2D/2D g-C3N4@BiOI S-scheme heterojunction with gas-liquid-solid triphase interface for highly efficient CO2 photoreduction DOI
Chao Yang, Qing‐He Zhang, Wang Wang

et al.

Science China Materials, Journal Year: 2024, Volume and Issue: 67(6), P. 1830 - 1838

Published: April 28, 2024

Language: Английский

Hydroxyl-Bonded Ru on Metallic TiN Surface Catalyzing CO2 Reduction with H2O by Infrared Light DOI

Bo Su,

Yuehua Kong, Sibo Wang

et al.

Journal of the American Chemical Society, Journal Year: 2023, Volume and Issue: 145(50), P. 27415 - 27423

Published: Dec. 11, 2023

Synchronized conversion of CO2 and H2O into hydrocarbons oxygen via infrared-ignited photocatalysis remains a challenge. Herein, the hydroxyl-coordinated single-site Ru is anchored precisely on metallic TiN surface by NaBH4/NaOH reforming method to construct an infrared-responsive HO-Ru/TiN photocatalyst. Aberration-corrected high-angle annular dark-field scanning transmission electron microscopy (ac-HAADF-STEM) X-ray absorption spectroscopy (XAS) confirm atomic distribution species. XAS density functional theory (DFT) calculations unveil formation HO-RuN5-Ti Lewis pair sites, which achieves efficient polarization/activation dual coordination with C O atoms HO-Ru/TiN. Also, implanting species powerfully boosts separation transfer photoinduced charges. Under infrared irradiation, catalyst shows superior CO2-to-CO transformation activity coupled oxidation release O2, reduction rate can further be promoted about 3-fold under simulated sunlight. With key reaction intermediates determined in situ diffuse reflectance Fourier transform (DRIFTS) predicted DFT simulations, possible photoredox mechanism system proposed.

Language: Английский

Citations

183
S-scheme heterojunction of crystalline carbon nitride nanosheets and ultrafine WO3 nanoparticles for photocatalytic CO2 reduction DOI

Gongjie Chen,

Ziruo Zhou,

Bifang Li

et al.

Journal of Environmental Sciences, Journal Year: 2023, Volume and Issue: 140, P. 103 - 112

Published: May 30, 2023

Language: Английский

Citations

142
Carbon quantum dots-modified tetra (4-carboxyphenyl) porphyrin/BiOBr S-scheme heterojunction for efficient photocatalytic antibiotic degradation DOI Open Access
Chunchun Wang,

Ke Rong,

Yan Liu

et al.

Science China Materials, Journal Year: 2024, Volume and Issue: 67(2), P. 562 - 572

Published: Jan. 23, 2024

Language: Английский

Citations

112
Metal Sulfide S‐Scheme Homojunction for Photocatalytic Selective Phenylcarbinol Oxidation DOI Creative Commons
Huijun Zhang, Yu‐Jie Gao, Sugang Meng

et al.

Advanced Science, Journal Year: 2024, Volume and Issue: 11(17)

Published: Feb. 28, 2024

Abstract Metal sulfide‐based homojunction photocatalysts are extensively explored with improved photocatalytic performance. However, the construction of metal S‐scheme remains a challenge. Herein, fabrication 2D CdIn 2 S 4 nanosheets coated 3D octahedra (referred to as 2D/3D n‐CIS/o‐CIS) photocatalyst is reported by simply adjustment polyvinyl pyrrolidone amount during solvothermal synthesis. The formation within n‐CIS/o‐CIS systematically investigated via series characterizations, which can generate an internal electric field facilitate separation and migration photogenerated electron‐hole pairs. composite exhibits significantly activity stability in selective oxidation phenylcarbinol (PhCH OH) benzaldehyde (PhCHO) when compared pure n‐CIS o‐CIS samples under visible light irradiation. It hoped that this work contribute novel insights into development sulfides for solar energy conversion.

Language: Английский

Citations

95
Twin S-Scheme g-C3N4/CuFe2O4/ZnIn2S4 Heterojunction with a Self-Supporting Three-Phase System for Photocatalytic CO2 Reduction: Mechanism Insight and DFT Calculations DOI
Dongdong Liu, Lipeng Jiang, Dengqian Chen

et al.

