Insights into layered–tunnel dynamic structural evolution based on local coordination chemistry regulation for high‐energy‐density and long‐cycle‐life sodium‐ion oxide cathodes DOI Creative Commons
Yao Xiao, Yi‐Feng Liu, Hongwei Li

et al.

InfoMat, Journal Year: 2023, Volume and Issue: 5(10)

Published: July 26, 2023

Abstract The pursuit of high energy density while achieving long cycle life remains a challenge in developing transition metal (TM) oxide cathode materials for sodium‐ion batteries (SIBs). Here, we present concept precisely manipulating structural evolution via local coordination chemistry regulation to design high‐performance composite materials. controllable process is realized by tuning magnesium content Na 0.6 Mn 1− x Mg O 2 , which elucidated combination experimental analysis and theoretical calculations. substitution into sites not only induces unique from layered–tunnel structure layered but also mitigates the Jahn–Teller distortion 3+ . Meanwhile, benefiting strong ionic interaction between 2+ 2− environments around coordinated with electrochemically inactive are anchored TM layer, providing pinning effect stabilize crystal smooth electrochemical profile. 0.95 0.05 material delivers 188.9 mAh g −1 specific capacity, equivalent 508.0 Wh kg at 0.5C, exhibits 71.3% capacity retention after 1000 cycles 5C as well excellent compatibility hard carbon anode. This work may provide new insights inspire more novel SIB image

Language: Английский

Practical Cathodes for Sodium‐Ion Batteries: Who Will Take The Crown? DOI Open Access
Xinghui Liang, Jang‐Yeon Hwang, Yang‐Kook Sun

et al.

Advanced Energy Materials, Journal Year: 2023, Volume and Issue: 13(37)

Published: Aug. 17, 2023

Abstract In recent decades, sodium‐ion batteries (SIBs) have received increasing attention because they offer cost and safety advantages avoid the challenges related to limited lithium/cobalt/nickel resources environmental pollution. Because sodium storage performance production of SIBs are dominated by cathode performance, developing materials with large‐scale capacity is key achieving commercial applications SIBs. Therefore, host high energy density, long cycling life, low cost, chemical/environmental stability crucial for implementing advanced Among developed SIBs, O3‐type sodiated transition‐metal oxides attracted extensive owing their simple synthesis methods, theoretical specific capacity, sufficient Na content. However, relatively large Na‐ion radius leads sluggish diffusion kinetics inevitable complex phase transitions during deintercalation/intercalation process, resulting in poor rate capability stability. this review comprehensively summarizes research progress modification strategies cathodes, including component design, surface modification, optimization methods. This work aims guide development layered provide technical support next generation energy‐storage systems.

Language: Английский

Citations

138
Routes to high-performance layered oxide cathodes for sodium-ion batteries DOI
Jingqiang Wang,

Yan‐Fang Zhu,

Yu Su

et al.

Chemical Society Reviews, Journal Year: 2024, Volume and Issue: 53(8), P. 4230 - 4301

Published: Jan. 1, 2024

Various optimization strategies are reviewed and summarized to formulate design principles for layered oxide cathodes sodium-ion batteries.

Language: Английский

Citations

131
The Distance Between Phosphate‐Based Polyanionic Compounds and Their Practical Application For Sodium‐Ion Batteries DOI Open Access
Zhiqiang Hao, Xiaoyan Shi, Zhuo Yang

et al.

Advanced Materials, Journal Year: 2023, Volume and Issue: 36(7)

Published: Aug. 18, 2023

Abstract Sodium‐ion batteries (SIBs) are a viable alternative to meet the requirements of future large‐scale energy storage systems due uniform distribution and abundant sodium resources. Among various cathode materials for SIBs, phosphate‐based polyanionic compounds exhibit excellent sodium‐storage properties, such as high operation voltage, remarkable structural stability, superior safety. However, their undesirable electronic conductivities specific capacities limit application in systems. Herein, development history recent progress cathodes first overviewed. Subsequently, effective modification strategies summarized toward high‐performance including surface coating, morphological control, ion doping, electrolyte optimization. Besides, electrochemical performance, cost, industrialization analysis SIBs discussed accelerating commercialization development. Finally, directions comprehensively concluded. It is believed that this review can provide instructive insight into developing practical SIBs.

Language: Английский

Citations

108
Roadmap for rechargeable batteries: present and beyond DOI Open Access
Sen Xin, Xu Zhang, Lin Wang

et al.

Science China Chemistry, Journal Year: 2023, Volume and Issue: 67(1), P. 13 - 42

Published: Dec. 26, 2023

Language: Английский

Citations

108
A 30‐year overview of sodium‐ion batteries DOI Creative Commons
Yun Gao, Hang Zhang, Jian Peng

et al.

