Journal of Colloid and Interface Science, Journal Year: 2024, Volume and Issue: 678, P. 1223 - 1229
Published: Sept. 23, 2024
Language: Английский
Coordination Chemistry Reviews, Journal Year: 2025, Volume and Issue: 529, P. 216458 - 216458
Published: Jan. 22, 2025
Language: Английский
Citations
2
Fuel, Journal Year: 2025, Volume and Issue: 388, P. 134550 - 134550
Published: Feb. 1, 2025
Language: Английский
Citations
2
Advanced Science, Journal Year: 2024, Volume and Issue: 11(21)
Published: March 25, 2024
Metal borides have received a lot of attention recently as potentially useful material for wide range applications. In particular, molybdenum-based and MBenes are great significance, due to their remarkable properties like good electronic conductivity, considerable stability, high surface area, environmental harmlessness. Therefore, in this article, the progress made recent years is reviewed. The first step understanding these materials begin with an overview structural properties. Then synthetic technologies production molybdenum borides, such high-temperature/pressure methods, physical vapor deposition (PVD), chemical (CVD), element reaction route, molten salt-assisted, selective etching methods surveyed. Then, critical performance numerous applications energy storage, catalysis, biosensors, biomedical devices, surface-enhanced Raman spectroscopy (SERS), tribology lubrication summarized. review concludes analysis current provides perspectives future research. Overall, will offer insightful reference development future.
Language: Английский
Citations
15
Advanced Functional Materials, Journal Year: 2024, Volume and Issue: unknown
Published: Nov. 15, 2024
Abstract The underutilization of active sites limits the performance enhancement 2D transition metal boride (MBene) in electrocatalytic nitrogen reduction reaction (NRR). Herein, a highly efficient NRR electrocatalyst with S atoms bridging Fe and Mo on surface MBene is successfully constructed by using an site electron optimization strategy, which increases charge density around enhances activation ability catalyst to N 2 molecules. It noteworthy that FeS ‐MBene demonstrates low intrinsic potential for (−0.2 V vs RHE). more favorable adsorption comparison hydrogen atoms, thereby it can effectively inhibit evolution (HER). Under −0.2 versus RHE, ammonia yield rate 37.13 ± 1.31 µg h −1 mg , FE 55.97 2.63%. Density functional theory (DFT) calculations demonstrate serves as . formation heterostructure transfer, resulting becoming electron‐rich state favor subsequent hydrogenation steps. This work offers significant insights into design utilization MBene‐based catalysts NRR.
Language: Английский
Citations
15
Advanced Functional Materials, Journal Year: 2025, Volume and Issue: unknown
Published: Feb. 7, 2025
Abstract An efficient electrocatalytic medium is very important for lithium–sulfur (Li–S) batteries. Herein, as a novel MBene‐based material, 2D MoB employed to facilitate the catalytic conversion of lithium polysulfides (LiPSs). Instead HF etching technology previous MXene, accordion‐like MoB‐based MBene adopts hydrothermal‐assisted process. Its F‐free surface property prevents harm negative sulfur cathode from −F terminations. The high charge conductivity and abundant active sites promote adsorption‐transfer LiPSs on accelerate redox kinetics. Theoretical calculation, visual detection in situ Raman results show that stratified MoB‐coated separator inhibits “shuttle effect” soluble through coupling physical chemical mechanisms. Therefore, this work achieves commendable stability 847 mAh g −1 reversible capacity (2.0 C) 0.0651% attenuation rate per cycle (4.0 C). area 4.93 cm −2 still obtained under loading. More importantly, has uncovered great potential promising catalyst reaction species.
Language: Английский
Citations
1
SusMat, Journal Year: 2024, Volume and Issue: 4(5)
Published: Aug. 20, 2024
Abstract In the past decade, molybdenum ditelluride (MoTe 2 ) has received significant attention from scientific community due to its structural features and unique properties originate them. current review, properties, various preparation approaches, versatile applications of MoTe are presented. The review provides a brief update on state our fundamental understanding material also discusses issues that need be resolved. To introduce , we briefly summarize structural, optoelectronic, magnetic, mechanical in beginning. Then, different methods such as exfoliation, laser treatment, deposition, hydrothermal, microwave, molecular beam epitaxy, included. excellent electrical conductivity, strong optical activity, tunable bandgap, high sensitivity, impressive stability make it an ideal contender for applications, including energy storage, catalysis, sensors, solar cells, photodetectors, transistors. performance these is systematically introduced along with mechanistic insights. At end article, challenges possible future directions highlighted further modify numerous functionalities. Therefore, availability phases layer structures implies potential lead era two‐dimensional materials began exfoliation graphene.
Language: Английский
Citations
8
Journal of the European Ceramic Society, Journal Year: 2024, Volume and Issue: 44(12), P. 6926 - 6934
Published: May 15, 2024
Language: Английский
Citations
7
Advanced Science, Journal Year: 2024, Volume and Issue: 11(33)
Published: July 1, 2024
2D transition metal borides (MBenes) with abundant surface terminals hold great promise in molecular sensing applications. However, MBenes from etching fluorine-containing reagents present inert -fluorine groups on the surface, which hinders their capability. Herein, multilayer fluorine-free MoBT
Language: Английский
Citations
7
Published: April 1, 2025
Language: Английский
Citations
0
Sustainable materials and technologies, Journal Year: 2025, Volume and Issue: unknown, P. e01427 - e01427
Published: May 1, 2025
Language: Английский
Citations
0