Journal of Colloid and Interface Science, Journal Year: 2024, Volume and Issue: 682, P. 1094 - 1103
Published: Dec. 9, 2024
Language: Английский
Journal of Colloid and Interface Science, Journal Year: 2024, Volume and Issue: 682, P. 1094 - 1103
Published: Dec. 9, 2024
Language: Английский
Advanced Functional Materials, Journal Year: 2025, Volume and Issue: unknown
Published: Jan. 7, 2025
Abstract The conversion of lignin into aviation fuel offers a promising, energy‐efficient route for sustainable jet production. key to this transformation lies in the selective hydrogenation lignin's aromatic rings, deoxygenation its oxygen‐containing and phenolic hydroxyl groups, cleavage bonds between polycyclic hydrocarbons. Using phosphorus‐doped CoMn‐P catalyst, electrochemical lignin, assisted by light, can reduce energy consumption ≈20%, resulting significant yield hydrocarbons cycloalkanes. Phosphorus doping modulates catalyst's electronic structure, enhancing adsorption β─O─4 bonds, methoxy thereby enabling with low reaction barrier. This approach provides an innovative pathway directly converting hydrocarbon mixtures suitable fuel.
Language: Английский
Citations
3Journal of Alloys and Compounds, Journal Year: 2025, Volume and Issue: 1017, P. 179064 - 179064
Published: Feb. 1, 2025
Language: Английский
Citations
1International Journal of Biological Macromolecules, Journal Year: 2025, Volume and Issue: 307, P. 142020 - 142020
Published: March 12, 2025
Language: Английский
Citations
1Carbon Energy, Journal Year: 2025, Volume and Issue: unknown
Published: March 20, 2025
ABSTRACT Carbon electrocatalyst materials based on lignocellulosic biomass with multi‐components, various dimensions, high carbon content, and hierarchical morphology structures have gained great popularity in electrocatalytic applications recently. Due to the catalytic deficiency of neutral atoms, usage single lignocellulosic‐based electrocatalysis involving energy storage conversion presents unsatisfactory applicability. However, atomic‐level modulation lignocellulose‐based can optimize electronic structures, charge separation, transfer processes, so forth, which results substantially enhanced performance carbon‐based catalysts. This paper reviews recent advances rational design as electrocatalysts from an perspective, such self/external heteroatom doping metal modification. Then, through systematic discussion principles reaction mechanisms catalysts, prepared catalysts rechargeable batteries are reviewed. Finally, challenges improving prospects diverse review contributes synthesis strategy via modulation, turn promotes lignocellulose valorization for conversion.
Language: Английский
Citations
1Industrial & Engineering Chemistry Research, Journal Year: 2025, Volume and Issue: unknown
Published: Jan. 13, 2025
The low-cost and high-capacity SiOx is widely recognized as an ideal anode material for lithium storage; however, the challenges of low conductivity significant volume expansion still need to be addressed. In this work, we incorporated into a lignin-derived carbon with elevated nitrogen content through step-by-step carbonization strategy. Initially, electrostatic assembly facilitated formation complex comprising modified lignin SiO2, which was subsequently subjected etching steps. Finally, due zinc species inhibiting decomposition, cocarbonization porous carbon/SiOx complex, oxalate, melamine enabled construction nitrogen-enriched composite. resulting composite exhibited moderate specific surface area, abundant mesoporous channels, exceptionally high doping 17.91 at. %. These characteristics effectively enhanced storage transportation ions while mitigating expansion. As anodes in half batteries, reversible capacity optimized reached 894 mAh/g during stable cycles, attributed ion diffusion rate kinetics from well improved structural stability encapsulated structure. Furthermore, assembled lithium-ion capacitor demonstrated energy density 82 Wh/kg maintained retention 93.1% after undergoing 15,000 cycles. This work presents novel concept synthesis nitrogen-rich matrixes but also offers insights optimization silicon-based negative electrodes using green biomass.
Language: Английский
Citations
0Chinese Journal of Chemical Engineering, Journal Year: 2025, Volume and Issue: unknown
Published: Jan. 1, 2025
Language: Английский
Citations
0Industrial Crops and Products, Journal Year: 2025, Volume and Issue: 225, P. 120513 - 120513
Published: Jan. 16, 2025
Language: Английский
Citations
0Sustainable materials and technologies, Journal Year: 2025, Volume and Issue: unknown, P. e01267 - e01267
Published: Jan. 1, 2025
Language: Английский
Citations
0Molecules, Journal Year: 2025, Volume and Issue: 30(4), P. 820 - 820
Published: Feb. 10, 2025
To achieve the "double carbon" goal, it is urgent to reform energy system. The oxygen evolution reaction (OER) a vital semi-reaction for many new energy-storage and conversion devices. Metal nanoparticles embedded in heteroatom-doped carbon materials prepared by pyrolyzing of metal-organic frameworks (MOFs) have been key route obtain high-performance electrochemical catalysts. Herein, nanocatalyst embedding Ni into S- N-co-doped nanoplate (Ni NPs@SN-CNP) has synthesized pyrolysis Ni-MOF precursor. NPs@SN-CNP exhibits superior performance with an overpotential 256 mV attain 10 mA cm-2 low Tafel slope value 95 dec-1. Moreover, self-assembled overall-water-splitting cell NPs@SN-CNP/NF||Pt-C/NF achieves potential 1.56 V at high cycling stability least h. improvement this benefit from its large surface area, unique morphology, nanostructure electrocatalyst. This study presents novel simple approach designing OER
Language: Английский
Citations
0Chemical Engineering Journal, Journal Year: 2025, Volume and Issue: unknown, P. 160565 - 160565
Published: Feb. 1, 2025
Language: Английский
Citations
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