A Scalable Robust Microporous Al‐MOF for Post‐Combustion Carbon Capture

Advanced Science, Journal Year: 2024, Volume and Issue: 11(21)

Published: March 25, 2024

Abstract Herein, a robust microporous aluminum tetracarboxylate framework, MIL‐120(Al)‐AP, (MIL, AP: Institute Lavoisier and Ambient Pressure synthesis, respectively) is reported, which exhibits high CO 2 uptake (1.9 mmol g −1 at 0.1 bar, 298 K). In situ Synchrotron X‐ray diffraction measurements together with Monte Carlo simulations reveal that this structure offers favorable capture configuration the pores being decorated density of µ ‐OH groups accessible aromatic rings. Meanwhile, based on calculations experimental evidence, moderate host‐guest interactions Q st (CO ) value MIL‐120(Al)‐AP (−40 kJ mol deduced, suggesting relatively low energy penalty for full regeneration. Moreover, an environmentally friendly ambient pressure green route, relying inexpensive raw materials, developed to prepare kilogram scale yield while Metal‐ Organic Framework (MOF) further shaped inorganic binders as millimeter‐sized mechanically stable beads. First evidences its efficient /N separation ability are validated by breakthrough experiments operando IR indicate kinetically adsorption over water. Finally, techno‐economic analysis gives estimated production cost ≈ 13 $ kg , significantly lower than other benchmark MOFs. These advancements make excellent candidate adsorbent industrial‐scale processes.

Language: Английский

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Hierarchical Fibrous Metal–Organic Framework/Ionic Liquid Membranes for Efficient CO₂/N₂ Separation

Nano Letters, Journal Year: 2025, Volume and Issue: unknown

Published: Feb. 6, 2025

The structural diversity and chemical functionality of metal–organic frameworks (MOFs) render them promising candidates for CO2 adsorption separation. However, their applications are often restricted by intrinsic fragility decreased processability. Herein, a hierarchical fibrous MOF/ionic liquid (IL) membrane was constructed assembling well-ordered ZIF-8 nanounits with an encapsulated IL along the polyimide (PI) fibers. This design promotes formation efficient three-dimensional gas transfer network generates abundance nanopores decorated CO2-philic units, thereby enhancing separation from N2. PI/ZIF-8/IL membranes exhibit remarkable features, including large specific surface area 79.89 m2 g–1, high porosity 93.28%, excellent mechanical stability. Moreover, demonstrate enhanced capacity 3.32 mmol/g at 298 K 1 bar, CO2/N2 selectivity 28, stable recyclable regeneration capability. integrated pore structure proposed in this study provides practical direction rational MOF/IL targeted applications.

Language: Английский

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Enhancing CO2 sequestration efficiency: A comprehensive study of nanostructured MOF-composite membrane for sustainable climate solution

Carbon Capture Science & Technology, Journal Year: 2025, Volume and Issue: unknown, P. 100366 - 100366

Published: Jan. 1, 2025

Language: Английский

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Recent advances and challenges in solid sorbents for CO2 capture

Carbon Capture Science & Technology, Journal Year: 2025, Volume and Issue: unknown, P. 100386 - 100386

Published: Feb. 1, 2025

Language: Английский

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Synthetic Aspects and Characterization Needs in MOF Chemistry – from Discovery to Applications

Advanced Materials, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 7, 2025

Even if MOFs are recently developed for large-scale applications, the road to applications of is long and rocky. This requires overcome challenges associated with phase discovery, synthesis optimization, basic advanced characterization, computational studies. Lab-scale results need be transferred processes, which often not trivial, life-cycle analyses techno-economic performed realistically assess their potential industrial relevance. Based on experience in field stable, functional combining synthesis, modeling, this mini-review gives recommendations especially non-specialists, example, from chemical engineers medical doctors, accelerate facilitate knowledge transfer will ultimately lead application MOFs. The include reporting characterization data as well standardization detailed information required mining machine learning techniques, increasingly used discovery new materials analysis. Once a suitable MOF identified its key properties determined, translational studies shall finally carried out collaboration end-users validate performance under real conditions allow understanding processes involved.

