Cited by A tripartite synergistic optimization strategy for zinc-iodine batteries

Interfacial chemistry in multivalent aqueous batteries: fundamentals, challenges, and advances DOI

Zhengyu Ju,

Tianrui Zheng,

Bowen Zhang

et al.

Chemical Society Reviews, Journal Year: 2024, Volume and Issue: 53(18), P. 8980 - 9028

Published: Jan. 1, 2024

As one of the most promising electrochemical energy storage systems, aqueous batteries are attracting great interest due to their advantages high safety, sustainability, and low costs when compared with commercial lithium-ion batteries, showing promise for grid-scale storage. This invited tutorial review aims provide universal design principles address critical challenges at electrode-electrolyte interfaces faced by various multivalent battery systems. Specifically, deposition regulation, ion flux homogenization, solvation chemistry modulation proposed as key tune inter-component interactions in corresponding interfacial strategies underlying working mechanisms illustrated. In end, we present a analysis on remaining obstacles necessitated overcome use under different practical conditions future prospects towards further advancement sustainable systems long durability.

Language: Английский

Citations

Achieving Dendrite‐Free and By‐Product‐Free Aqueous Zn‐Ion Battery Anode via Nicotinic Acid Electrolyte Additive with Molecule‐Ion Conversion Mechanism DOI

Hanhao Liang,

Jian Wu, Jiaming Li

et al.

Small, Journal Year: 2024, Volume and Issue: unknown

Published: May 19, 2024

Abstract The widespread adoption of aqueous Zn ion batteries is hindered by the instability anode. Herein, an elegant strategy proposed to enhance stability anode incorporating nicotinic acid (NA), additive with a unique molecule‐ion conversion mechanism, optimize anode/electrolyte interface and typical ZnSO 4 electrolyte system. Experimental characterization theoretical calculations demonstrate that NA preferentially replaces H 2 O in original solvation shell adsorbs onto surface upon from molecule environment, thereby suppressing side reactions arising activated decomposition stochastic growth dendrites. Simultaneously, such molecule‐to‐ion mechanism may induce preferential deposition along (002) plane. Benefiting it, Zn||Zn symmetric battery cycles stably for 2500 h at 1 mA cm −2 , mAh . More encouragingly, Zn||AC full using Zn||VO also exhibit excellent performance improvements. This work emphasizes role variation form additives (especially weak acid‐based additives) fine‐tuning structure interface, hopefully enhancing various metal batteries.

Language: Английский

Citations

Tailoring the Whole Deposition Process from Hydrated Zn2+ to Zn0 for Stable and Reversible Zn Anode DOI

Quan Zong, Ruiling Li,

Jiangying Wang

et al.

Angewandte Chemie International Edition, Journal Year: 2024, Volume and Issue: 63(41)

Published: July 22, 2024

Abstract The practical application of aqueous zinc‐ion batteries (ZIBs) indeed faces challenges primarily attributed to the inherent side reactions and dendrite growth associated with Zn anode. In present work, N‐Methylmethanesulfonamide (NMS) is introduced optimize transfer, desolvation, reduction 2+ , achieving highly stable reversible plating/stripping. NMS molecule can substitute one H 2 O in solvation structure hydrated be preferentially chemisorbed on surface protect anode against corrosion hydrogen evolution reaction (HER), thereby suppressing byproducts formation. Additionally, a robust N‐rich organic inorganic (ZnS ZnCO 3 ) hybrid solid electrolyte interphase situ generated due decomposition NMS, resulting enhanced transport kinetics uniform deposition. Consequently, cells achieve long lifespan 2300 h at 1 mA cm −2 mAh high cumulative plated capacity 3.25 Ah excellent reversibility an average coulombic efficiency (CE) 99.7 % over 800 cycles.

Language: Английский

Citations

Regulating Electrode/Electrolyte Interface with Additives towards Dendrite‐Free Zinc‐Ion Batteries DOI

Jin Cao,

Yongxin Sun,

Dongdong Zhang

et al.

ChemElectroChem, Journal Year: 2024, Volume and Issue: 11(13)

Published: April 11, 2024

Abstract Aqueous zinc‐ion batteries (AZIBs) are highly promising for grid‐scale energy storage due to their high‐safety and low‐cost characteristics. Nevertheless, the progress in AZIBs has been impeded challenges encompassing corrosion, hydrogen evolution reaction, formation of dendrites on Zn anodes. These issues arise from decomposition active water molecules 2+ solvation structure electrolyte. Various strategies have proposed regulate electrode/electrolyte interface effectively address these problems. In spite remarkable headway, an inadequacy comprehensive studies addressing mechanisms evolutionary dynamics is evident within scientific literature. This overview aims provide a regulating interface, focusing dendrite‐free side reactions‐suppressed AZIBs. include introduction metal ion additives, inorganic surfactant polymer additives organic additives. Furthermore, detailed examination made effects underlying associated with modifying electrolyte at between electrode Moreover, appraisal provided performance metrics diverse prospective research directions recommended as well.

Language: Английский

Citations

A tripartite synergistic optimization strategy for zinc-iodine batteries DOI

Weibin Yan,

Ying Liu, Jiehong Qiu

et al.

Nature Communications, Journal Year: 2024, Volume and Issue: 15(1)

Published: Nov. 9, 2024

The energy industry has taken notice of zinc-iodine (Zn-I

Language: Английский

Citations