Energy storage materials, Journal Year: 2024, Volume and Issue: 70, P. 103438 - 103438
Published: May 5, 2024
Language: Английский
Energy Materials and Devices, Journal Year: 2023, Volume and Issue: 1(1), P. 9370003 - 9370003
Published: Sept. 1, 2023
Lithium batteries play a dominant role in the power source market of electric vehicles and portable electronic devices. The electrolyte is critical to determining performance lithium batteries. Conventional electrolytes cannot meet ever-growing demands fast-charging, wide-temperature operation, safety properties Despite great success (localized) high-concentration electrolytes, they still suffer from disadvantages like low ionic conductivity high cost. emerging weakly solvating also known as low-solvating offer another solution these challenges have attracted intensive research interests recent years. This contribution reviews working mechanisms, design principles, advances developing electrolytes. A summary perspective about future directions this field provided. insights will benefit both academic industrial communities designing safe high-performance next-generation Li
Language: Английский
Citations
74
Journal of Energy Chemistry, Journal Year: 2024, Volume and Issue: 91, P. 484 - 500
Published: Jan. 19, 2024
Language: Английский
Citations
40
Advanced Materials, Journal Year: 2024, Volume and Issue: 36(27)
Published: April 16, 2024
Abstract The lignin derived ultrathin all‐solid composite polymer electrolyte (CPE) with a thickness of only 13.2 µm, which possess 3D nanofiber ionic bridge networks composed single‐ion lignin‐based lithium salt (L‐Li) and poly(vinylidene fluoride‐ co ‐hexafluoropropylene) (PVDF‐HFP) as the framework, poly(ethylene oxide)/lithium bis(trifluoromethanesulfonyl)imide (PEO/LiTFSI) filler, is obtained through electrospinning/spraying hot‐pressing. t. Li‐symmetric cell assembled CPE can stably cycle more than 6000 h under 0.5 mA cm −2 little Li dendrites growth. Moreover, Li||CPE||LiFePO 4 cells over 700 cycles at 0.2 C super high initial discharge capacity 158.5 mAh g −1 room temperature, favorable 123 −20 °C for 250 cycles. excellent electrochemical performance mainly attributed to reason that network afford uniformly dispersed L‐Li electrospinning, synergizes LiTFSI well in PEO form abundant efficient + transfer channels. induces uniform deposition interface, effectively inhibit dendrites. This work provides promising strategy achieve biobased electrolytes solid‐state ion batteries.
Language: Английский
Citations
37
Nano Letters, Journal Year: 2024, Volume and Issue: 24(24), P. 7499 - 7507
Published: June 10, 2024
Lithium metal batteries utilizing lithium as the anode can achieve a greater energy density. However, it remains challenging to improve low-temperature performance and fast-charging features. Herein, we introduce an electrolyte solvation chemistry strategy regulate properties of ethylene carbonate (EC)-based electrolytes through intermolecular interactions, weakly solvated fluoroethylene (FEC) replace EC, incorporating low-melting-point solvent 1,2-difluorobenzene (2FB) diluent. We identified that interaction between 2FB facilitate Li
Language: Английский
Citations
27
Advanced Materials, Journal Year: 2024, Volume and Issue: 36(38)
Published: Jan. 9, 2024
Sodium layered-oxides (Na
Language: Английский
Citations
18
Chemical Engineering Journal, Journal Year: 2025, Volume and Issue: unknown, P. 159927 - 159927
Published: Jan. 1, 2025
Language: Английский
Citations
2
Energy & Environmental Science, Journal Year: 2023, Volume and Issue: 17(1), P. 227 - 237
Published: Nov. 14, 2023
Correlations between the temperature-responsive solvation structure, interfacial chemistry and performance of graphite anodes are revealed to understand structure–property relationships, providing insights into designing temperature-adaptative batteries.
Language: Английский
Citations
39
Angewandte Chemie International Edition, Journal Year: 2024, Volume and Issue: 63(36)
Published: June 14, 2024
Electrolytes endowed with high oxidation/reduction interfacial stability, fast Li-ion desolvation process and decent ionic conductivity over wide temperature region are known critical for low fast-charging performance of energy-dense batteries, yet these characteristics rarely satisfied simultaneously. Here, we report anchored weakly-solvated electrolytes (AWSEs), that designed by extending the chain length polyoxymethylene ether electrolyte solvent, can achieve above merits at moderate salt concentrations. The -O-CH
Language: Английский
Citations
16
Angewandte Chemie International Edition, Journal Year: 2024, Volume and Issue: unknown
Published: July 15, 2024
Abstract Lithium iron phosphate (LFP)/graphite batteries have long dominated the energy storage battery market and are anticipated to become dominant technology in global power market. However, poor fast‐charging capability low‐temperature performance of LFP/graphite seriously hinder their further spread. These limitations strongly associated with interfacial lithium (Li)‐ion transport. Here we report a wide‐temperature‐range ester‐based electrolyte that exhibits high ionic conductivity, fast kinetics excellent film‐forming ability by regulating anion chemistry Li salt. The barrier is quantitatively unraveled employing three‐electrode system distribution relaxation time technique. superior role proposed preventing 0 plating sustaining homogeneous stable interphases also systematically investigated. cells exhibit rechargeability an ultrawide temperature range −80 °C 80 outstanding without compromising lifespan. Specially, practical pouch achieve 80.2 % capacity retention after 1200 cycles (2 C) 10‐min charge 89 (5 at 25 provide reliable even °C.
Language: Английский
Citations
14
Energy storage materials, Journal Year: 2024, Volume and Issue: 71, P. 103692 - 103692
Published: Aug. 1, 2024
Language: Английский
Citations
13