Layer-Structured Multitransition-Metal Oxide Cathode Materials for Potassium-Ion Batteries with Long Cycling Lifespan and Superior Rate Capability DOI
Shuaishuai Wang,

Zhao-Meng Liu,

Xuan‐Wen Gao

et al.

ACS Applied Materials & Interfaces, Journal Year: 2023, Volume and Issue: unknown

Published: Nov. 29, 2023

Manganese (Mn)-based layer-structured transition metal oxides are considered as excellent cathode materials for potassium ion batteries (KIBs) owing to their low theoretical cost and high voltage plateau. The energy density cycling lifetime, however, cannot simultaneously satisfy the basic requirements of market storage systems. One primary causes results from complex structural transformation migration during intercalation deintercalation process. orbital electronic structure octahedral center element plays an important role maintaining integrity improving K+ diffusivity by introduced heterogeneous [Me-O] chemical bonding. A multitransition oxide, P3-type K0.5Mn0.85Co0.05Fe0.05Al0.05O2 (KMCFAO), was synthesized employed a material KIBs. Beneficial larger layer spacing better accommodate effectively preventing irreversible in insertion/extraction process, it can reach superior capacity retention up 96.8% after 300 cycles at current 500 mA g-1. full cell KMCFAO//hard carbon exhibits encouraging promising 113.8 W h kg-1 100 g-1 72.6% cycles.

Language: Английский

Recent Advances in Sodium-Ion Batteries: Cathode Materials DOI Open Access
Thang Phan Nguyen, Il Tae Kim

Materials, Journal Year: 2023, Volume and Issue: 16(21), P. 6869 - 6869

Published: Oct. 26, 2023

Emerging energy storage systems have received significant attention along with the development of renewable energy, thereby creating a green platform for humans. Lithium-ion batteries (LIBs) are commonly used, such as in smartphones, tablets, earphones, and electric vehicles. However, lithium has certain limitations including safety, cost-effectiveness, environmental issues. Sodium is believed to be an ideal replacement owing its infinite abundance, low cost, friendliness, behavior similar that lithium. Inhered achievement LIBs, sodium-ion (SIBs) rapidly evolved commercialized. Among cathode, anode, electrolyte, cathode remains challenge achieving stable, high-rate, high-capacity device. In this review, recent advances optimization materials, inorganic, organometallic, organic discussed SIBs. addition, challenges strategies enhancing stability performance SIBs highlighted.

Language: Английский

Citations

27
Challenges and Progress in Rechargeable Magnesium‐Ion Batteries: Materials, Interfaces, and Devices DOI

Dong Wang,

Zhenyu Zhang,

Yue Hao

et al.

Advanced Functional Materials, Journal Year: 2024, Volume and Issue: unknown

Published: Sept. 17, 2024

Abstract Rechargeable magnesium‐ion batteries (RMBs) have garnered increasing research interest in the field of post‐lithium‐ion battery technologies owing to their potential for high energy density, enhanced safety, cost‐effectiveness, and material resourcefulness. Despite substantial advancements RMB research, a number intrinsic challenges remain unresolved, such as strong Coulombic interaction between Mg 2+ host crystal structure cathode materials, sluggish diffusion kinetic, poor electrolyte compatibility, formation passivation films on anode interface. These issues hinder commercial applications RMBs. This review provides comprehensive overview progress key areas including representative storage cathode/anode materials conducting electrolytes. Additionally, recent developments electrode‐electrolyte interface regulations pouch‐cell fabrication are outlined, highlighting current implementation effective solutions. Finally, future directions proposed guide development high‐performance RMBs with practical applications.

Language: Английский

Citations

13
Exploring nature-behaviour relationship of carbon black materials for potassium-ion battery electrodes DOI Open Access

Sabrina Trano,

Daniele Versaci, Micaela Castellino

et al.

Energy Materials, Journal Year: 2024, Volume and Issue: 4(1)

Published: Jan. 11, 2024

An essential component of a working electrode is the conductive additive: whether it used in very low amounts or constitutes matrix, its electrochemical response not negligible. Commercially diffused carbon black species (i.e., Super P, C65, and C45) still lack an in-depth characterisation emerging field potassium-ion battery systems, which are on way towards large-scale stationary storage application. Thus, this work aims to provide strong tools discriminate their active role such secondary cells. First, effect pseudo-amorphous structure mechanism potassium ions, tend mainly adsorb surface rather than intercalate within graphene layers, leading pseudocapacitive response, discussed. Then, Dunn’s Trasatti’s methods considered identify potential ranges surface-dominated reactions occur, quantifying weight at same time. This observation surely linked with properties exposed functional groups; thus, X-ray photoelectron spectroscopy exploited correlate features both pristine cycled surfaces species.

Language: Английский

Citations

11
High-Voltage Na0.76Ni0.25–x/2Mgx/2Mn0.75O2–xFx Cathode Improved by One-Step In Situ MgF2 Doping with Superior Low-Temperature Performance and Extra-Stable Air Stability DOI
S He, Xing Shen, Han Miao

et al.