ACS Catalysis, Journal Year: 2024, Volume and Issue: 14(7), P. 5326 - 5343

Published: March 26, 2024

The use of photocatalytic solar energy to drive CO2 reduction is beneficial for addressing fossil fuel shortages and environmental pollution issues. We synthesized a twin S-scheme g-C3N4/CuFe2O4/ZnIn2S4 heterojunction, which was used construct self-supporting three-phase system reduction. Two built-in electric fields in this heterojunction induced effective migration photogenerated carriers, resulting wide light response range strong oxidation ability. This without sacrificial agent had high CH4 selectivity (96.8%) surprise production rate (267.4 μmol g–1 h–1), still maintained an excellent cycle (249–267.4 h–1) during five cycles. In addition, possessed both hydrophilicity hydrophobicity, achieved efficient transformation into by controlling interface wettability. g-C3N4 as hydrophobic layer promoted mass transfer achieve the enrichment on surface; ZnIn2S4 hydrophilic could well adsorb H2O, further oxidized holes many protons (H+). Finally, DFT calculations found that Fe–N bonds located between CuFe2O4 played crucial role They served bridge electron induce bending adsorption CO2, enhanced *CO stabilization *H.

Language: Английский

Citations

76
Defect and nanostructure engineering of polymeric carbon nitride for visible-light-driven CO2 reduction DOI

Ziruo Zhou,

Wenyu Guo,

Tingyu Yang

et al.

Chinese Journal of Structural Chemistry, Journal Year: 2024, Volume and Issue: 43(3), P. 100245 - 100245

Published: Feb. 5, 2024

Language: Английский

Citations

69
Rational design of Ag/CuO@ZnIn2S4 S-scheme plasmonic photocatalyst for highly selective CO2 conversion DOI
Yining Zhang, Jinze Li, Weiqiang Zhou

et al.

Applied Catalysis B Environment and Energy, Journal Year: 2023, Volume and Issue: 342, P. 123449 - 123449

Published: Oct. 30, 2023

Language: Английский

Citations

57
TiO2-based S-scheme photocatalysts for solar energy conversion and environmental remediation DOI Open Access

Baolong Zhang,

Bin Sun,

Fangxuan Liu

et al.

Science China Materials, Journal Year: 2024, Volume and Issue: 67(2), P. 424 - 443

Published: Jan. 23, 2024

Language: Английский

Citations

57
Atomic-level surface modification of ultrathin Bi2WO6 nanosheets for boosting photocatalytic CO2 reduction DOI
Lulu Zhao, Huilin Hou, Lin Wang

et al.

Chemical Engineering Journal, Journal Year: 2023, Volume and Issue: 480, P. 148033 - 148033

Published: Dec. 14, 2023

Language: Английский

Citations

56
2D semiconductor nanosheets for solar photocatalysis DOI Creative Commons
Cai Meng,

Yixin Wei,

Yukun Li

et al.

EcoEnergy, Journal Year: 2023, Volume and Issue: 1(2), P. 248 - 295

Published: Dec. 1, 2023

Abstract In the advancing world of graphene, highly anisotropic 2D semiconductor nanosheets, notable for their nanometer‐scale thickness, have emerged as a leading innovation, displaying immense potential in exploration renewable and clean energy production. These garnered significant attention from researchers. The nanosheets are marked by extraordinary electronic, optical, chemical attributes, positioning them attractive foundational components heterogeneous photocatalysts. This review diligently summarizes both seminal work ongoing developments pertaining to application solar within context photocatalysis. We begin detailing distinctive properties concentrating on pivotal roles augmenting photocatalytic efficiency, explaining intrinsic mechanisms that govern migration rate photogenerated carriers material's surface. Subsequently, we delineate methods employed synthesize typical nanosheets. alignment with overarching objective expanding light absorption capacity accelerating charge transfer, also examine current research hybridization techniques involving materials varied dimensions, well deployment diverse applications. conclude identifying promising avenues challenges await further this burgeoning field.

Language: Английский

Citations

55