous Asymmetric Supercapacitors: Advances, Strategies, and Challenges DOI
Jun Huang, Kai Yuan, Yiwang Chen

et al.

Advanced Functional Materials, Journal Year: 2021, Volume and Issue: 32(4)

Published: Oct. 10, 2021

Abstract Asymmetric supercapacitors (ASCs) can substantially broaden their working voltage range, benefiting from the advantages of both cathode and anode while breaking through energy storage limitations corresponding symmetric cells. Wide aqueous ASCs hold great promise for future electronic systems that require satisfied density, power cycle life, due to electrolyte in terms low cost, operational safety, facile manufacture, environment‐friendly, high ionic conductivity. This review will first briefly present an overview historical developments, charge mechanisms, matching principles wide ASCs. Then, materials with potential windows building over last few decades are summarized. The next section details optimization methods related In addition, basic device configurations classified discussed. Furthermore, several strategies proposed achieving high‐performance window, specific capacitance, rate performance, electrochemical stability. Finally, motivate further research development, key scientific challenges perspectives

Language: Английский

Citations

207

Electrospun nanofibers promote wound healing: theories, techniques, and perspectives DOI
Chen Gao, Liyuan Zhang, Juan Wang

et al.

Journal of Materials Chemistry B, Journal Year: 2021, Volume and Issue: 9(14), P. 3106 - 3130

Published: Jan. 1, 2021

We provides a review on how electrospun nanofiber scaffolds promote wound healing and the technology has been used for fabricating multi-functional that have greatly promoted development of dressings.

Language: Английский

Citations

169

Macroscopic MOF Architectures: Effective Strategies for Practical Application in Water Treatment DOI

Yiyuan Yao,

Chaohai Wang, Jongbeom Na

et al.

Small, Journal Year: 2021, Volume and Issue: 18(8)

Published: Oct. 29, 2021

Metal-organic frameworks (MOFs) have potential applications in removing pollutants such as heavy metals, oils, and toxins from water. However, due to the intrinsic fragility of MOFs their fine powder form, there are still technical barriers practical application blockage pipes, difficulty recovery, environmental toxicity. Therefore, attention has focused on approaches convert nanocrystalline into macroscopic materials overcome these limitations. Recently, strategies for shaping beads (0D), nanofibers (1D), membranes (2D), gels/sponges (3D) with macrostructures developed including direct mixing, situ growth, or deposition polymers, cotton, foams other porous substrates. In this review, successful fabrication water adsorption, separation, advanced oxidation processes, discussed. The relationship between performance microstructure materials, how range 0D 3D can be used treatment also outlined.

Language: Английский

Citations

160

Metal‐Organic Frameworks and Electrospinning: A Happy Marriage for Wastewater Treatment DOI
Farhad Ahmadijokani, Hossein Molavi,

Addie Bahi

et al.

Advanced Functional Materials, Journal Year: 2022, Volume and Issue: 32(51)

Published: Oct. 21, 2022

Abstract Metal‐organic frameworks (MOFs), an emerging class of porous organic‐inorganic hybrid materials, have shown great potential for water and wastewater treatment applications. However, pure MOF powders limited practical applications in due to their insolubility, poor processability, brittleness, safety hazard from dust formation, difficult separation aqueous solutions. Thus, exploring MOFs composites with improved performance is importance. The marriage electrospun nanofiber forethought into the final product's morphology, structure, chemistry has opened up new opportunities efficient treatment. present review exhaustively summarizes strategies integrate nanofibers via electrospinning remove various pollutants (i.e., organic dyes, heavy metal ions, pharmaceuticals, personal care products, oily compounds, solvents, etc.) adsorption, photodegradation, membrane filtration. Besides, most recent advances current challenges future outlook are delineated.

Language: Английский

Citations

142

Asymmetric catalysis using metal-organic frameworks DOI
Danil N. Dybtsev, Konstantin P. Bryliakov

Coordination Chemistry Reviews, Journal Year: 2021, Volume and Issue: 437, P. 213845 - 213845

Published: March 9, 2021

Language: Английский

Citations

115

Enrofloxacin degradation in a heterogeneous electro-Fenton system using a tri-metal-carbon nanofibers composite cathode DOI
Xian Li, Chun Xiao, Xian Ruan

et al.

Chemical Engineering Journal, Journal Year: 2021, Volume and Issue: 427, P. 130927 - 130927

Published: June 20, 2021

Language: Английский

Citations

113