Electrides: emerging electronic materials for catalysis DOI Creative Commons

Fangkun Sun,

Zhilin Guo, Yangfan Lu

et al.

Fundamental Research, Journal Year: 2024, Volume and Issue: unknown

Published: Dec. 1, 2024

BaCu, a Two-Dimensional Electride with Cu Anions DOI
Biao Wan,

Yifang Yuan,

Lu Zheng

et al.

Journal of the American Chemical Society, Journal Year: 2024, Volume and Issue: 146(25), P. 17508 - 17516

Published: June 11, 2024

The electron-rich characteristic and low work function endow electrides with excellent performance in (opto)electronics catalytic applications; these two features are closely related to the structural topology, constituents, valence electron concentration of electrides. However, synthesized electrides, especially two-dimensional (2D) limited specific prototypes anionic

Language: Английский

Citations

11

Functional Electrospun Nanofibrous Hybrid Materials for Colorimetric Sensors: A Review DOI Creative Commons
Shuying Li, Song Yang, Linxu Xu

et al.

ACS Omega, Journal Year: 2024, Volume and Issue: 9(5), P. 5157 - 5174

Published: Jan. 25, 2024

Electrospun nanofibrous hybrid materials have several advantageous characteristics, including easy preparation, high porosity, and a large specific surface area. Meanwhile, they can be more suitable for colorimetric detection in environmental food areas than organic due to the advantages of inorganic nanomaterials, i.e., stability, low toxicity, durability. In addition being able immobilize nanomaterials avoid particle aggregation, electrospinning also area which is beneficial constructing sensors. This review mainly summarizes fabrication methods electrospun application material based First, preparation strategies were discussed. Then, applications obtained sensors molecules gas liquid phase further investigated. Finally, this looks forward development prospects challenges practical order support detection.

Language: Английский

Citations

6

2D Multifunctional Spin‐Orbit Coupled Dirac Nodal Line Materials DOI Creative Commons
Weizhen Meng, Ying Liu,

Jialin Gong

et al.

Advanced Functional Materials, Journal Year: 2025, Volume and Issue: unknown

Published: April 27, 2025

Abstract 2D spin‐orbit coupled Dirac nodal line (SOC‐DNL) materials integrated with multifunctional properties are the cornerstone for constructing an abundant application pool, but remain largely limited. Here, a combination of symmetry analysis, high‐throughput screening, and first‐principles calculations employed to identify comprehensive set 473 nonmagnetic antiferromagnetic (AFM) SOC‐DNL materials, spanning 5 layer groups 12 magnetic space groups. Building on potential these it further integrates their topological electride, multiferroic, characteristics, revealing unique systems expanded functionalities promising applications. Specifically, three representative cases highlighted illustrate distinctive features: i) The electride material so‐MoS₂, which exhibits floating surface states highly anisotropic Fermi surfaces; ii) ferroelastic β‐PbO, demonstrates multiferroic behavior driven by hole‐doping‐induced magnetism polarization‐switch‐enabled phase transitions; iii) AFM system Ti 2 O, features lower work function, significantly enhancing its catalytic performance NH 3 synthesis. These findings not only establish database exploration also enhance multifunctionality, paving way diverse applications in quantum science, spintronics, energy‐related technologies.

Language: Английский

Citations

0

Electride-Induced Electron Transfer to Metal Phthalocyanines: A Mechanistic and Catalytic Study DOI
Zhilin Guo, Yijia Liu,

Xinmeng Hu

et al.

Chemistry of Materials, Journal Year: 2025, Volume and Issue: unknown

Published: May 4, 2025

Language: Английский

Citations

0

In-Situ Characterization Techniques for Investigations of Heterogeneous Catalysis DOI
Guanhua Lin, Gang Chen,

Jingyu Lu

et al.

Journal of Alloys and Compounds, Journal Year: 2024, Volume and Issue: 1010, P. 177552 - 177552

Published: Nov. 14, 2024

Language: Английский

Citations

2

Boosted Heterogeneous Catalysis by Surface‐Accumulated Excess Electrons of Non‐Oxidized Bare Copper Nanoparticles on Electride Support DOI Creative Commons

Sung Su Han,

Athira Thacharon, Jun Kim

et al.

Advanced Science, Journal Year: 2022, Volume and Issue: 10(2)

Published: Nov. 17, 2022

Engineering active sites of metal nanoparticle-based heterogeneous catalysts is one the most prerequisite approaches for efficient production chemicals, but limited and undesired oxidation on nanoparticles still remain as key challenges. Here, it reported that negatively charged surface copper 2D [Ca

Language: Английский

Citations

10

A DFT study on the copper-single-atom modified 2D electride Ca2N monolayer for ethanol dehydrogenation DOI
Yuli Ma, Junyu Lang

International Journal of Hydrogen Energy, Journal Year: 2023, Volume and Issue: 51, P. 970 - 981

Published: July 27, 2023

Language: Английский

Citations

3

A 2D Ba2N Electride for Transition Metal-Free N2 Dissociation under Mild Conditions DOI Creative Commons
Zhujun Zhang, Yihao Jiang, Jiang Li

et al.

Journal of the American Chemical Society, Journal Year: 2023, Volume and Issue: unknown

Published: Oct. 6, 2023

N2 activation is a key step in the industrial synthesis of ammonia and other high-value-added N-containing chemicals, typically heavily reliant on transition metal (TM) sites as active centers to reduce large energy barrier for dissociation. In present work, we report that 2D electride Ba2N with anionic electrons interlayer spacings works efficiently TM-free dissociation under mild conditions. The significantly boost very small 35 kJ mol-1, confirmed by isotopic exchange reaction. reaction molecules stabilizes (N2)2- anions, so-called diazenide, space (∼4.5 Å) sandwiched 2 cationic slabs main intermediate.

Language: Английский

Citations

2

Room-Temperature Synthesis and Transformation of Gqds from Liquid Oxygenates into Nanocrystalline Sp2−Sp3 Hybrid Carbon DOI

Rungkiat Nganglumpoon,

Krongkwan Poolboon,

Pongpan Sitiputa

et al.

Published: Jan. 1, 2024

Language: Английский

Citations

0

Electrides: emerging electronic materials for catalysis DOI Creative Commons

Fangkun Sun,

Zhilin Guo, Yangfan Lu

et al.

Fundamental Research, Journal Year: 2024, Volume and Issue: unknown

Published: Dec. 1, 2024

Citations

0