Synergistic Bimetallic Effects of BiSb Anodes Enable Long‐Stable Sodium Storage
Liu Yang,
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Xi Liu,
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Xinying Wang
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et al.
Advanced Functional Materials,
Journal Year:
2024,
Volume and Issue:
unknown
Published: Oct. 28, 2024
Abstract
Alloy‐type
anodes
are
of
interest
for
their
resource‐rich
and
high
theoretical
capacity
performance
in
sodium‐ion
batteries
(SIBs).
However,
severe
volume
expansion
may
lead
to
rapid
decay
electrode
pulverization.
In
this
work,
metallic
Bi
with
better
structure
stability
is
rationally
selected
as
a
skeleton
form
2D
BiSb
alloy
alleviate
the
expansion.
Interestingly,
by
combining
in‐situ
XRD
ex‐situ
TEM
characterizations,
reversible
multi‐step
alloying
sodium
storage
mechanism
↔
Na(Bi,
Sb)
Na
3
(Bi,
0.4
Sb
0.6
anode
elucidated,
partial
amorphization
expanded
interlayer
spacing
also
revealed,
which
greatly
thereby
enhancing
electrochemical
stability.
Furthermore,
density
functional
theory
kinetic
calculations
demonstrate
that
demonstrates
lower
+
adsorption
energy
diffusion
barriers,
ensuring
fast
electron
ion
transportation
during
storage.
Benefiting
from
synergistic
effects
binary
alloy,
exhibits
cycling
446
mAh
g
−1
at
0.1
A
,
70%
after
1100
cycles
0.5
.
This
work
provides
new
insights
opportunities
develop
advanced
precise
alloy‐type
materials
SIBs.
Language: Английский
Monodisperse Manganese‐Vanadium‐Oxo Clusters with Extraordinary Lithium Storage
Advanced Science,
Journal Year:
2024,
Volume and Issue:
11(29)
Published: June 3, 2024
Abstract
Although
possessing
well‐defined
nanostructures
and
excellent
multi‐electron
redox
properties,
polyoxometalate
clusters
have
poor
intrinsic
electrical
conductivity
are
prone
to
aggregation
due
large
surface
energy,
which
makes
them
difficult
be
fully
utilized
when
applying
as
electrode
materials
for
lithium‐ion
batteries.
In
this
paper,
monodisperse
K
7
MnV
13
O
38
(MnV
)
achieved
by
rationally
utilizing
nano‐sized
high
conductive
carbon
dots
(CDs)
stabilizers.
Benefiting
from
the
exposed
sites
of
(high
utilization
rate)
sufficient
interfaces
with
(extra
interfacial
energy
storage),
optimized
/10CDs
anode
delivers
a
discharge
capacity
up
1348
mAh
g
−1
at
current
density
0.1
A
exhibits
superb
rate/cycling
capabilities.
Density
functional
theory
(DFT)
calculations
verify
that
ionic
archway
channels
formed
between
CDs,
eliminating
bandgap
greatly
improving
electron/ion
CDs.
This
paper
paves
brand‐new
way
synthesis
maximization
extra
storage.
Language: Английский
Electrochemical performance of polyoxometalate-based composite materials fabricated by a localization-coating strategy
Peiqin Tang,
No information about this author
Xuan Li,
No information about this author
Rui Liu
No information about this author
et al.
Colloids and Surfaces A Physicochemical and Engineering Aspects,
Journal Year:
2025,
Volume and Issue:
720, P. 137071 - 137071
Published: April 28, 2025
Language: Английский
Targeting Protein Aggregation: the Promising Application of Polyoxometalates in Neurodegenerative Diseases
Junyi Chen,
No information about this author
Wenzhu Yang,
No information about this author
Huilan Chen
No information about this author
et al.
Inorganic Chemistry Frontiers,
Journal Year:
2024,
Volume and Issue:
unknown
Published: Jan. 1, 2024
Recent
progress
in
the
therapeutic
applications
of
polyoxometalates
(POMs)
to
target
protein
aggregates
neurodegenerative
diseases
(NDDs)
is
reviewed.
Language: Английский