Electrolyte Developments for All‐Solid‐State Lithium Batteries: Classifications, Recent Advances and Synthesis Methods DOI Creative Commons

Cheuk Hei Chan,

Hon Ho Wong,

Suzhe Liang

et al.

Batteries & Supercaps, Journal Year: 2024, Volume and Issue: 7(12)

Published: Aug. 16, 2024

Abstract The developments of all‐solid‐state lithium batteries (ASSLBs) have become promising candidates for next‐generation energy storage devices. Compared to conventional batteries, ASSLBs possess higher safety, density, and stability, which are determined by the nature solid electrolyte materials. In particular, various types materials been developed achieve similar or even superior ionic conductivity organic liquid at room temperature. Although tremendous efforts devoted mechanistic understanding materials, unsatisfactory electrochemical mechanical performances limit commercialization practical application ASSLBs. To further improve their performances, current different advanced electrolytes highly significant. this review, we summarize comprehensive performance common fabrication strategies, including inorganic‐based electrolytes, polymer composite electrolytes. constructed systematically compared. challenges will also be summarized in review. This review aims provide a discuss strategies facilitate future

Language: Английский

Designing Reliable Cathode System for High‐Performance Inorganic Solid‐State Pouch Cells DOI Creative Commons

Shuying Wang,

Sheng Liu, Wei Chen

et al.

Advanced Science, Journal Year: 2024, Volume and Issue: 11(23)

Published: March 30, 2024

Abstract All‐solid‐state batteries (ASSBs) based on inorganic solid electrolytes fascinate a large body of researchers in terms overcoming the inferior energy density and safety issues existing lithium‐ion batteries. To date, cathode designs ASSBs achieve remarkable achievements, adding urgency scaling up battery system toward solid‐state pouch cell configuration for application market. Herein, recent developments materials design considerations their format are reviewed to straighten out roadmap ASSBs. Specifically, intercalation compounds conversion with chemistries highlighted discussed as two potentially valuable material types. This review focuses basic electrochemical mechanisms, mechanical contact issues, sheet‐type structure cells corresponding perspectives, thus guiding future research direction. Finally, benchmarks manufacturing meet practical high targets provided this development commercially viable products.

Language: Английский

Citations

8
Lithium Metal Based Battery Systems Beyond 500 Wh kg-1 DOI
Chenyu Yang,

Zhan Jiang,

X. Y. Chen

et al.

Chemical Communications, Journal Year: 2024, Volume and Issue: 60(75), P. 10245 - 10264

Published: Jan. 1, 2024

As industries and consumption patterns evolve, new electrical appliances are increasingly playing critical roles in national production, defense, cognitive exploration. However, the slow development of energy storage devices with ultra-high density (beyond 500 W h kg

Language: Английский

Citations

7
Finely‐Tuned Polar‐Nonpolar Synergistic Binder Enables Ultra‐Thin Sulfide Solid Electrolyte Membrane for All‐Solid‐State Batteries DOI
Rui Li,

Ning Chen,

Shengnan Liu

et al.

Advanced Functional Materials, Journal Year: 2024, Volume and Issue: unknown

Published: Sept. 13, 2024

Abstract The solid electrolyte (SE) membrane plays a crucial role in sulfide‐based all‐solid‐state batteries (ASSBs). However, the challenge of finding appropriate polymer binders with excellent (electro‐)chemical compatibility and adhesive properties, remains significant obstacle for wet slurry processing sulfide SE membranes. Herein, novel “polar‐nonpolar synergistic” finely‐tuned strategy is employed to design an ethylene‐methyl acrylate (EMA) copolymer binder facilitate wet‐slurry‐based fabrication Significantly, by adjusting ratio polar nonpolar groups, this methodology enables dissolve effectively toluene‐based also ensures good adhesion between EMA particles. prepared exhibits ultra‐thin thickness (36 µm), flexibility, ionic conductivity (1.43 mS cm −1 ). ASSB assembled shows capacity retention rate 92.9% after 120 cycles at 0.5 C. This work on effect provides insight manufacturing high‐quality

Language: Английский

Citations

4
Strategies Toward Stable Anode Interface for Sulfide‐Based All‐Solid‐State Lithium Metal Batteries DOI Open Access
E.Z. Luo, Xuemei Ren, Miao He

et al.

