Journal of Colloid and Interface Science, Journal Year: 2024, Volume and Issue: 672, P. 287 - 298
Published: May 22, 2024
Language: Английский
Chemical Engineering Journal, Journal Year: 2024, Volume and Issue: 491, P. 151979 - 151979
Published: May 6, 2024
Language: Английский
Citations
11
Journal of Colloid and Interface Science, Journal Year: 2024, Volume and Issue: 670, P. 519 - 529
Published: May 18, 2024
Language: Английский
Citations
11
Energy storage materials, Journal Year: 2024, Volume and Issue: 72, P. 103596 - 103596
Published: June 25, 2024
Zinc-based batteries are gaining prominence as promising alternatives to lithium-ion (LIBs) in the pursuit of Net-Zero goals, owing their cost-effectiveness, scalability, and reduced resource dependency. Aqueous rechargeable zinc-iodine (Zn-I2) batteries, particular, emerging an enticing choice for future energy storage systems, thanks eco-friendly nature, impressive theoretical capacity, energy/power density. Nevertheless, several challenges, including well-known polyiodide shuttling phenomenon, suboptimal thermodynamic stability, issues like corrosion dendrite formation on Zn metal anodes, impede practical implementation. Tremendous progress has been achieved circumvent these recent years, though a comprehensive review article both entry-level experienced researchers is still lacking up date. This aims at discussing fundamentals, solutions enable understanding electrochemistry mechanisms, systematically summarizing past, present, technologies strategies involving iodine cathode design modification, interlayer construction/separator electrolytes optimization, anodes protection. Additionally, based achievements, some directions efforts developing high-performance Zn−I2 proposed accelerate commercial applications.
Language: Английский
Citations
11
Journal of Colloid and Interface Science, Journal Year: 2025, Volume and Issue: 688, P. 11 - 21
Published: Feb. 18, 2025
Language: Английский
Citations
1
Carbon Neutralization, Journal Year: 2025, Volume and Issue: 4(2)
Published: Feb. 19, 2025
ABSTRACT The development of high‐performance energy storage systems requires several key attributes, including high and power density, cost‐effectiveness, safety, environmental sustainability. Among the various potential technologies, lithium–sulfur batteries stand out as a promising contender for future solutions due to their exceptional theoretical specific density (2600 Wh kg⁻¹) relatively capacity (1675 mAh g⁻¹). However, commercialization faces significant challenges, such low sulfur loading, rapid degradation, poor cycling stability. At heart these issues lies limited understanding complex conversion chemistry involved in batteries. In recent years, progress has been made elucidating reaction mechanisms, thanks use both ex situ characterization techniques. Methods optical spectroscopy, time‐of‐flight secondary ion mass spectrometry, synchrotron X‐ray, neural network analysis have demonstrated great uncovering redox processes lithium polysulfides underlying significantly advancing research battery systems. This review focuses on major advancements research, particularly study electrocatalytic mechanisms using emerging We discuss aspects accurately revealing through advanced diagnostic methods, well main challenges techniques face. Finally, we explore prospects commercialization.
Language: Английский
Citations
1
Small, Journal Year: 2025, Volume and Issue: unknown
Published: Feb. 24, 2025
Abstract Lithium‐sulfur (Li‐S) batteries are recognized as a most promising energy storage technology for their high theoretical density, abundant sulfur resources, and environmental friendliness. Nonetheless, practical applications of Li‐S currently hindered by obstacles such the shuttle effect lithium polysulfides (LiPSs), sluggish reaction kinetics, formation Li dendrites. Heterostructured electrocatalysts can achieve synergistic adsorption‐catalysis LiPSs regulating component composition to accelerate electrochemical guide uniform deposition Li. Electrospinning has emerged versatile approach precise fabrication heterostructured nanomaterials, advantages including tunable composition, controlled fiber diameter, diverse pore structures, flexible morphological heterogeneous interfacial design. In this contribution, latest research progress on heterostructures constructed electrospinning is reviewed. Initially, definition outlined mechanisms promote kinetics in analyzed. Subsequently, principles influencing factors constructing based discussed. The application cathodes, separators, anodes further comprehensively Finally, issues identified, corresponding effective solutions provided. This review intended inspire design construction efficient batteries.
Language: Английский
Citations
1
Interdisciplinary materials, Journal Year: 2023, Volume and Issue: 2(5), P. 761 - 770
Published: Sept. 1, 2023
Abstract Lithium–sulfur (Li–S) batteries has emerged as a promising post‐lithium‐ion battery technology due to their high potential energy density and low raw material cost. Recent years have witnessed substantial progress in research on Li–S batteries, yet no high‐energy products reached the market at scale. Achieving necessitates multidisciplinary approach involving advanced electrode design, electrochemistry, cell engineering. In this perspective, we offer holistic view of pathways for realizing under practical conditions. Starting with outlook present comprehensive quantitative analysis critical parameters that dictate cell‐level battery. Thereby establish protocol expedite integration lab‐scale results into cell. Furthermore, underscore several key considerations promotion commercial viability from perspective industrialization.
Language: Английский
Citations
20
Small, Journal Year: 2023, Volume and Issue: 20(17)
Published: Dec. 4, 2023
Abstract Lithium–sulfur batteries (LSBs) with ultra‐high energy density (2600 W h kg −1 ) and readily available raw materials are emerging as a potential alternative device low cost for lithium‐ion batteries. However, the insulation of sulfur unavoidable shuttle effect leads to slow reaction kinetics LSBs, which in turn cause various roadblocks including poor rate capability, inferior cycling stability, coulombic efficiency. The most effective way solve issues mentioned above is rationally design control synthesis cathode host LSBs. Transition metal phosphides (TMPs) good electrical conductivity dual adsorption‐conversion capabilities polysulfide (PS) regarded promising hosts new‐generation In this review, main obstacles commercializing LSBs development processes their first elaborated. Then, fixation principles, methods TMPs briefly summarized recent progress reviewed detail. Finally, perspective on future research directions provided.
Language: Английский
Citations
20
Journal of Colloid and Interface Science, Journal Year: 2024, Volume and Issue: 660, P. 458 - 468
Published: Jan. 19, 2024
Language: Английский
Citations
7
Science Bulletin, Journal Year: 2024, Volume and Issue: 69(8), P. 1071 - 1080
Published: Jan. 21, 2024
Language: Английский
Citations
7