Construct wave-like structure on the anode surface for achieving controllable zinc deposition in aqueous zinc-ion batteries

Journal of Energy Storage, Journal Year: 2025, Volume and Issue: 115, P. 115991 - 115991

Published: Feb. 27, 2025

Language: Английский

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Metal-organic frameworks (MOFs) in aqueous batteries (ABs): unlocking potential through innovative materials design

Science China Chemistry, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 8, 2025

Language: Английский

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2D Conjugated Metal–Organic Frameworks Bearing Large Pore Apertures and Multiple Active Sites for High‐Performance Aqueous Dual‐Ion Batteries

Angewandte Chemie International Edition, Journal Year: 2024, Volume and Issue: 63(29)

Published: April 26, 2024

Abstract 2D conjugated metal–organic frameworks (2D c ‐MOFs) with large pore sizes and high surface areas are advantageous for adsorbing iodine species to enhance the electrochemical performance of aqueous dual‐ion batteries (ADIBs). However, most reported ‐MOFs feature microporous structures, few examples exhibiting mesoporous characteristics. Herein, we developed two ‐MOFs, namely PA‐TAPA−Cu‐MOF PA‐PyTTA−Cu‐MOF, using newly designed arylimide based multitopic catechol ligands (6OH‐PA‐TAPA 8OH‐PA‐PyTTA). Notably, exhibits largest (3.9 nm) among all ‐MOFs. Furthermore, demonstrated that these can serve as promising cathode host materials polyiodides in ADIBs first time. The incorporation triphenylamine moieties resulted a higher specific capacity (423.4 mAh g −1 after 100 cycles at 1.0 A ) superior cycling performance, retaining 96 % over 1000 10 compared PA‐PyTTA−Cu‐MOF. Our comparative analysis revealed increased number N anchoring sites larger size facilitate efficient conversion I 3 − , supported by spectroscopic electrochemistry density functional theory calculations.

Language: Английский

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Porous zinc metal anodes for aqueous zinc-ion batteries: Advances and prospectives

Energy Materials and Devices, Journal Year: 2024, Volume and Issue: 2(3), P. 9370040 - 9370040

Published: May 27, 2024

The intensifying challenges posed by climate change and the depletion of fossil fuels have spurred concerted global efforts to develop alternative energy storage solutions. Aqueous zinc-ion batteries (AZIBs) emerged as promising candidates for large-scale electrochemical systems, owing their intrinsic safety, cost-effectiveness environmental sustainability. However, persistent issue Zn dendrite growth poses a significant challenge performance improvements commercial viability AZIBs. use three-dimensional porous anodes instead planar plates has been demonstrated an effective strategy regulate deposition/stripping behavior Zn²⁺ ions, thereby inhibiting growth. Here, we summarize merits provide comprehensive overview recent advancements in engineering metal anodes, with particular emphasis on structural orderliness critical role structure modulation enhancing battery performance. Furthermore, present strategic insights into design aiming facilitate practical implementation AZIBs grid-scale applications.

Language: Английский

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In Situ Formation of 3D ZIF‐8/MXene Composite Coating for High‐Performance Zinc‐Iodine Batteries

Advanced Functional Materials, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 5, 2025

Abstract Aqueous Zn batteries have garnered a great deal of attention owing to environmental benefits, intrinsic safety, and cost‐effectiveness. However, the commercial viability these is hindered by anode issues, including dendrite formation side reactions. Herein, authors modulate deposition behavior 2+ ions through 3D ZIF‐8@MXene (Z@M) composite coating. The Z@M coating can effectively reduce contact area with electrolyte, inhibiting hydrogen evolution reaction corrosion. Notably, theoretical calculations in situ experimental observations reveal that dual coordination mechanism MXene ZIF‐8 significantly improves adsorption energy atoms. This improved capacity capture will promote desolvation hydrated ions, resulting dendrite‐free process. Therefore, symmetry cell, Z@M‐Zn demonstrates an impressive cycle life 1050 h at 1 mA cm −2 . When applies aqueous Zn‐I 2 battery, remarkable lifespan over 2400 cycles 5 C. work provides straightforward approach designing reversible anode, offering promising potential for broader applications across various metal‐based systems.

Language: Английский

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Engineering interfaces of zinc metal anode for stable batteries

Chemical Engineering Journal, Journal Year: 2024, Volume and Issue: 491, P. 152050 - 152050

Published: May 8, 2024

Language: Английский

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Superelastic hydrogel electrolyte incorporating helical protein molecules as zinc ion transport pathways to enhance cycling stability of zinc metal batteries

Energy & Environmental Science, Journal Year: 2024, Volume and Issue: unknown

Published: Jan. 1, 2024

A superelastic, high ionic conductivity and environment-friendly hydrogel electrolyte is developed based on the unique advantages of α-helical proteins.

Language: Английский

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Metal-organic framework based composite polymer electrolytes with hierarchical pores and hydrogen bond network for efficient lithium-ion transport channels in solid-state batteries

Journal of Power Sources, Journal Year: 2025, Volume and Issue: 635, P. 236513 - 236513

Published: Feb. 16, 2025

Language: Английский

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Terminal Active Oxygen Enriched Ldhs with Zincophilic Sites as a Versatile Interface Layer for Highly Reversible Zinc Metal Anodes

Published: Jan. 1, 2025

Language: Английский

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Manipulating oriented crystal growth of Zn via lattice-matched and zincophilic MXene nanoarrays towards dendrite-free Zn batteries

Journal of Colloid and Interface Science, Journal Year: 2025, Volume and Issue: 691, P. 137433 - 137433

Published: March 24, 2025

Language: Английский

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