Carbon Energy, Journal Year: 2024, Volume and Issue: 6(6)

Published: Feb. 28, 2024

Abstract Sodium‐ion batteries (NIBs) have emerged as a promising alternative to commercial lithium‐ion (LIBs) due the similar properties of Li and Na elements well abundance accessibility resources. Most current research has been focused on half‐cell system (using metal counter electrode) evaluate performance cathode/anode/electrolyte. The relationship between achieved in half cells that obtained full cells, however, neglected much this research. Additionally, trade‐off electrochemical cost needs be given more consideration. Therefore, systematic comprehensive insights into status key issues for full‐cell need gained advance its commercialization. Consequently, review evaluates recent progress based various cathodes highlights most significant challenges cells. Several strategies also proposed enhance NIBs, including designing electrode materials, optimizing electrolytes, sodium compensation, so forth. Finally, perspectives outlooks are provided guide future sodium‐ion

Language: Английский

Citations

90
Low‐Temperature Sodium‐Ion Batteries: Challenges and Progress DOI Creative Commons
Zhongchao Bai, Qian Yao, Mingyue Wang

et al.

Advanced Energy Materials, Journal Year: 2024, Volume and Issue: 14(17)

Published: Feb. 15, 2024

Abstract As an ideal candidate for the next generation of large‐scale energy storage devices, sodium‐ion batteries (SIBs) have received great attention due to their low cost. However, practical utility SIBs faces constraints imposed by geographical and environmental factors, particularly in high‐altitude cold regions. In these areas, low‐temperature (LT) performance presents a pressing technological challenge that requires significant breakthroughs. LT environments, electrochemical reaction kinetics are sluggish, electrode/electrolyte interface is unstable, diffusion sodium ions electrode materials slow, leading decrease battery performance. Therefore, reasonable design electrolyte significance optimizing SIBs. this review, research progress electrolytes, cathode, anode materials, as well metal solid‐state electrolytes systematically summarized recent years, aiming understand principles SIBs, clarify basic development high‐performance applications, promote technology full temperature range.

Language: Английский

Citations

80
Facilitating Layered Oxide Cathodes Based on Orbital Hybridization for Sodium‐Ion Batteries: Marvelous Air Stability, Controllable High Voltage, and Anion Redox Chemistry DOI

Xin‐Bei Jia,

Jingqiang Wang, Yi‐Feng Liu

et al.

Advanced Materials, Journal Year: 2023, Volume and Issue: 36(15)

Published: Nov. 1, 2023

Layered oxides have become the research focus of cathode materials for sodium-ion batteries (SIBs) due to low cost, simple synthesis process, and high specific capacity. However, poor air stability, unstable phase structure under voltage, slow anionic redox kinetics hinder their commercial application. In recent years, concept manipulating orbital hybridization has been proposed simultaneously regulate microelectronic modify surface chemistry environment intrinsically. this review, modes between atoms in 3d/4d transition metal (TM) orbitals O 2p near region Fermi energy level (E

Language: Английский

Citations

62
Resolving the Origins of Superior Cycling Performance of Antimony Anode in Sodium‐ion Batteries: A Comparison with Lithium‐ion Batteries DOI
Ruiwen Shao, Zhefei Sun, Lei Wang

et al.

Angewandte Chemie International Edition, Journal Year: 2024, Volume and Issue: 63(11)

Published: Jan. 24, 2024

Abstract Alloying‐type antimony (Sb) with high theoretical capacity is a promising anode candidate for both lithium‐ion batteries (LIBs) and sodium‐ion (SIBs). Given the larger radius of Na + (1.02 Å) than Li (0.76 Å), it was generally believed that Sb would experience even worse degradation in SIBs due to more substantial volumetric variations during cycling when compared LIBs. However, unexpectedly exhibited better electrochemical structural stability LIBs, mechanistic reasons underlie this performance discrepancy remain undiscovered. Here, using situ transmission electron microscopy, X‐ray diffraction, Raman techniques complemented by simulations, we explicitly reveal lithiation/delithiation process, sodiation/desodiation process displays previously unexplored two‐stage alloying/dealloying mechanism polycrystalline amorphous phases as intermediates featuring improved resilience mechanical damage, contributing superior SIBs. Additionally, properties weaker atomic interaction Na−Sb alloys Li−Sb favor enabling mitigated stress, accounting enhanced unveiled simulations. Our finding delineates origins potential implications other large‐volume‐change electrode materials.

Language: Английский

Citations

60
Sodium layered oxide cathodes: properties, practicality and prospects DOI

Yu‐Jie Guo,

Ruo-Xi Jin,

Min Fan

et al.

Chemical Society Reviews, Journal Year: 2024, Volume and Issue: 53(15), P. 7828 - 7874

Published: Jan. 1, 2024

This review depicts a broad picture of fundamental electrochemical properties, challenges in practical use, improvement strategies and future prospects Na layered oxides, attempting to offer insights into design high-performance cathodes.

Language: Английский

Citations

51
Advanced electrolytes for high-performance aqueous zinc-ion batteries DOI

Jie Wei,

Pengbo Zhang,

Jingjie Sun

et al.

Chemical Society Reviews, Journal Year: 2024, Volume and Issue: unknown

Published: Jan. 1, 2024

This review presents an comprehensive overview of various advanced aqueous electrolytes for zinc-ion batteries, including “water-in-salt” electrolytes, eutectic molecular crowding and hydrogel electrolytes.

Language: Английский

Citations

50