A combined strategy to constructure MoX2 (X=Se and S)-based core@shell structure flower-like multicomponent nanocomposites for boosted conduction loss, polarization loss and microwave absorption capacities DOI

Li Yao,

Xiaosi Qi,

Beibei Zhan

et al.

Composites Communications, Journal Year: 2024, Volume and Issue: 50, P. 102014 - 102014

Published: July 22, 2024

Language: Английский

Single Precursor-Derived Sub-1 nm MoCo Bimetallic Particles Decorated on Phosphide–Carbon Nitride Framework for Sustainable Hydrogen Generation DOI

Sadam Hussain,

Manzar Sohail, Nadia Shahzad

et al.

ACS Applied Materials & Interfaces, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 8, 2025

The strategic design and fabrication of efficient electrocatalysts are pivotal for advancing the field electrochemical water splitting (EWS). To enhance EWS performance, integrating non-noble transition metal catalysts through a cooperative double incorporation strategy is important offers compelling alternative to conventional precious metal-based materials. This study introduces novel, straightforward, single-step process fabricating bimetallic MoCo catalyst integrated within three-dimensional (3D) nanoporous network N, P-doped carbon nitride derived from self-contained precursor. subsequent carbonization at 550 °C yields highly effective phosphide electrocatalyst, denoted as MoCoPCN, tailored explicitly EWS. MoCoPCN electrocatalyst demonstrates exceptional electrocatalytic with low onset potential 1.43 V an overpotential value 202 mV current density 10 mA/cm2 oxygen evolution reaction (OER) 49.5 hydrogen (HER), respectively. Moreover, exhibits high electrochemically active surface area 2720 cm–2, small Tafel slope 47.5 dec–1 HER 45.7 OER, charge transfer resistance 0.09 Ω 0.805 OER. optimal was tested overall performance in 1 M KOH electrolyte, demonstrating excellent efficiency cell voltage 1.49 required achieve mA/cm2. These outstanding characteristics, combined synergistic effects arising interaction between P-g-C3N4 (PCN), underscore material promising splitting.

Language: Английский

Citations

1
Dual‐Site Bridging Mechanism for Bimetallic Electrochemical Oxygen Evolution DOI
Hongshuai Cao, Xue Wen,

Xianzhu Luo

et al.

Angewandte Chemie International Edition, Journal Year: 2024, Volume and Issue: 63(46)

Published: Aug. 9, 2024

Abstract Heterogeneous dual‐site electrocatalysts are emerging cutting‐edge materials for efficient electrochemical water splitting. However, the corresponding oxygen evolution reaction (OER) mechanism on these is still unclear. Herein, based a series of in situ spectroscopy experiments and density function theory (DFT) calculations, new heterogeneous O−O bridging (DSBM) proposed. This to elucidate sequential appearance dual active sites through construction (hybrid ions undergo reconstruction initially), determine crucial role hybrid this (with Ni preferentially adsorbing hydroxyls catalysis followed by proton removal at Fe sites), assess impact bond formation activation state (inducing orderliness activated water), investigate universality Co doping Ni(P 4 O 11 )). Under guidance mechanism, with Fe−Ni(P ) as pre‐catalyst, formed Fe−Ni(OH) 2 electrocatalyst has reached record‐low overpotential 156.4 mV current 18.0 mA cm −2 . Successfully constructed )/Ti uplifting overall efficacy phosphate from moderate superior, positioning it an innovative highly proficient OER.

Language: Английский

Citations

7
Cyanobacteria–probiotics symbionts for modulation of intestinal inflammation and microbiome dysregulation in colitis DOI Creative Commons
Jiali Yang,

Shaochong Tan,

Shengchan Ge

et al.

Proceedings of the National Academy of Sciences, Journal Year: 2024, Volume and Issue: 121(52)

Published: Dec. 16, 2024

Inflammatory bowel disease (IBD) is often associated with excessive inflammatory response and highly dysregulated gut microbiota. Traditional treatments utilize drugs to manage inflammation, potentially probiotic therapy as an adjuvant. However, current standard practices suffer from detrimental side effects, low bioavailability, unsatisfactory therapeutic outcomes. Microbial complexes characterized by mutually beneficial symbiosis hold great promise for IBD therapy. Here, we aggregated Synechocystis sp. PCC6803 (Sp) Bacillus subtilis (BS) biomimetic mineralization form cyanobacteria–probiotics symbionts (ASp@BS), which reshaped a healthy immune system microbiota in murine model of acute colitis. The exhibited excellent tolerance the harsh environment gastrointestinal tract. Importantly, probiotics within created local anaerobic activate [NiFe]-hydrogenase enzyme cyanobacteria, facilitating production hydrogen gas (H 2 ) persistently scavenge elevated reactive oxygen species alleviate factors. resulting reduced inflammation improves viability efficiently regulate reshape intestinal barrier functions. Our research elucidates that ASp@BS leverages synergistic interaction between Sp BS create platform addresses multiple aspects IBD, offering promising comprehensive solution treatment.

Language: Английский

Citations

4
Achievements and challenges in glucose oxidase-instructed multimodal synergistic antibacterial applications DOI
Ran Zhao,

Yanzhao Ke,

Huiyan Sun

et al.

Microbiological Research, Journal Year: 2025, Volume and Issue: unknown, P. 128149 - 128149

Published: March 1, 2025

Language: Английский

Citations

0
Dual‐Site Bridging Mechanism for Bimetallic Electrochemical Oxygen Evolution DOI
Hongshuai Cao, Xue Wen,

Xianzhu Luo

et al.

Angewandte Chemie, Journal Year: 2024, Volume and Issue: 136(46)

Published: Aug. 9, 2024

Abstract Heterogeneous dual‐site electrocatalysts are emerging cutting‐edge materials for efficient electrochemical water splitting. However, the corresponding oxygen evolution reaction (OER) mechanism on these is still unclear. Herein, based a series of in situ spectroscopy experiments and density function theory (DFT) calculations, new heterogeneous O−O bridging (DSBM) proposed. This to elucidate sequential appearance dual active sites through construction (hybrid ions undergo reconstruction initially), determine crucial role hybrid this (with Ni preferentially adsorbing hydroxyls catalysis followed by proton removal at Fe sites), assess impact bond formation activation state (inducing orderliness activated water), investigate universality Co doping Ni(P 4 O 11 )). Under guidance mechanism, with Fe−Ni(P ) as pre‐catalyst, formed Fe−Ni(OH) 2 electrocatalyst has reached record‐low overpotential 156.4 mV current 18.0 mA cm −2 . Successfully constructed )/Ti uplifting overall efficacy phosphate from moderate superior, positioning it an innovative highly proficient OER.

Language: Английский

Citations

3
Amorphous/crystalline NiFe LDH hierarchical nanostructure for large-current-density electrocatalytic water oxidation DOI
Yilong Li, Mingzhe Li, Chenxuan Xie

et al.

Journal of Alloys and Compounds, Journal Year: 2024, Volume and Issue: 1002, P. 175328 - 175328

Published: Oct. 1, 2024

Language: Английский

Citations

2
A combined strategy to constructure MoX2 (X=Se and S)-based core@shell structure flower-like multicomponent nanocomposites for boosted conduction loss, polarization loss and microwave absorption capacities DOI

Li Yao,

Xiaosi Qi,

Beibei Zhan

et al.

Composites Communications, Journal Year: 2024, Volume and Issue: 50, P. 102014 - 102014

Published: July 22, 2024

Language: Английский

Citations

2