Carbon‐based anode materials for potassium‐ion batteries: From material, mechanism to performance DOI

Jinhui Zhou,

Shaojun Guo

SmartMat, Journal Year: 2021, Volume and Issue: 2(2), P. 176 - 201

Published: June 11, 2021

Abstract Potassium‐ion batteries (PIBs) show great potential in the application of large‐scale energy storage devices due to comparable high operating voltage with lithium‐ion and lower cost. Carbon‐based materials are promising candidates as anodes for PIBs, their low cost, abundance, nontoxicity, environmental benignity, sustainability. In this review, we will first discuss potassium mechanisms graphitic defective carbon carbon‐based composites various compositions microstructures comprehensively understand behavior. Then, several strategies based on heteroatoms doping, unique nanostructure design, introduction conductive matrix form proposed optimize achieve performance PIBs. Finally, conclude existing challenges perspectives further development materials, which is believed promote practical PIBs future.

Language: Английский

Unveiling Superior Capacitive Behaviors of One‐Pot Molten Salt‐Engineered B, N Co‐Doped Porous Carbon Sheets DOI
Huichao Liu, Sheng Zhu, Yuxin Zhang

et al.

Small, Journal Year: 2023, Volume and Issue: 19(40)

Published: May 31, 2023

Abstract Heteroatom‐doped porous carbon materials with distinctive surface properties and capacitive behavior have been accepted as promising candidates for supercapacitor electrodes. Currently, the researches mainly focus on developing facile synthetic method unveiling structure‐activity relationship to further elevate their performance. Here, B, N co‐doped sheet (BN‐PCS) is constructed by one‐pot pyrolysis of agar in KCl/KHCO 3 molten salt system. In this process, urea acts directing agent guide formation 2D morphology, decomposition KHCO boric acid creates rich micro‐ mesopores framework. The specific capacitance optimized BN‐PCS reaches 361.1 F g −1 at a current density 0.5 A an aqueous KOH electrolyte. Impressively, fabricated symmetrical affords maximum energy 43.5 Wh kg power 375.0 W 1.0 mol L TEABF 4 /AN It also achieves excellent long‐term stability retention 91.1% Columbic efficiency 100% over 10 000 cycles. This study indicates effective engineering advanced high‐performance storage devices.

Language: Английский

Citations

53
Dual Activation for Tuning N, S Co‐Doping in Porous Carbon Sheets Toward Superior Sodium Ion Storage DOI
Dingyue Zhang, Hao Zhang, Fan Gao

et al.

Small, Journal Year: 2024, Volume and Issue: 20(24)

Published: Jan. 4, 2024

Abstract Porous carbon has been widely focused to solve the problems of low coulombic efficiency (ICE) and multiplication capacity Sodium‐ion batteries (SIBs) anodes. The superior energy storage properties two‐dimensional(2D) nanosheets can be realized by modulating structure, but limited sources, making it challenging obtain 2D structures with large surface area. In this work, a new method for forming materials high N/S doping content based on combustion activation using dual effect K 2 SO 4 /KNO 3 is proposed. synthesized material as an anode SIBs reversible 344.44 mAh g −1 at 0.05 A . Even current density 5 Ag , remained 143.08 And ICE sodium‐ion in ether electrolytes ≈2.5 times higher than that ester electrolytes. sodium mechanism ether/ester‐based further explored through ex‐situ characterizations. disparity electrochemical performance ascribed discrepancy kinetics, wherein ether‐based exhibit rate Na + shedding compared ester‐based This work suggests effective way develop doubly doped SIBs.

Language: Английский

Citations

36
Recent progress on carbon materials for emerging zinc-ion hybrid capacitors DOI Creative Commons

Lai Yu,

Jie Li, Nazir Ahmad

et al.

Journal of Materials Chemistry A, Journal Year: 2024, Volume and Issue: 12(16), P. 9400 - 9420

Published: Jan. 1, 2024

The fundamental and research progress on carbon materials for zinc ion hybrid capacitors (ZHCs) is systematically summarized. existing challenges perspectives are also proposed to promote the practical applications of high-performance ZHCs.

Language: Английский

Citations

26
Regulating the coordination microenvironment of atomic bismuth sites in nitrogen-rich carbon nanosheets as anode for superior potassium-ion batteries DOI

Y. P. Tan,

Haoxiang Lin, Zhisong Chen

et al.

Journal of Energy Chemistry, Journal Year: 2024, Volume and Issue: 99, P. 365 - 374

Published: Aug. 6, 2024

Language: Английский

Citations

21
N/B co-doped porous carbon with superior specific surface area derived from activation of biomass waste by novel deep eutectic solvents for Zn-ion hybrid supercapacitors DOI
Daohai Zhang, Xiao Zhan, Teng Zhou

et al.

Journal of Material Science and Technology, Journal Year: 2024, Volume and Issue: 193, P. 22 - 28

Published: Feb. 4, 2024

Language: Английский

Citations

20
Biomimetic-Mineralization-Assisted Self-Activation Creates a Delicate Porous Structure in Carbon Material for High-Rate Sodium Storage DOI
Hao Zhang, Gang Huang, Longbo Luo

et al.

