Microchimica Acta, Journal Year: 2024, Volume and Issue: 191(8)
Published: July 16, 2024
Language: Английский
Advanced Science, Journal Year: 2023, Volume and Issue: 10(33)
Published: Oct. 23, 2023
Strong substrate affinity and high catalytic efficiency are persistently pursued to generate high-performance nanozymes. Herein, with unique surface atomic configurations distinct d-orbital coupling features of different metal components, a class highly efficient MnFeCoNiCu transition high-entropy nanozymes (HEzymes) is prepared for the first time. Density functional theory calculations demonstrate that improved between metals increases electron density near Fermi energy level (EF ) shifts position overall d-band center respect EF , thereby boosting site-to-site transfer while also enhancing adsorption oxygen intermediates during catalysis. As such, proposed HEzymes exhibit superior affinities efficiencies comparable natural horseradish peroxidase (HRP). Finally, superb (POD)-like activity used in biosensing antibacterial applications. These results suggest have great potential as new-generation
Language: Английский
Citations
57
Advanced Materials, Journal Year: 2024, Volume and Issue: 36(24)
Published: March 4, 2024
Abstract High‐entropy (HE) materials, celebrated for their extraordinary chemical and physical properties, have garnered increasing attention broad applications across diverse disciplines. The expansive compositional range of these materials allows nuanced tuning properties innovative structural designs. Recent advances been centered on versatile photothermal conversion capabilities, effective the full solar spectrum (300–2500 nm). HE effect, coupled with hysteresis diffusion, imparts desirable thermal stability. These attributes position as a revolutionary alternative to traditional signifying transformative shift in technology. This review delivers comprehensive summary current state knowledge regarding emphasizing intricate relationship between compositions, structures, light‐absorbing mechanisms, optical properties. Furthermore, outlines notable contributions areas, such water evaporation, personal management, thermoelectric generation, catalysis, biomedical applications. culminates presenting roadmap that prospective directions future research this burgeoning field, also fruitful ways develop advanced expand promising
Language: Английский
Citations
40
ACS Nano, Journal Year: 2024, Volume and Issue: unknown
Published: Sept. 23, 2024
Point-of-care (POC) nanosensors with high screening efficiency show promise for user-friendly manipulation in the ever-increasing on-site analysis demand illness diagnosis, environmental monitoring, and food safety. Currently, inspired by merits of integrating advanced nanomaterials, molecular biology, machine learning, artificial intelligence, lateral flow immunoassay (LFIA)-based POC have been devoted to satisfying commercial demands terms sensitivity, specificity, practicality. Herein, we examine use multidimensional enhanced LFIA various fields over past two decades, focusing on introducing nanomaterials improve acquisition capability small order magnitude targets through engineering transformations emphasizing interdomain fusion collaboratively address inherent challenges current applications, such as multiplexing, development detectors quantitative analysis, more practical sensitivity enhancement. Specifically, this comprehensive review encompasses latest advances comprehending an alternative signal transduction pattern, aiming achieve rapid, ultrasensitive, "sample-to-answer" available options progressive applications nanosensors. In summary, cross-collaboration disciplines, has potential break barriers toward commercialization laboratory-level nanosensors, thus leading emergence next generation LFIA.
Language: Английский
Citations
24
Advanced Functional Materials, Journal Year: 2024, Volume and Issue: 34(34)
Published: April 13, 2024
Abstract The peroxidase (POD)‐mimic nanozymes can be a potential tool for point‐of‐care (POC) diseases diagnosis. However, the complex sample matrix and unspecific multiple‐enzyme activities of nanozyme generate false background signal decrease diagnostic accuracy. Here, magnetic POD‐specific covalent organic framework (COF) confined osmium (Os) nanoclusterzyme Fe 3 O 4 @COF@Os is developed biomarkers biosensing. First, found that catalytic activity specificity regulated by deoxidizers functional groups COF ligands. By using ascorbic acid as deoxidizer F ligands, displayed superior negligible oxidase (OXD) catalase (CAT) mimic activity. Therefore, separate analyze targets in bio‐matrix without interference. For application, based lateral flow assay established serum cancer biomarker prostate‐specific antigen, detection limit 3.83 pg mL −1 . clinical prostatic samples, accuracy 100% with correlation coefficient 0.998 commercial ELISA kit. chronic disease sensing, salivary glucose quantified low 0.1 µ m , interference favorable recyclability. This specific offer promising pretreatment‐free POC strategy rapid accurate
Language: Английский
Citations
15
Chemical Engineering Journal, Journal Year: 2024, Volume and Issue: 489, P. 151374 - 151374
Published: April 16, 2024
Language: Английский
Citations
14
ACS Nano, Journal Year: 2024, Volume and Issue: 18(37), P. 25865 - 25879
Published: Sept. 2, 2024
Greatly improving the sensitivity and detection range of lateral flow immunoassays (LFAs) by at least 100 times without using additional instruments remains challenging. Herein, we develop a three-dimensional (3D) film-like nanozyme (GO-Pt
Language: Английский
Citations
14
ACS Materials Letters, Journal Year: 2024, Volume and Issue: 6(6), P. 2487 - 2496
Published: May 23, 2024
Nanozyme hybrids with photothermally mediated catalytic activity have received increasing attention in addressing the challenges of public health events caused by bacterial infections. However, designing photothermal nanozyme efficient synergistic antibacterial properties remains a challenge but is desirable. Herein, prepared CuxO@PDA (CP) showed excellent conversion efficiency 39.81%. More interestingly, CP also possesses peroxidase-like activity, which could convert H2O2 to •OH, and capability was improved under NIR irradiation. The effect between makes proposed therapy able kill 99.74% Staphylococcus aureus (S. aureus) 99.82% Escherichia coli (E. coli). In vivo experiments further that ability be well applied wound infection treatment. Overall, our work provides insight into design high-efficacy photothermal-mediated compounds for broad-spectrum applications.
Language: Английский
Citations
13
Advanced Science, Journal Year: 2024, Volume and Issue: 11(38)
Published: Aug. 9, 2024
Engineering multimetallic nanocatalysts with the entropy-mediated strategy to reduce reaction activation energy is regarded as an innovative and effective approach facilitate efficient heterogeneous catalysis. Accordingly, conformational entropy-driven high-entropy alloys (HEAs) are emerging a promising candidate settle catalytic efficiency limitations of nanozymes, attributed their versatile active site compositions synergistic effects. As proof nanozymes (HEzymes) concept, elaborate PdMoPtCoNi HEA nanowires (NWs) abundant sites tuned electronic structures, exhibiting peroxidase-mimicking activity comparable that natural horseradish peroxidase reported. Density functional theory calculations demonstrate enhanced electron abundance NWs near Fermi level (E
Language: Английский
Citations
13
Sensors and Actuators B Chemical, Journal Year: 2024, Volume and Issue: 414, P. 135952 - 135952
Published: May 11, 2024
Language: Английский
Citations
12
Journal of Materials Chemistry B, Journal Year: 2024, Volume and Issue: 12(14), P. 3404 - 3416
Published: Jan. 1, 2024
Schematic diagram of the preparation enzyme-responsive nanoplatform HA-CP@Fe 3 O 4 and its application in study antibacterial infection vivo .
Language: Английский
Citations
10