Steering Geometric Reconstruction of Bismuth with Accelerated Dynamics for CO2 Electroreduction DOI
Xiaowen Wang, Yangyang Zhang,

Shao Wang

et al.

Angewandte Chemie, Journal Year: 2024, Volume and Issue: 136(34)

Published: June 5, 2024

Abstract Bismuth‐based materials have emerged as promising catalysts in the electrocatalytic reduction of CO 2 to formate. However, reasons for reconstruction Bi‐based precursors form bismuth nanosheets are still puzzling, especially formation defective sites. Herein, we prepare with vacancy‐rich defects (V‐Bi NS) by rapidly reconstructing Bi 19 Cl 3 S 27 under negative potential. Theoretical analysis reveals that introduction chlorine induces generation intrinsic electric field precursor, thereby increasing electron transfer rate and further promoting metallization trivalent bismuth. Meanwhile, experimental tests verify has a faster than . The formed V‐Bi NS exhibits up 96 % HCOO − Faraday efficiency 400 mA cm −2 partial current densities, its electrochemical active surface area normalized formate density yield 2.2 times higher those intact (I‐Bi NS). Density functional theory calculations indicate vacancies electron‐rich aggregation reduce activation energy *CO radicals stabilize adsorption key intermediate *OCHO, thus facilitating reaction kinetics production.

Language: Английский

Electrochemical reduction of carbon dioxide to multicarbon (C2+) products: challenges and perspectives DOI Creative Commons
Bin Chang, Hong Pang,

Fazal Raziq

et al.

Energy & Environmental Science, Journal Year: 2023, Volume and Issue: 16(11), P. 4714 - 4758

Published: Jan. 1, 2023

This review analyzes advanced catalysts and C 2+ synthesis mechanisms based on theoretical explorations in situ / operando characterizations. Triphasic interface optimization is discussed for the potential of industry-compatible stability.

Language: Английский

Citations

170
Laser-controlled tandem catalytic sites of CuNi alloys with ampere-level electrocatalytic nitrate-to-ammonia reduction activities for Zn–nitrate batteries DOI

Wanqiang Yu,

Jiayuan Yu, Man Huang

et al.

Energy & Environmental Science, Journal Year: 2023, Volume and Issue: 16(7), P. 2991 - 3001

Published: Jan. 1, 2023

Laser-constructed CuNi alloy electrodes with tandem sites of Ni provide H* and Cu for NO 3 − reduction, achieving ampere-level reduction high-performance Zn–NO batteries.

Language: Английский

Citations

118
Nanoscale Engineering of P‐Block Metal‐Based Catalysts Toward Industrial‐Scale Electrochemical Reduction of CO2 DOI
Pengfei Li, Fangqi Yang, Jing Li

et al.

Advanced Energy Materials, Journal Year: 2023, Volume and Issue: 13(34)

Published: July 27, 2023

Abstract The efficient conversion of CO 2 to value‐added products represents one the most attractive solutions mitigate climate change and tackle associated environmental issues. In particular, electrochemical reduction fuels chemicals has garnered tremendous interest over last decades. Among all from reduction, formic acid is considered economically vital products. P‐block metals (especially Bi, Sn, In, Pb) have been extensively investigated recognized as catalytic materials for electroreduction formate. Despite remarkable progress, future implementation this technology at industrial‐scale hinges on ability solve remaining roadblocks. review, current research status, challenges, prospects p‐block metal‐based catalysts primarily formate are comprehensively reviewed. rational design nanostructure engineering these metal optimization their performances discussed in detail. Subsequently, recent progress development state‐of‐the‐art operando characterization techniques together with advanced cells uncover intrinsic catalysis mechanism discussed. Lastly, a perspective directions including tackling critical challenges realize its early industrial presented.

Language: Английский

Citations

45
Enhancing Local CO2 Adsorption by L‐histidine Incorporation for Selective Formate Production Over the Wide Potential Window DOI Open Access
Yicheng Li, Ernest Pahuyo Delmo, Guoyu Hou

et al.

Angewandte Chemie International Edition, Journal Year: 2023, Volume and Issue: 62(49)

Published: Oct. 19, 2023

Electrochemical carbon dioxide reduction reaction (CO2 RR) to produce valuable chemicals is a promising pathway alleviate the energy crisis and global warming issues. However, simultaneously achieving high Faradaic efficiency (FE) current densities of CO2 RR in wide potential range remains as huge challenge for practical implements. Herein, we demonstrate that incorporating bismuth-based (BH) catalysts with L-histidine, common amino acid molecule proteins, an effective strategy overcome inherent trade-off between activity selectivity. Benefiting from significantly enhanced adsorption capability promoted electron-rich nature by L-histidine integrity, BH catalyst exhibits excellent FEformate unprecedented windows (>90 % within -0.1--1.8 V >95 -0.2--1.6 versus reversible hydrogen electrode, RHE). Excellent performance can still be achieved under low-concentration feeding (e.g., 20 vol.%). Besides, extremely low onset -0.05 VRHE (close theoretical thermodynamic -0.02 ) was detected situ ultraviolet-visible (UV-Vis) measurements, together stable operation over 50 h preserved ≈95 partial density 326.2 mA cm-2 at -1.0 .

