Inorganic Chemistry,
Journal Year:
2025,
Volume and Issue:
64(10), P. 4784 - 4790
Published: March 5, 2025
A
novel
magnetic
hollowed
CoFe@C-650
prism
catalyst
has
been
successfully
prepared
and
applied
in
the
N-alkylation
of
alcohols
amines
through
a
hydrogen
borrowing
strategy.
The
demonstrates
good
to
excellent
activities
reaction
with
broad
substrate
scope
afford
up
99%
yield
target
products.
preliminary
mechanistic
study
reveals
that
high
valent
Co
species
may
promote
adsorption
conversion
alcohols,
while
Fe
assists
hydrogenating
imine
intermediates.
Small,
Journal Year:
2024,
Volume and Issue:
unknown
Published: Dec. 12, 2024
It
is
of
great
significance
for
the
development
hydrogen
energy
technology
by
exploring
new-type
and
high-efficiency
electrocatalysts
(such
as
single
atom
catalysts
(SACs))
water
splitting.
In
this
paper,
combining
interface
engineering
doping
engineering,
a
unique
iron
(Fe)-doped
carbon-coated
nickel
sulfide
(Ni
Inorganic Chemistry,
Journal Year:
2025,
Volume and Issue:
64(10), P. 4784 - 4790
Published: March 5, 2025
A
novel
magnetic
hollowed
CoFe@C-650
prism
catalyst
has
been
successfully
prepared
and
applied
in
the
N-alkylation
of
alcohols
amines
through
a
hydrogen
borrowing
strategy.
The
demonstrates
good
to
excellent
activities
reaction
with
broad
substrate
scope
afford
up
99%
yield
target
products.
preliminary
mechanistic
study
reveals
that
high
valent
Co
species
may
promote
adsorption
conversion
alcohols,
while
Fe
assists
hydrogenating
imine
intermediates.
