Light-promoted synergy between CO2 adsorption sites and active oxygen leads to efficient photothermocatalytic dry reforming of methane on Ni/Ni-Sr-Al2O3 DOI

Wenhao Liao,

Lei Ji, Yuanzhi Li

et al.

Applied Surface Science, Journal Year: 2025, Volume and Issue: unknown, P. 163027 - 163027

Published: March 1, 2025

Language: Английский

Photon and phonon powered photothermal catalysis DOI
Chang Xu, Qijun Tang, Wenguang Tu

et al.

Energy & Environmental Science, Journal Year: 2024, Volume and Issue: 17(13), P. 4461 - 4480

Published: Jan. 1, 2024

Synergistic coupling of photons and phonons make the photothermal catalytic conversion various important processes possible.

Language: Английский

Citations

29
Ni/CaO-based dual-functional materials for calcium-looping CO2 capture and dry reforming of methane: Progress and challenges DOI
Enna Wang,

Zhengtong Zhu,

Rongrong Li

et al.

Chemical Engineering Journal, Journal Year: 2024, Volume and Issue: 482, P. 148476 - 148476

Published: Jan. 23, 2024

Language: Английский

Citations

25
Highly Efficient and Selective Light-Driven Dry Reforming of Methane by a Carbon Exchange Mechanism DOI

Hailong Xiong,

Yueyue Dong,

Canyu Hu

et al.

Journal of the American Chemical Society, Journal Year: 2024, Volume and Issue: 146(13), P. 9465 - 9475

Published: March 20, 2024

Dry reforming of methane (DRM) is a promising technique for converting greenhouse gases (namely, CH4 and CO2) into syngas. However, traditional thermocatalytic processes require high temperatures suffer from low selectivity coke-induced instability. Here, we report high-entropy alloys loaded on SrTiO3 as highly efficient coke-resistant catalysts light-driven DRM without secondary source heating. This process involves carbon exchange between reactants (i.e., CO2 CH4) oxygen the lattice supports, during which CO H2 are gradually produced released. Such mechanism deeply suppresses undesired side reactions such reverse water–gas shift reaction deep dissociation. Impressively, optimized CoNiRuRhPd/SrTiO3 catalyst achieves ultrahigh activity (15.6/16.0 mol gmetal–1 h–1 H2/CO production), long-term stability (∼150 h), remarkable (∼0.96). work opens new avenue future energy-efficient industrial applications.

Language: Английский

Citations

25
GaN Nanowire-Supported NiO for Low-Temperature and Durable Dry Reforming of Methane toward Syngas DOI
Yixin Li, Lin Yao, Jinglin Li

et al.

Applied Catalysis B Environment and Energy, Journal Year: 2025, Volume and Issue: unknown, P. 125051 - 125051

Published: Jan. 1, 2025

Language: Английский

Citations

3
Photothermal Methane Dry Reforming Catalyzed by Multifunctional (Ni–Cu/CeO2)@SiO2 Catalyst DOI
Lei Wang,

Ziliang Pu,

Yu Shi

et al.

ACS Sustainable Chemistry & Engineering, Journal Year: 2023, Volume and Issue: 11(49), P. 17384 - 17399

Published: Nov. 29, 2023

Photothermal catalysis is a promising technique for utilizing sustainable solar energy. In this work, we studied multifunctional (Ni-Cu/CeO2)@SiO2 catalyst photothermal methane dry reforming. The CeO2 enhanced light absorbance and provided the Ni-CeO2 interface compared to Ni@SiO2, while Cu further increased more effective (Ni/CeO2)@SiO2. CH4 CO2 rates reached 339 366 μmol/(gcat s), respectively, at 1023 K over catalyst, which were 105% 48% higher than those achieved Ni@SiO2. encapsulation of SiO2 metal–support interaction ensured trace aggregation Ni, lessened carbon deposition on used catalyst. work demonstrated powerful approach MDR, applicable other photosensitive reactions enhance performance.

Language: Английский

Citations

29
Recent advances in unconventional heating and external field-assisted enhancement for dry reforming of methane DOI

Zhiyong Tu,

Chunxia Mu,

Yuan Yao

et al.

Chemical Engineering Journal, Journal Year: 2024, Volume and Issue: 481, P. 148899 - 148899

Published: Jan. 20, 2024

Language: Английский

Citations

17
In-situ exsolved ultrafine Ni nanoparticles from CeZrNiO2 solid solution for efficient photothermal catalytic CO2 reduction by CH4 DOI Creative Commons
Guanrui Ji, Lei Ji, Shaowen Wu

et al.

Advanced Powder Materials, Journal Year: 2024, Volume and Issue: 3(3), P. 100188 - 100188

Published: March 15, 2024

CO2 reduction by CH4 (CRM) to produce fuel is of great significance for solar energy storage and eliminating greenhouse gas. Herein, the catalyst ultrafine Ni nanoparticles supported on CeZrNiO2 solid solution (Ni@CZNO) was synthesized sol-gel method. High yield H2 CO (58.0 69.8 mmol min−1 g−1) excellent durability (50 h) were achieved photothermal catalytic CRM merely under focused light irradiation. Structural characterization DFT calculations reveal that CZNO has rich oxygen vacancies can adsorb activate reactive species. Oxygen species are transferred through Ni-CZNO interface accelerate carbon oxidation, thereby maintaining stability catalyst. Moreover, experimental results irradiation not only enhance activity conversion molecular activation, but also improve increasing concentration inhibiting disproportionation.

Language: Английский

Citations

14
Rh/InGaN1−O nanoarchitecture for light-driven methane reforming with carbon dioxide toward syngas DOI
Yixin Li, Jinglin Li, Tianqi Yu

et al.

Science Bulletin, Journal Year: 2024, Volume and Issue: 69(10), P. 1400 - 1409

Published: Feb. 12, 2024

Language: Английский

Citations

12
A strategy of Co doping in MgO to significantly improve the performance of solar-driven thermocatalytic CO2 reduction on Ru/Co-MgO DOI
Huamin Cao, Yuanzhi Li, Qianqian Hu

et al.

Chemical Engineering Journal, Journal Year: 2024, Volume and Issue: 481, P. 148551 - 148551

Published: Jan. 10, 2024

Language: Английский

Citations

10
Synergetic effect for highly efficient light-driven CO2 reduction by CH4 on Co/Mg-CoAl2O4 promoted by a photoactivation DOI

Zhengyan Cui,

Qianqian Hu, Yuanzhi Li

et al.

Applied Catalysis B Environment and Energy, Journal Year: 2024, Volume and Issue: 350, P. 123917 - 123917

Published: April 24, 2024

Language: Английский

Citations

7