Metal Electrocatalysts for Hydrogen Production in Water Splitting DOI Creative Commons
Amir Kazemi, Faranak Manteghi, Zari Tehrani

et al.

ACS Omega, Journal Year: 2024, Volume and Issue: unknown

Published: Jan. 29, 2024

The rising demand for fossil fuels and the resulting pollution have raised environmental concerns about energy production. Undoubtedly, hydrogen is best candidate producing clean sustainable now in future. Water splitting a promising efficient process production, where catalysts play key role evolution reaction (HER). HER electrocatalysis can be well performed by Pt with low overpotential close to zero Tafel slope of 30 mV dec–1. However, main challenge expanding production using inexpensive catalysts. Due electrocatalytic activity electrochemical stability, transition metal compounds are options electrocatalysts. This study will focus on analyzing current situation recent advances design development nanostructured electrocatalysts noble non-noble metals electrocatalysis. In general, strategies including doping, crystallization control, structural engineering, carbon nanomaterials, increasing active sites changing morphology helpful improve performance. Finally, challenges future perspectives designing functional stable from water-splitting electrolysis described.

Language: Английский

A review: Synthesis, modification and photocatalytic applications of ZnIn2S4 DOI
Jie Wang, Sijia Sun, Run Zhou

et al.

Journal of Material Science and Technology, Journal Year: 2020, Volume and Issue: 78, P. 1 - 19

Published: Nov. 14, 2020

Language: Английский

Citations

268

Freestanding Metal–Organic Frameworks and Their Derivatives: An Emerging Platform for Electrochemical Energy Storage and Conversion DOI Creative Commons
Bing He, Qichong Zhang, Zhenghui Pan

et al.

Chemical Reviews, Journal Year: 2022, Volume and Issue: 122(11), P. 10087 - 10125

Published: April 21, 2022

Metal–organic frameworks (MOFs) have recently emerged as ideal electrode materials and precursors for electrochemical energy storage conversion (EESC) owing to their large specific surface areas, highly tunable porosities, abundant active sites, diversified choices of metal nodes organic linkers. Both MOF-based MOF-derived in powder form been widely investigated relation synthesis methods, structure morphology controls, performance advantages targeted applications. However, engage them applications, both binders additives would be required postprocessed electrodes, fundamentally eliminating some the sites thus degrading superior effects MOF-based/derived materials. The advancement freestanding electrodes provides a new promising platform EESC thanks apparent merits, including fast electron/charge transmission seamless contact between current collectors. Benefiting from synergistic effect structures materials, outstanding can achieved, stimulating increasing enthusiasm recent years. This review timely comprehensive overview on structural features fabrication techniques electrodes. Then, latest advances are summarized devices electrocatalysis. Finally, insights into currently faced challenges further perspectives these feasible solutions discussed, aiming at providing set guidance promote development scale-up production commercial

Language: Английский

Citations

255

Direct synthesis of metastable phases of 2D transition metal dichalcogenides DOI Creative Commons
Maria S. Sokolikova, Cecilia Mattevi

Chemical Society Reviews, Journal Year: 2020, Volume and Issue: 49(12), P. 3952 - 3980

Published: Jan. 1, 2020

The different polymorphic phases of transition metal dichalcogenides (TMDs) have attracted enormous interest in the last decade. metastable metallic and small band gap group VI TMDs displayed leading performance for electrocatalytic hydrogen evolution, high volumetric capacitance some them exhibit large quantum spin Hall (QSH) insulating behaviour. Metastable 1T(1T') require higher formation energy, as compared to thermodynamically stable 2H phase, thus standard chemical vapour deposition transport processes materials normally grow phases. Only destabilization their phase via external means, such charge transfer or electric field, allows conversion crystal structure into phase. Bottom-up synthesis measurable quantities would broaden prospective applications practical utilization. There is an emerging evidence that these can be directly synthesized bottom-up vapour- liquid-phase methods. This review will provide overview strategies which been designed achieve control TMDs, mechanisms drive We a critical comparison between growth pathways techniques. Morphological characteristics described along with ability act electrocatalysts evolution reaction from water. Phase stability reversibility discussed new potential introduced. aims at providing insights fundamental understanding favourable synthetic conditions stabilization TMD crystals stimulating future advancements field large-scale control.

Language: Английский

Citations

196

Recent Advances on Electrolysis for Simultaneous Generation of Valuable Chemicals at both Anode and Cathode DOI
Rui Li, Kun Xiang, Zhikun Peng

et al.

