Energy & Environmental Science,
Journal Year:
2023,
Volume and Issue:
16(10), P. 4670 - 4678
Published: Jan. 1, 2023
An
operando
DIC-based
technique
is
developed
to
analyze
the
strain
and
partial
molar
volume
of
Zn
2+
in
combination
with
an
electrochemical–mechanical
coupling
model,
which
provides
fundamental
explanations
for
enhanced
cycling
stability
AZIBs.
Chemical Science,
Journal Year:
2023,
Volume and Issue:
14(46), P. 13346 - 13366
Published: Jan. 1, 2023
Aqueous
zinc
ion
batteries
(AZIBs)
are
regarded
as
one
of
the
most
promising
large-scale
energy
storage
systems
because
their
considerable
density
and
intrinsic
safety.
Nonetheless,
severe
dendrite
growth
Zn
anode,
serious
degradation
cathode,
boundedness
separators
restrict
application
AZIBs.
Fortunately,
electrospinning
nanofibers
demonstrate
huge
potential
bright
prospects
in
constructing
AZIBs
with
excellent
electrochemical
performance
due
to
controllable
nanostructure,
high
conductivity,
large
specific
surface
area
(SSA).
In
this
review,
we
first
briefly
introduce
principles
processing
technique
structure
design
electrospun
fibers
Then,
summarize
recent
advances
AZIBs,
including
cathodes,
anodes,
separators,
highlighting
nanofibers'
working
mechanism
correlations
between
electrode
performance.
Finally,
based
on
insightful
understanding,
for
high-performance
also
presented.
Angewandte Chemie International Edition,
Journal Year:
2024,
Volume and Issue:
63(23)
Published: April 2, 2024
The
extensively
studied
Prussian
blue
analogs
(PBAs)
in
various
batteries
are
limited
by
their
low
discharge
capacity,
or
subpar
rate
etc.,
which
solely
reliant
on
the
cation
(de)intercalation
mechanism.
In
contrast
to
currently
predominant
focus
cations,
we
report
overlooked
anion-cation
competition
chemistry
(Cl
Energy & Environmental Science,
Journal Year:
2023,
Volume and Issue:
16(10), P. 4670 - 4678
Published: Jan. 1, 2023
An
operando
DIC-based
technique
is
developed
to
analyze
the
strain
and
partial
molar
volume
of
Zn
2+
in
combination
with
an
electrochemical–mechanical
coupling
model,
which
provides
fundamental
explanations
for
enhanced
cycling
stability
AZIBs.