Language: Английский

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CALF-20 obtained by mechanochemical synthesis for temperature swing adsorption CO2 Capture: A thermodynamic and kinetic study

Chemical Engineering Journal, Journal Year: 2025, Volume and Issue: unknown, P. 159966 - 159966

Published: Jan. 1, 2025

Language: Английский

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Turning Microstructure in Block Copolymer Membranes: A Facile Strategy to Improve CO₂ Separation Performance

Advanced Science, Journal Year: 2025, Volume and Issue: unknown

Published: April 17, 2025

Abstract To mitigate global climate change, the development of membranes with high CO 2 permeability and selectivity is urgently needed. Here, a simple effective non‐solvent‐induced microstructure rearrangement (MSR) technique proposed to enhance gas separation performance Pebax 2533 membranes. By immersing in amino acid salt solutions induce MSR, optimized 2533‐GlyK 10 wt.% membrane reached 1180 Barrer, 4.5‐fold increase compared original membrane, without compromising /N selectivity. Moreover, MSR maintains stable for nearly 500 days, demonstrating excellent long‐term stability. Furthermore, applying thin‐film composite (TFC) revealed that both 2533/polyvinyl chloride (PVC) hollow fiber (HF) TFC 2533/polyacrylonitrile (PAN) flat‐sheet exhibited significantly enhanced permeance under treatment DI water. Characterization results indicated chemical‐physical properties before after are unchanged, suggesting promising next‐generation carbon capture.

Language: Английский

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Green and Scalable Preparation of an Isomeric CALF‐20 Adsorbent with Tailored Pore Size for Molecular Sieving of Propylene from Propane

Small Methods, Journal Year: 2024, Volume and Issue: unknown

Published: July 29, 2024

Abstract Molecular sieving of propylene (C 3 H 6 ) from propane 8 is highly demanded for C purification. However, delicate control over aperture size to achieve both high uptake and /C selectivity with low cost remains a significant challenge. Herein, green scalable approach reported preparing an isomeric CALF‐20 adsorbent, termed as NCU‐20, using water the only solvent $10 per kilogram. NCU‐20 features contracted pore (4.2 × 4.7 Å 2 compared (5.2 5.7 ), which enables molecular (4.16 4.65 (4.20 4.80 ). Notably, exhibits record‐high adsorption capacity (94.41 cm −3 at 298 K 1.0 bar, outperforming all adsorbents. The performances are well maintained elevated temperatures. Therefore, balance between (91.62 (uptake ratio 22.2) obtained on 0.5 bar. Furthermore, dynamic breakthrough experiments demonstrate productivity 65.39 high‐purity (>99.5%) equimolar gas‐mixture.

Language: Английский

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Carbon Dioxide Capture and Conversion Using Metal–Organic Framework (MOF) Materials: A Comprehensive Review

Nanomaterials, Journal Year: 2024, Volume and Issue: 14(16), P. 1340 - 1340

Published: Aug. 12, 2024

The escalating threat of anthropogenic climate change has spurred an urgent quest for innovative CO2 capture and utilization (CCU) technologies. Metal–organic frameworks (MOFs) have emerged as prominent candidates in conversion due to their large specific surface area, well-defined porous structure, tunable chemical properties. This review unveils the latest advancements MOF-based materials specifically designed superior adsorption, precise separation, advanced photocatalytic electrocatalytic reduction, progressive hydrogenation, dual functionalities. We explore strategies that enhance MOF efficiency examine challenges opportunities afforded by transitioning from laboratory research industrial application. Looking ahead, this offers a visionary perspective on harnessing MOFs sustainable CO2.

Language: Английский

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NanoMOF‐Based Multilevel Anti‐Counterfeiting by a Combination of Visible and Invisible Photoluminescence and Conductivity

Advanced Functional Materials, Journal Year: 2025, Volume and Issue: unknown

Published: April 2, 2025

Abstract This study presents nanosized metal‐organic framwork (nanoMOF)‐based multifunctional mixed‐matrix‐membranes (MMMs) and composite powders as extremely sensitive responder materials for a responder‐stimulus based multilevel anti‐counterfeiting. The physicochemical properties of nanoMOF‐based composites offer wide operational range anti‐counterfeiting tags. Nine are presented, constituted trivalent lanthanide‐containing nanoMOFs ([Ln 3 (bdc) 4.5 (H 2 O) (dmf) ] (nLn‐bdc); bdc 2− ═benzene‐1,4‐dicarboxylate; Ln═Eu, Tb, Yb) polystyrene sulfonate, pyrolyzed resorcinol‐formaldehyde polysulfone matrices. These inherit distinct properties, their combination provides visible near‐infrared light emission specific conductivity multiple security level additive interdependent nature features in the developed ensures that altering one feature will invariably affect others, thereby reinforcing overall integrity resilience mechanism. Even pitch‐black nLn‐bdc show bright to range, when stimulated by UV‐light being suitable black materials. work also describes matrix‐based active contribution an tag, instead solely used carrier feature‐bearing nanoMOFs. levels different marks these complicated copy including proof‐of‐principle experiment.

Language: Английский

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