Metal–Organic Frameworks and Derivative Materials in Perovskite Solar Cells: Recent Advances, Emerging Trends, and Perspectives DOI
Syed Afaq Ali Shah, Muhammad Hassan Sayyad, Zhongyi Guo

et al.

Solar RRL, Journal Year: 2024, Volume and Issue: unknown

Published: Oct. 30, 2024

The power conversion efficiency (PCE) of perovskite solar cells (PSCs) has reached an impressive value 26.1%. While several initiatives such as structural modification and fabrication techniques helped steadily increase the PCE stability PSCs in recent years, incorporation metal–organic frameworks (MOFs) stands out among other innovations emerged a promising path forward to make this technology front‐runner for realizing next‐generation low‐cost photovoltaic technologies. Owing their unique physiochemical properties extraordinary advantages large specific surface area tunable pore structures, incorporating them as/in different functional layers endows devices with optoelectronic properties. This article reviews latest research practices adapted integrating MOFs derivative materials into constituent blocks photoactive absorber, electron‐transport layer, hole‐transport interfacial layer. Notably, special emphasis is placed on aspect improvement by materials. Also, potential lead absorbents highlighted. Finally, outlook critical challenges faced future perspectives employing light commercialization provided.

Language: Английский

Inhibited superoxide‐induced halide oxidation with a bioactive factor for stabilized inorganic perovskite solar cells DOI Creative Commons
Xingxing Duan, Jialong Duan,

Naimin Liu

et al.

SusMat, Journal Year: 2024, Volume and Issue: 4(4)

Published: July 29, 2024

Abstract Active oxygen highly affects the efficiency and stability of perovskite solar cells (PSCs) owing to capacity either passivate defects or decompose lattice. To better understand in‐depth interaction, we demonstrate for first time that photooxidation mechanism in all‐inorganic film dominates phase deterioration kinetics by forming superoxide species presence light oxygen, which is significantly different from organic‒inorganic hybrid even tin‐based perovskites. In perovskites, prefer oxidize longer weaker Pb‒I bond PbO I 2 , leaving much stable CsPbBr 3 phase. From this chemical proof‐of‐concept, employ an organic bioactive factor, Tanshinone IIA, as a sweeper enhance environmental tolerance inorganic perovskite, serving “skincare” agent anti‐aging organisms. Combined with another key point on healing defective lattice, best carbon‐based CsPbI Br cell delivers high 15.12% superior against light, humidity, heat attacks. This method also applicable p‒i‒n inverted (Cs 0.05 MA FA 0.9 )Pb(I 0.93 0.07 ) 23.46%. These findings not only help us decomposition mechanisms depth but provide potential strategy advanced PSC platforms.

Language: Английский

Citations

10

Heterocyclic and heteropolycyclic moieties in organic hole transport materials for perovskite solar cells: Design, synthesis, and performance DOI Creative Commons
Shakil N. Afraj,

Arulmozhi Velusamy,

Ming‐Chou Chen

et al.

Coordination Chemistry Reviews, Journal Year: 2025, Volume and Issue: 532, P. 216500 - 216500

Published: Feb. 20, 2025

Language: Английский

Citations

1

Effective n-type de-doping of perovskite surface via defect passivation and improved film crystallization for high-efficiency inorganic solar cells DOI
Hui Li, Jialong Duan,

Naimin Liu

et al.

Journal of Materials Chemistry A, Journal Year: 2024, Volume and Issue: 12(34), P. 23067 - 23075

Published: Jan. 1, 2024

An n/n − homojunction at the top perovskite/carbon interface is realized by doping natural additive for accelerating charge extraction and suppressing carrier nonradiative recombination in carbon-based CsPbI 2 perovskite solar cells.

Language: Английский

Citations

6

Large-Area Perovskite Solar Modules Based on Uniformity Engineering of Perovskite Films: The Critical Role of Methyldiphenylphosphine Oxide Additive DOI

Yaling Han,

Jing Liu, Pengfei Wang

et al.

ACS Applied Materials & Interfaces, Journal Year: 2024, Volume and Issue: 16(30), P. 39312 - 39320

Published: July 22, 2024

Perovskite solar cells (PSCs) have led to distinguished achievements and become one of the state-of-the-art photovoltaic technologies. Undoubtedly, reliable preparation large area high-quality perovskite (PVK) films with uniform optoelectronic properties has a critical challenging task transition PSCs from lab market. Here, methyldiphenylphosphine oxide (MDPPO) is employed as an additive in PVK precursor solution promote conductivity carrier transport films. More important, check its compatibility upscaling process, MDPPO strategy was further applied doctor-blade large-area As result, benefit favorable role additive, power conversion efficiencies (PCEs) small-area reach 23.85% superb open circuit voltage (

Language: Английский

Citations

3

Indium-less and indium-free inverted perovskite solar cells using sputtered tin oxide transparent electrodes DOI

B H Chen,

Linpeng Yao, Zerong Li

et al.

