Recent Advances in the Lithium Recovery from Water Resources: From Passive to Electrochemical Methods

Advanced Science, Journal Year: 2022, Volume and Issue: 9(27)

Published: July 27, 2022

The ever-increasing amount of batteries used in today's society has led to an increase the demand lithium last few decades. While mining resources this element have been steadily exploited and are rapidly depleting, water constitute interesting reservoir just out reach current technologies. Several techniques being explored novel materials engineered. evaporation is very time-consuming large footprints, ion sieves supramolecular systems can be suitably tailored even integrated into membrane electrochemical techniques. This review gives a comprehensive overview available solutions recover from both by passive electrically enhanced Accordingly, work aims provide single document rational comparison outstanding strategies remove aqueous sources. To end, practical figures merit main groups provided. An absence common experimental protocol resulting variability data methods identified. need for shared methodology agreement report performance metrics underlined.

Language: Английский

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Adsorbents for lithium extraction from salt lake brine with high magnesium/lithium ratio: From structure-performance relationship to industrial applications

Desalination, Journal Year: 2024, Volume and Issue: 579, P. 117480 - 117480

Published: Feb. 27, 2024

Language: Английский

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Doping engineering of lithium-aluminum layered double hydroxides for high-efficiency lithium extraction from salt lake brines

Nano Research, Journal Year: 2023, Volume and Issue: 17(3), P. 1646 - 1654

Published: Aug. 19, 2023

Language: Английский

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The recovery and separation of lithium by using solvent extraction methods

Coordination Chemistry Reviews, Journal Year: 2024, Volume and Issue: 509, P. 215727 - 215727

Published: March 23, 2024

Language: Английский

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Uranium and lithium extraction from seawater: challenges and opportunities for a sustainable energy future

Journal of Materials Chemistry A, Journal Year: 2023, Volume and Issue: 11(42), P. 22551 - 22589

Published: Jan. 1, 2023

Our analysis of the current literature shows that advances in extractive technologies for U/Li recovery lie at intersection between molecular simulation, nanotechnology and materials science, electrochemistry, membrane engineering.

Language: Английский

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Reduced Lattice Constant in Al‐Doped LiMn₂O₄ Nanoparticles for Boosted Electrochemical Lithium Extraction

Advanced Materials, Journal Year: 2024, Volume and Issue: 36(14)

Published: Jan. 9, 2024

Extracting lithium selectively and efficiently from brine sources is crucial for addressing energy environmental challenges. The electrochemical system employing LiMn

Language: Английский

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Material Design Strategies for Recovery of Critical Resources from Water

Advanced Materials, Journal Year: 2023, Volume and Issue: 35(36)

Published: March 31, 2023

Abstract Population growth, urbanization, and decarbonization efforts are collectively straining the supply of limited resources that necessary to produce batteries, electronics, chemicals, fertilizers, other important products. Securing chains these critical via development separation technologies for their recovery represents a major global challenge ensure stability security. Surface water, groundwater, wastewater emerging as potential new sources bolster chains. Recently, variety material‐based have been developed employed separations resource in water. Judicious selection design materials tune properties targeting specific solutes is central realizing water source resources. Here, membranes, sorbents, catalysts, electrodes, interfacial solar steam generators demonstrate promise applications reviewed. In addition, perspective offered on grand challenges key research directions need be addressed improve practical viability.

Language: Английский

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Adsorption-type aluminium-based direct lithium extraction: The effect of heat, salinity and lithium content

Desalination, Journal Year: 2024, Volume and Issue: 577, P. 117406 - 117406

Published: Feb. 2, 2024

Conventional lithium production through solar evaporation is considered a time-consuming procedure, taking substantial 12 to 18 months with significant environmental impacts such as aquifer depletion and damaging the basin's complex hydrological system. Direct Lithium Extraction (DLE) has emerged promising alternative for extraction from brines, offering reduced impact. Although adsorption-type DLE aluminium-based adsorbents sole commercial technology of DLE, debate persists concerning its Technology Readiness Level (TRL), which challenges prevailing notion that undeniably reaches TRL 9. Within this narrative, we propose adsorption capable attaining highest potential in recovery brines when three critical conditions are met: presence certain level salinity, minimum content brine, heat source up brine. In account, an attempt been made elucidate role these criteria during DLE.

Language: Английский

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Recent Advances in High‐Rate Solar‐Driven Interfacial Evaporation

Advanced Science, Journal Year: 2024, Volume and Issue: 11(26)

Published: May 5, 2024

Abstract Recent advances in solar‐driven interfacial evaporation (SDIE) have led to high rates that open promising avenues for practical utilization freshwater production and industrial application pollutant nutrient concentration, resource recovery. Breakthroughs overcoming the theoretical limitation of 2D allowed developing systems with rates. This study presents a comprehensive review various evaporator designs achieved pure beyond 4 kg m −2 h −1 , including structural material allowing rapid evaporation, passive 3D designs, coupled alternative energy sources wind joule heating. The operational mechanisms each design are outlined together discussion on current benefits areas improvement. overarching challenges encountered by SDIE concerning feasibility direct integration into contemporary settings assessed, issues relating sustaining elevated under diverse environmental conditions addressed.

Language: Английский

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Understanding the Electrochemical Extraction of Lithium from Ultradilute Solutions

Environmental Science & Technology, Journal Year: 2024, Volume and Issue: 58(8), P. 3997 - 4007

Published: Feb. 17, 2024

The electrochemical extraction of lithium (Li) from aqueous sources using means is a promising direct Li technology. However, to this date, most studies are confined Li-rich brine, neglecting the practical and existing Li-lean resources, with their overall behaviors currently not fully understood. More still, effect elevated sodium (Na) concentrations typically found in water on unclear. Hence, work, we first understand ultradilute solutions spinel manganese oxide as model electrode. We discovered that depends highly concentration cell operation current density. Then, switched our focus low Na ratio solutions, revealing can dominate electrostatic screening layer, reducing ion concentration. Based these understandings, rationally employed pulsed restructure electrode surface distribute surface-adsorbed species, which efficiently achieves high selectivity even extremely initial Li/Na up 1:20,000.

Language: Английский

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