Language: Английский

Citations

45
Nb1-Zr dual active sites constructed on ZrO2 boost nitrite-to-ammonia electroreduction DOI

Wenyu Du,

Zeyi Sun,

Kai Chen

et al.

Chemical Engineering Journal, Journal Year: 2024, Volume and Issue: 481, P. 148733 - 148733

Published: Jan. 13, 2024

Language: Английский

Citations

33
A Sulfur‐Doped Copper Catalyst with Efficient Electrocatalytic Formate Generation during the Electrochemical Carbon Dioxide Reduction Reaction DOI Creative Commons
Yinuo Wang, Hongming Xu, Yushen Liu

et al.

Angewandte Chemie International Edition, Journal Year: 2024, Volume and Issue: 63(9)

Published: Jan. 8, 2024

Catalysts involving post-transition metals have shown almost invincible performance on generating formate in electrochemical CO

Language: Английский

Citations

25
Oxygen‐Pinned Ag1In Single‐Atom Alloy for Efficient Electroreduction CO2 to Formate DOI

Chaoqiong Fang,

Lijun Huang,

Wenqiang Gao

et al.

Advanced Energy Materials, Journal Year: 2024, Volume and Issue: 14(27)

Published: May 2, 2024

Abstract Catalytic conversion of CO 2 to valuable formate provides a pathway carbon neutrality. Indium (In), as promising catalyst, exhibits high selectivity toward due its suitable bonding ability *OCHO intermediates. However, it still suffers from the activation and protonation steps, leading low activity productivity. Here, an oxygen‐pinned stabilization AgIn single‐atom alloy (O p ‐Ag 1 In) is presented for efficiently converting into (≈92.03% Faradaic efficiency) with partial current density 13 mA cm −2 at −0.95 V vs RHE by using standard H‐type reactor. The O In electrocatalyst more effective in because activated sites catalyst regulate step RR formation sufficient amounts *OCHO, which are confirmed situ spectroscopic theoretical calculations. continuous production showcased 70 –2 24 h utilizing flow cell In.

Language: Английский

Citations

17
Advances in Sn-based oxide catalysts for the electroreduction of CO2 to formate DOI Creative Commons

Xiaoyue Tu,

Xiangjian Liu, Yu Zhang

et al.

Green Carbon, Journal Year: 2024, Volume and Issue: 2(2), P. 131 - 148

Published: April 17, 2024

The excessive consumption of fossil fuels increases CO2 emissions, and the consequent greenhouse effect resulting from higher levels this gas in atmosphere has a significant impact on environment climate. This necessitated development environmentally friendly efficient methods for conversion. carbon dioxide electroreduction reaction (CO2RR), which is driven by electricity generated renewable energy sources (e.g., wind solar) to convert into value-added or chemicals, regarded as promising prospective path toward cycling. Among various products, formate, with its relatively simple preparation process, broad application prospects, can be used fuel, hydrogen storage material, raw material downstream chemicals. Sn-based oxide electrocatalysts have advantages being inexpensive nontoxic. In addition, these catalysts offer high product selectivity are electrochemical reduction formate. review, we first clarify mechanisms factors that influence then provide some examples technologies could study evolution during reaction. particular, focus traditional oxides (SnO2) novel perovskite been developed use field CO2RR recent years considering their synthesis, catalytic performance, optimization strategies, intrinsic principles. Finally, current challenges opportunities discussed. perspectives latest trends presented review expected inspire researchers contribute more efforts comprehensively optimizing performance produce

Language: Английский

Citations

16
Urea Synthesis via Coelectrolysis of CO2 and Nitrate over Heterostructured Cu–Bi Catalysts DOI
Xinning Song, Xiaodong Ma, Tianhui Chen

et al.

Journal of the American Chemical Society, Journal Year: 2024, Volume and Issue: 146(37), P. 25813 - 25823

Published: Sept. 5, 2024

Electrocatalytic coupling of CO

Language: Английский

Citations

16
Engineering Atom‐Scale Cascade Catalysis via Multi‐Active Site Collaboration for Ampere‐Level CO2 Electroreduction to C2+ Products DOI Open Access
Cheng‐Hao Jin, Lin Yue, Yanan Wang

et al.

Advanced Materials, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 15, 2025

Electrochemical reduction of CO2 to value-added multicarbon (C2+) productions offers an attractive route for renewable energy storage and utilization, but it remains challenging achieve high C2+ selectivity at industrial-level current density. Herein, a Mo1Cu single-atom alloy (SAA) catalyst is reported that displays remarkable Faradaic efficiency 86.4% under 0.80 A cm-2. Furthermore, the partial density over reaches 1.33 cm-2 with surpasses 74.3%. The combination operando spectroscopy functional theory (DFT) indicates as-prepared SAA enables atom-scale cascade catalysis via multi-active site collaboration. introduced Mo sites promote H2O dissociation fabricate active *H, meanwhile, Cu (Cu0) far from atom are activation toward CO. Further, CO *H captured by adjacent (Cu&+) near atom, accelerating conversion C─C coupling process. Our findings benefit design tandem electrocatalysts atomic scale transforming products rate.

Language: Английский

Citations

3