In Situ Design of Metal‐Phenolic Networks Coated Layered Double Hydroxides S‐Scheme Photothermal Nanoreactor for Highly Efficient CO₂ Reduction

Advanced Functional Materials, Journal Year: 2025, Volume and Issue: unknown

Published: Feb. 28, 2025

Abstract Light‐driven conversion of CO 2 to fuel is the most attractive approach achieve global carbon neutrality. However, severe recombination photogenerated carriers and narrow range solar spectrum utilization make its application still challenging. Here, a metal‐phenolic networks (MPNs) coated layered double hydroxide S‐scheme photothermal nanoreactor (CoAl‐LDH @ TA‐Cu‐6 nm) designed. It can efficiently capture infrared light surprising 23‐fold performance improvement over CoAl‐LDH under simulated sunlight illumination. A variety in situ characterizations (in XPS DRIFTS) DFT calculations explore that fascinating comes from efficient charge separation migration catalysts, properties endowed by creatively introduced MPNs nanoscale pseudo‐greenhouse effect brought about ingenious coating structure. This work provides new insights into integration micromorphology electronic state modification (defect heterojunction engineering) broad spectrally responsive photocatalytic design reveals mechanism for synergistically enhancing activity at nano‐, atomic‐, subatomic‐scales, giving golden key address energy crisis environmental challenges.

Language: Английский

Aggregation-Induced Equidistant Dual Pt Atom Pairs for Effective CO₂ Photoreduction to C₂H₄

ACS Catalysis, Journal Year: 2025, Volume and Issue: unknown, P. 5614 - 5622

Published: March 21, 2025

Language: Английский

Effective photocatalytic antibacterial of Bi2WO6/Bi4O5I2 driven by visible light

Ceramics International, Journal Year: 2025, Volume and Issue: unknown

Published: April 1, 2025

Language: Английский