ACS Applied Materials & Interfaces, Journal Year: 2024, Volume and Issue: unknown

Published: April 26, 2024

Porous carbons have shown their potential in sodium-ion batteries (SIBs), but the undesirable initial Coulombic efficiency (ICE) and rate capability hinder practical application. Herein, learning from nature, we report an efficient method for fabricating a carbon framework (CK) with delicate porous structural regulation by biomimetic mineralization-assisted self-activation. The abundant pores defects of CK anode can improve ICE performance SIBs ether-based electrolytes, whereas they are confined carbonate ester-based electrolytes. Notably, electrolytes enable to possess excellent (82.9%) high-rate (111.2 mAh g-1 at 50 A g-1). Even after 5500 cycles large current density 10 g-1, capacity retention still be maintained 73.1%. More importantly, full cell consisting Na3V2(PO4)3 cathode delivers high energy 204.4 Wh kg-1, power 2828.2 W kg-1. Such outstanding is attributed (1) hierarchical pores, oxygen doping, that pave way transportation storage Na+, further enhancing ICE; (2) high-proportion NaF-based solid-electrolyte-interphase (SEI) layer facilitates Na+ kinetics electrolytes; (3) determine dominate SIBs. These results provide compelling evidence promising our synthetic strategy development carbon-based materials electrochemical storage.

Language: Английский

Citations

18
Transforming lignin into functionalized B/N co-doped porous carbon for high-performance zinc-ion hybrid capacitors DOI

Tianqi Cao,

Wei Li,

Jiarui Zhu

et al.

Energy Conversion and Management, Journal Year: 2025, Volume and Issue: 326, P. 119498 - 119498

Published: Jan. 21, 2025

Language: Английский

Citations

2
Ultrafast Potassium Storage in F-Induced Ultra-High Edge-Defective Carbon Nanosheets DOI
Yu Jiang, Yang Yang, Rui Xu

et al.

ACS Nano, Journal Year: 2021, Volume and Issue: 15(6), P. 10217 - 10227

Published: May 26, 2021

Carbonaceous materials have been considered as promising anodes for potassium-ion batteries (PIBs) because of their high electronic conductivity, eco-friendliness, and structural stability. However, the small interlayer spacing serious volume expansion caused by repeated insertion/extraction large K-ions restrict storage performance. Herein, F N codoped carbon nanosheets (FNCS) with rich-edge defects are designed to resolve these problems. The doping is in favor formation more edge layer, offering strong K+ adsorption capability promoting storage. ultrathin can provide a contact area electrochemical reactions shorten transportation pathways both electrons. Consequently, FNCS anode shows reversible capacity (610 mAh g–1 at 0.1 A g–1) ultrastable cyclability over 4000 cycles 5 g–1. Moreover, K-ion full cells (FNCS|K2FeFe(CN)6) display excellent cycling stability (128 1 after 500 cycles) rate (93 20 g–1). This design strategy be extended other electrode high-performance energy storage, such magnesium-ion batteries, supercapacitors, electrocatalysis.

Language: Английский

Citations

100
Perspective on Carbon Anode Materials for K+ Storage: Balancing the Intercalation‐Controlled and Surface‐Driven Behavior DOI
Jiaying Yang,

Yixuan Zhai,

Xiuhai Zhang

et al.

Advanced Energy Materials, Journal Year: 2021, Volume and Issue: 11(29)

Published: June 12, 2021

Abstract Potassium‐ion batteries (PIBs) have emerged as a compelling complement to existing lithium‐ion for large‐scale energy storage applications, due the resource‐abundance of potassium, low standard redox potential and high conductivity K + ‐based electrolytes. Rapid progress has been made in identifying suitable carbon anode materials address sluggish kinetics huge volume variation problems caused by large‐size . However, most research into focused on structural design performance optimization one or several parameters, rather than considering holistic especially realistic applications. This perspective examines recent efforts enhance terms initial Coulombic efficiency, capacity, rate capability, cycle life. The balancing intercalation surface‐driven capacitive mechanisms while designing structures is emphasized, after which compatibility with electrolyte cell assembly technologies should be considered under practical conditions. It anticipated that this work will engender further intensive can better aligned toward implementation storage.

Language: Английский

Citations

80
Water‐Soluble Salt Template‐Assisted Anchor of Hollow FeS2 Nanoparticle Inside 3D Carbon Skeleton to Achieve Fast Potassium‐Ion Storage DOI
Yongpeng Cui, Wenting Feng, Dandan Wang

et al.

Advanced Energy Materials, Journal Year: 2021, Volume and Issue: 11(33)

Published: July 2, 2021

Abstract The rationally structural engineering is an efficient strategy to improve the comprehensive performance of potassium‐ion storage anode materials. In this paper, a hybrid with hollow FeS 2 nanoparticles anchored into 3D carbon skeleton (labeled as H‐FeS @3DCS) successfully constructed through two critical steps in situ chemical deposition and anion‐exchange reaction strategies. former, water‐soluble Na CO 3 crystals are used hard templates for preparation 3DCS, while Fe 3+ ‐containing aqueous solutions utilized remove templates. Interestingly, intense collision between 2‐ solution produces nanoscale Fe(OH) colloidal particles, which firmly pores form “lotus‐seed”‐like nanostructure. latter case, central void space created inside due different diffusion rates S‐anions Fe‐cations during subsequent sulfidation process. Thanks unique composition model, @3DCS not only alleviates volume expansion efficiently by structure design, but also provides spacious “roads” (3D skeleton) “houses” (hollow nanoparticles) fast K‐ion transition storage. As PIBs PIHCs, resultant electrode delivers obviously enhanced K‐ions over state‐of‐the‐art.

Language: Английский

Citations

78