Advanced Energy Materials, Journal Year: 2021, Volume and Issue: 11(46)

Published: Nov. 6, 2021

Abstract To make efficient use of electrical energy in the whole electrocatalysis conversion process, integrating anode and cathode reactions plays a vital role. The combination electrocatalytic anodic oxidation with cathodic reduction can not only maximize return investment, but also produces value‐added materials on both sides. Herein, this review, recent advances co‐electrolysis processes for valuable chemical production are systematically summarized. be more specific, popular hydrogen evolution reaction, carbon dioxide nitrogen reaction as well nitrate integrated to products, respectively comprehensively reviewed, then other paired electrolysis systems (especially biomass‐based compounds) toward high‐value‐added generation discussed detail. This review sheds light integration reductions develop high‐value substances. benefit researchers facilitate progress field, challenges future prospects these proposed.

Language: Английский

Citations

196

Interfacial electronic structure modulation of Pt-MoS2 heterostructure for enhancing electrocatalytic hydrogen evolution reaction DOI

Aixian Shan,

Xueai Teng,

Yu Zhang

et al.

Nano Energy, Journal Year: 2022, Volume and Issue: 94, P. 106913 - 106913

Published: Jan. 3, 2022

Language: Английский

Citations

195

Recent Advances on Transition Metal Dichalcogenides for Electrochemical Energy Conversion DOI
Xin Wu, Huabin Zhang, Jian Zhang

et al.

Advanced Materials, Journal Year: 2021, Volume and Issue: 33(38)

Published: Aug. 18, 2021

Abstract Transition metal dichalcogenides (TMDCs) hold great promise for electrochemical energy conversion technologies in view of their unique structural features associated with the layered structure and ultrathin thickness. Because inert basal plane accounts majority a TMDC's bulk, activation sites is necessary to fully exploit intrinsic potential TMDCs. Here, recent advances on TMDCs‐based hybrids/composites greatly enhanced activity are reviewed. After summary synthesis TMDCs different sizes morphologies, comprehensive in‐plane strategies described detail, mainly including in‐plane‐modification‐induced phase transformation, surface‐layer modulation, interlayer modification/coupling. Simultaneously, underlying mechanisms improved activities highlighted. Finally, strategic evaluation further research directions featured. This work would shed some light future design trends functional materials energy‐related applications.

Language: Английский

Citations

172

A general approach to the synthesis of transition metal phosphide nanoarrays on MXene nanosheets for pH-universal hydrogen evolution and alkaline overall water splitting DOI
Yan Liang, Bing Zhang, Shangyou Wu

et al.

Journal of Materials Chemistry A, Journal Year: 2020, Volume and Issue: 8(28), P. 14234 - 14242

Published: Jan. 1, 2020

Exploring highly efficient, stable, and non-noble-metal bifunctional electrocatalysts for overall water splitting is greatly desired but still remains an ongoing challenge.

Language: Английский

Citations

171

2D Transition Metal Dichalcogenides‐Based Electrocatalysts for Hydrogen Evolution Reaction DOI Creative Commons
Aniruddha Mondal, Alberto Vomiero

Advanced Functional Materials, Journal Year: 2022, Volume and Issue: 32(52)

Published: Oct. 30, 2022

Abstract Hydrogen is an efficient, clean, and economical energy source, owing to its huge density. Electrochemical water splitting a potential candidate for inexpensive eco‐friendly hydrogen production. Recently, the development of 2D transition metal chalcogenides (TMDs) nanomaterials with variety physicochemical properties has shown their as eminent non‐noble metal‐based nanoscale electrocatalysts evolution. Nanostructuring such materials induces deep modification functionalities, compared bulk counterparts. High density different types exposed active sites formed, small diffusion paths, which enhances electron transfer in structures, can successfully aid charge collection process electrocatalytic evolution reactions. In this review, key parameters improve catalyst performance TMDs electrochemical reaction (HER) processes are discussed detail most recent developments field summarized, focusing on improvement activity TMDs. This review delivers insight clear understanding HER, suggesting new type efficient HER well other renewable fields.

Language: Английский

Citations

160

Nature-inspired 3D hierarchical structured “vine” for efficient microwave attenuation and electromagnetic energy conversion device DOI
Qiangqiang Wang, Ben Niu, Yuhang Han

et al.

Chemical Engineering Journal, Journal Year: 2022, Volume and Issue: 452, P. 139042 - 139042

Published: Sept. 5, 2022

Language: Английский

Citations

150

Edge-oriented, high-percentage 1T′-phase MoS2 nanosheets stabilize Ti3C2 MXene for efficient electrocatalytic hydrogen evolution DOI
Xitao Li,

Xinding Lv,

Xiangnan Sun

et al.

Applied Catalysis B Environment and Energy, Journal Year: 2020, Volume and Issue: 284, P. 119708 - 119708

Published: Nov. 21, 2020

Language: Английский

Citations

147