ACS Nano, Journal Year: 2024, Volume and Issue: 18(17), P. 11375 - 11388

Published: April 17, 2024

P2-NaxMnO2 has garnered significant attention due to its favorable Na+ conductivity and structural stability for large-scale energy storage fields. However, achieving a balance between high density extended cycling remains challenge the Jahn–Teller distortion of Mn3+ anionic activity above 4.1 V. Herein, we propose one-step in situ MgF2 strategy synthesize P2-Na0.76Ni0.225Mg0.025Mn0.75O1.95F0.05 cathode with improved Na-storage performance decent water/air stability. By partially substituting cost-effective Mg Ni incorporating extra F O, optimized material demonstrates both enhanced capacity structure via promoting Ni2+/Ni4+ oxygen redox activity. It delivers 132.9 mA h g–1 an elevated working potential ≈3.48 V maintains ≈83.0% retention after 150 cycles at 100 within 2–4.3 V, compared 114.9 3.32 discharging undoped Na0.76Ni0.25Mn0.75O2. While increasing charging voltage 4.5 133.1 3.55 (vs Na/Na+) were achieved 72.8% cycles, far beyond that pristine sample (123.7 g–1, 3.45 43.8%@100 cycles). Moreover, exceptional low-temperature is achieved, 95.0% cycles. Finally, mechanism samples employing various doping strategies was investigated using EIS, XRD, ex XPS techniques.

Language: Английский

Citations

9
Preparation and electrochemical performance of Na0.67Mn0.67Fe0.2Co0.1Cu0.03O2 cathode material for sodium-ion batteries DOI
Wen Fengchun, Juan Liao,

Lan Jiayi

et al.

Chemical Engineering Journal, Journal Year: 2025, Volume and Issue: 509, P. 161239 - 161239

Published: March 4, 2025

Language: Английский

Citations

1
Entropy-Stabilized Layered K0.6Ni0.05Fe0.05Mg0.05Ti0.05Mn0.725O2 as a High-Rate and Stable Cathode for Potassium-Ion Batteries DOI
Yuqing Cai, Wenjing Liu,

Fangfei Chang

et al.

ACS Applied Materials & Interfaces, Journal Year: 2023, Volume and Issue: 15(41), P. 48277 - 48286

Published: Oct. 6, 2023

Mn-based layered oxides have been considered the most promising cathode candidates for cost-effective potassium-ion batteries (PIBs). Herein, equiatomic constituents of Ni, Fe, Mg, and Ti introduced into transition metal layers oxide to design a high-entropy K0.6Ni0.05Fe0.05Mg0.05Ti0.05Mn0.0725O2 (HE-KMO, S = 1.17R). Consequently, experimental results manifest that structure HE-KMO is more stable than conventional low-entropy K0.6MnO2 (LE-KMO, 0.66R) during successive cycling even upon exposure moisture. Diffraction electrochemical measurements reveal undergoes solid-solution mechanism, contrary multistage phase processes typically exemplified in K0.6MnO2. Benefiting from stabilized framework K+ storage entropy-stabilized not only demonstrates exceptional rate capability but also shows excellent cyclic stability. Notably, capacity retention ratio 86% after 3000 cycles can still be sustained at remarkable current density 5000 mA g-1.

Language: Английский

Citations

23
Carbon anode from carbon dots-regulated polypyrrole for enhanced potassium storage DOI Open Access
Lin Li,

Deliang Cheng,

Guoqiang Zou

et al.

Journal of Alloys and Compounds, Journal Year: 2023, Volume and Issue: 958, P. 170481 - 170481

Published: May 8, 2023

Language: Английский

Citations

18
Stable cathode material enabled by Mg2+ intercalation layered potassium vanadate for high rate and long life potassium ion batteries DOI
Haoxiang Lin, Yuanji Wu, Hongyan Li

et al.

Applied Surface Science, Journal Year: 2023, Volume and Issue: 633, P. 157603 - 157603

Published: May 29, 2023

Language: Английский

Citations

16
Co-doped P3 type K0.5Mn1-xCoxO2 (x≤0.5) cathodes for long cycle life potassium ion battery DOI

Shujie Yang,

Xin Min,

Bozhi Yang

et al.

Journal of Physics and Chemistry of Solids, Journal Year: 2024, Volume and Issue: 188, P. 111924 - 111924

Published: Feb. 8, 2024

Language: Английский

Citations

5
Review on Cathode Materials for Sodium‐ and Potassium‐Ion Batteries: Structural Design with Electrochemical Properties DOI
Hyunyoung Park, Yongseok Lee, Wonseok Ko

et al.

Batteries & Supercaps, Journal Year: 2022, Volume and Issue: 6(3)

Published: Dec. 15, 2022

Abstract As a promising candidates for next‐generation secondary battery system, sodium‐ion (Na‐ion) batteries and potassium‐ion (K‐ion) are recently attracting considerable attention because of their cost‐effectiveness similar reaction mechanism to that lithium‐ion batteries. However, the major challenges practical application sluggish ionic kinetic with excessive volume change cathode material, caused by larger radius than Li + ion. The current demand high energy density is not satisfactory electrochemical properties materials Na‐ion K‐ion studied so far, but extensive studies have been conducted achieve large reversible capacity, power long life in recent years. This review provides comprehensive information on material reported date batteries, particular focus various strategies each properties. In this regard, diverse compared Li‐ion systems, future research directions discussed along related prospects.

Language: Английский

Citations

20