Small, Journal Year: 2025, Volume and Issue: unknown

Published: March 24, 2025

Abstract Sulfide‐based all‐solid‐state batteries (ASSBs) have ushered in a new era of energy storage technology, offering the tantalizing prospect unprecedented density and safety. However, poor electrode‐electrolyte interface between Li anodes sulfide solid electrolytes has hindered its practical application. In this review, primary focus lies current fundamental understanding, challenges, optimization strategies regarding chemistries anode. First, an in‐depth discussion is conducted provides detailed summary interfacial challenges that exist anode electrolytes. Among these compatibility stability stand out as two crucial issues. Subsequently, effective approaches are systematically explored to surmount These encompass component structural design bulk anode, doping coating electrolytes, Finally, insights present into limitations studies, perspectives, recommendations for further development sulfide‐based solid‐state batteries, aiming offer comprehensive enlightening overview engineering, which great significance integration applicable metal (ASSLMBs).

Language: Английский

Citations

0
Degradation and Failure Mechanisms of Lithium/LiNixCoyMn1–x–yO2 Batteries DOI Creative Commons
Jia Guo, Pengwei Li, F. Del Piccolo

et al.

ACS Energy Letters, Journal Year: 2025, Volume and Issue: unknown, P. 2318 - 2340

Published: April 15, 2025

Citations

0
Inorganic solid electrolytes for all-solid-state sodium/lithium-ion batteries: recent development and applications DOI Creative Commons
Muhammad Muzakir, M. Karnan, Eric Jianfeng Cheng

et al.

Journal of Materials Chemistry A, Journal Year: 2024, Volume and Issue: unknown

Published: Nov. 14, 2024

This review provides a comprehensive overview of recent advancements in preparation techniques and electrolyte engineering. It also discusses the integration both single- multi-phase electrolytes ASSBs future research potentials.

Language: Английский

Citations

3
Optimization of Porous Structures of Carbon Matrices for Loading Red Phosphorus to Achieve High-Capacity and Long-Life Anodes for All-Solid-State Lithium-Ion Batteries DOI
Sirui Wang, Dan Liú, Yu Chen

et al.

ACS Applied Materials & Interfaces, Journal Year: 2024, Volume and Issue: 16(29), P. 38041 - 38052

Published: July 12, 2024

All-solid-state lithium-ion batteries (ASSLIBs) using sulfide electrolytes and high-capacity alloy-type anodes have attracted sizable interest due to their potential excellent safety high energy density. Encapsulating insulating red phosphorus (P) inside nanopores of a carbon matrix can adequately activate its electrochemical alloying reaction with lithium. Therefore, the porosity plays crucial role in performance resulting P/carbon composites. Here, we use zeolite-templated (ZTC) monodisperse micropores mesoporous (CMK-3) uniform mesopores as model hosts P. Our results reveal that enable more effective pore utilization for P loading, P@ZTC material achieve record-high content (65.0 wt %) confined within pores. When used an anode ASSLIBs, electrode delivers ultrahigh capacity 1823 mA h g–1 initial Coulombic efficiency 87.44%. After 400 deep discharge–charge cycles (running over 250 days) at 0.2 A g–1, still holds reversible 1260 (99.92% retention per cycle). Moreover, P@ZTC||LiNi0.8Co0.1Mn0.1O2 full cell deliver areal 3 cm–2 0.1C after 100 cycles.

Language: Английский

Citations

1
Electrolyte Developments for All‐Solid‐State Lithium Batteries: Classifications, Recent Advances and Synthesis Methods DOI Creative Commons

Cheuk Hei Chan,

Hon Ho Wong,

Suzhe Liang

et al.

Batteries & Supercaps, Journal Year: 2024, Volume and Issue: 7(12)

Published: Aug. 16, 2024

Abstract The developments of all‐solid‐state lithium batteries (ASSLBs) have become promising candidates for next‐generation energy storage devices. Compared to conventional batteries, ASSLBs possess higher safety, density, and stability, which are determined by the nature solid electrolyte materials. In particular, various types materials been developed achieve similar or even superior ionic conductivity organic liquid at room temperature. Although tremendous efforts devoted mechanistic understanding materials, unsatisfactory electrochemical mechanical performances limit commercialization practical application ASSLBs. To further improve their performances, current different advanced electrolytes highly significant. this review, we summarize comprehensive performance common fabrication strategies, including inorganic‐based electrolytes, polymer composite electrolytes. constructed systematically compared. challenges will also be summarized in review. This review aims provide a discuss strategies facilitate future

Language: Английский

Citations

0