Journal of environmental chemical engineering, Journal Year: 2024, Volume and Issue: unknown, P. 114642 - 114642
Published: Oct. 1, 2024
Language: Английский
Journal of environmental chemical engineering, Journal Year: 2024, Volume and Issue: unknown, P. 114642 - 114642
Published: Oct. 1, 2024
Language: Английский
Nano Energy, Journal Year: 2025, Volume and Issue: 135, P. 110643 - 110643
Published: Jan. 5, 2025
Language: Английский
Citations
11Inorganic Chemistry, Journal Year: 2025, Volume and Issue: unknown
Published: Jan. 14, 2025
Here, we reported a highly efficient nitrate electroreduction (NO3RR) electrocatalyst that integrated alloying and heterostructuring strategies comprising FeCo alloy Mo0.82N (FeCo-Mo0.82N/NC). Notably, the maximum NH3 Faraday efficiency (FE) of 83.24%, yield 12.28 mg h-1 mgcat.-1, good stability were achieved over FeCo-Mo0.82N/NC. Moreover, Zn-NO3- battery assembled with FeCo-Mo0.82N/NC exhibited power density 0.87 mW cm-2, an 14.09 FE as high 76.31%.
Language: Английский
Citations
7Small Methods, Journal Year: 2025, Volume and Issue: unknown
Published: Jan. 7, 2025
Abstract Urea‐assisted water splitting is a promising energy‐saving hydrogen (H 2 ) production technology. However, its practical application hindered by the lack of high‐performance bifunctional catalysts for urea oxidation reaction (UOR) and evolution (HER). Herein, heterostructured catalyst comprising highly active NiSe Ni 3 Se , along with conductive graphene‐coated nickel foam skeleton (NiSe‐Ni /GNF) reported. The NiSe‐Ni originates from in situ selenization foam, allowing careful regulation to ratio simply adjusting calcination temperature. Theoretical calculations charge transfer between components can optimize pathways reduce corresponding energy barriers. Accordingly, designed exhibits excellent UOR HER activity stability. Furthermore, /GNF‐based UOR‐HER electrolyzer requires only 1.54 V achieve current density 50 mA cm −2 which lower than many recent reports much 1.83 OER‐HER electrolyzers. Moreover, exhibited negligible cell voltage variation during 28‐h stability test, indicating satisfactory stability, provides new viable paradigm H production.
Language: Английский
Citations
6Materials Chemistry Frontiers, Journal Year: 2025, Volume and Issue: unknown
Published: Jan. 1, 2025
A phosphide heterojunction has been developed as an efficient catalyst toward methanol-assisted seawater splitting with good activity and high durability.
Language: Английский
Citations
5Advanced Materials, Journal Year: 2025, Volume and Issue: unknown
Published: March 31, 2025
Abstract Metal‐organic frameworks (MOFs) are highly versatile materials with tunable chemical and structural properties, making them promising for triboelectric nanogenerators (TENGs) electrocatalysis. However, achieving precise control over MOF coordination structures to optimize facet‐dependent properties remains challenging. Here, a facile scalable dual‐solvent synthesis strategy is presented fabricate dendrite Co‐2‐methylimidazole (ZIF‐67‐D), enabling tailored preferred facet environments. Using density functional theory (DFT) calculations synchrotron‐based X‐ray absorption spectroscopy, it demonstrated that ZIF‐67‐D, enriched (112) facets, features reduced Co number enhanced electron‐donating ability compared the conventionally (011) facet‐dominated rhombic dodecahedron ZIF‐67 (ZIF‐67‐R). This engineering boosts TENG charge by 2.4‐fold, OER current 9.9‐fold (@1.65 V), HER 1.9‐fold (@‐0.3 V). The (112)/(011) ratio can be also tuned precisely alter output. Moreover, optimized ZIF‐67‐D shows excellent stability, maintaining electrolyzer performance 72 h devices even in high humidity. Consequently, ZIF‐67‐D‐based (D‐TENG) exhibit robust energy generation power ZIF‐67‐D||ZIF‐67‐D electrolyzers continuous hydrogen (H 2 ) production. These findings introduce new paradigm converting mechanical into sustainable energy, offering insights high‐performance harvesting systems.
Language: Английский
Citations
1Advanced Functional Materials, Journal Year: 2024, Volume and Issue: unknown
Published: Dec. 29, 2024
Abstract Triboelectric nanogenerators (TENGs) represent an effective approach for transforming mechanical energy into electrical power, making them suitable wearable electronic applications. Hydrogels as TENGs electrodes are common, but their use direct triboelectric layers remains insufficiently explored. Here, a novel zwitterionic monomer 3‐{1‐[6‐(hydroxymethyl)‐2‐methyl‐3,8‐dioxo‐9‐aza‐4,7‐dioxadodec‐1‐en‐12‐yl]imidazol‐3‐ium‐3‐yl}propane‐1‐sulfonate (VNIPS) is synthesized in combination with acrylic acid (AA) and sulfobetaine methacrylate (SBMA) to create double‐network hydrogel. The hydrogel developed using solvent‐exchange process that facilitated the creation of microphase‐separated domains, notablely increasing its strength (211.9 kPa, 472.3%), conductivity (0.6 mS cm −1 ), anti‐freezing capability (−18.3 °C). In addition, hydrogel's hydrophilic groups interacted water molecules, reducing charge loss humid conditions. When employed positive layer, hydrogel‐based achieved substantial density 456 µC m − 2 output power 464 mW , while maintaining steady open‐circuit voltage (V oc ) 97 V, 92% retention under 80% relative humidity. Moreover, strong adhesion biocompatibility make it applications, such motion sensing Morse code communication. This work demonstrates feasibility hydrogels materials, providing new strategy creating efficient, humidity‐resistant harvesters.
Language: Английский
Citations
7ACS Applied Polymer Materials, Journal Year: 2025, Volume and Issue: unknown
Published: Jan. 28, 2025
Language: Английский
Citations
0Small, Journal Year: 2025, Volume and Issue: unknown
Published: Feb. 3, 2025
Abstract Environmental‐friendly aqueous Zn−CO 2 batteries present bifunctional potentials of achieving carbon neutrality and energy storage. Nonetheless, anode corrosions derived from H O molecules high risks volatilization leakage hinder the advancement batteries. In this work, polyvinyl alcohol (PVA)‐based hydrogel electrolyte with fast ion diffusion kinetics, mechanical strength, flexibility is developed to replace liquid electrolyte. Since hydroxyl radicals in polymer chain can interact Zn 2+ , electrode corrosion free active around significantly inhibited, facilitating uniform deposition cations. The introduction an ionic plasticizer further enhances interaction between backbone, as well amorphous extent possesses adequate self‐healing ability, whose conductivity reaches 7.95 × 10 −3 S cm −1 . symmetric metal containing remain steady for >2000 h under different current densities. Furthermore, battery based on Ru nanoparticles cathode realizes a discharge capacity 6028 mAh g stable cyclicity 90 times. reaction path electrolyte‐based that CO reduced ZnCO 3 C species followed by reversible decomposition products recharge.
Language: Английский
Citations
0Polymer, Journal Year: 2025, Volume and Issue: unknown, P. 128143 - 128143
Published: Feb. 1, 2025
Language: Английский
Citations
0Polymer, Journal Year: 2025, Volume and Issue: unknown, P. 128242 - 128242
Published: March 1, 2025
Language: Английский
Citations
0