Solar Energy, Journal Year: 2025, Volume and Issue: 287, P. 113235 - 113235

Published: Jan. 7, 2025

Language: Английский

Citations

0

Mitigating Face‐Sharing Octahedral Impurity Phases for Efficient FA‐Based Perovskite Photovoltaics DOI Open Access

Hanfeng Liu,

Baochao Zheng, Xingtao Wang

et al.

Advanced Functional Materials, Journal Year: 2025, Volume and Issue: unknown

Published: March 3, 2025

Abstract Formamidinium (FA) based perovskites have emerged as one of the most promising light‐absorber layers for both single‐junction and advanced top‐cell tandem photovoltaics, owing to their precisely engineered electronic bandgap exceptional stability. However, because mismatch FA cation intricate crystallization FA‐based perovskite, formation an impurity phase is inevitable, which reduces efficiency Herein, a N‐Phenyl‐bis(trifluoromethanesulfonimide) (NPTFSI)‐assisted method presented mitigate phase, i.e., face‐sharing octahedra, achieve pure stable perovskite. Comprehensive characterization shows that addition NPTFSI increases energy octahedra while reducing corner‐sharing. This effectively suppresses in perovskite films. Suppressing these octahedral phases not only enhances stability films under heating or humidity conditions but also improves carrier dynamics. Finally, champion devices deliver significantly enhanced from 23.23% 25.74%. Moreover, PSCs exhibit excellent stability: retain 96% initial after over 500 h maximum power point test.

Language: Английский

Citations

0

Decoding recombination dynamics in perovskite solar cells: an in-depth critical review DOI
Ramkrishna Das Adhikari, Mayur Jagdishbhai Patel, Himangshu Baishya

et al.

Chemical Society Reviews, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 1, 2025

This review systematically analyses the recombination pathways in PSCs, unveils cutting-edge suppression strategies, and underscores potential of ML optimizing device performance expediting commercial integration.

Language: Английский

Citations

0

Revealing the Critical Role of Electron‐Withdrawing Cores in Bulk Passivation of Diammonium Ligands Toward High‐Performance Perovskite Solar Cells DOI Open Access
Jiayu Hu, Ying Qiao, Jie Zeng

et al.

Advanced Functional Materials, Journal Year: 2025, Volume and Issue: unknown

Published: March 20, 2025

Abstract Diammonium derivatives with electron‐withdrawing cores of cyclohexyl or phenyl have demonstrated enormous potential in achieving high‐performance perovskite solar cells. Nevertheless, the critical role these diammonium passivation on device performance is yet to be elucidated. Herein, two kinds ligands 1, 4‐cyclohexyldimethylammonium diiodide (CyDMADI) and 4‐phenyldimethylammonium (PhDMADI) are introduced into precursor for bulk passivation. The PhDMADI system exhibits a stronger unit comparison CyDMADI core, thus resulting enhanced electrostatic interaction between uncoordinated Pb 2+ groups hydrogen bonds I─Pb skeleton. Such strengthened interactions effectively inhibit generation trap states therefore significantly decrease non‐radiative recombination. PhDMADI‐passivated film demonstrates mitigated microstrain decreased grain boundary grooves (GBGs) compared CyDMADI‐based counterpart. Simultaneously, treatment can efficiently slow down hot‐carriers cooling dynamics process, benefiting transfer hot‐carriers. Consequently, achieves an impressive efficiency 26.04%, along excellent operating stability which retains 90% its initial after 1100 h tracking at maximum power point under continuous one sun illumination.

Language: Английский

Citations

0

Enhancing Stability in 1.78 eV Wide-Bandgap Inverted Perovskite Solar Cells via GlyHCl-Induced Inhibition of Phase Segregation DOI
Xinyu Zhao, Weisheng Li,

Xuefei Jia

et al.

Materials Today Communications, Journal Year: 2025, Volume and Issue: unknown, P. 112294 - 112294

Published: March 1, 2025

Language: Английский

Citations

0

Self-aggregation of the Interfacial Passivation Layer from Ionic Additive-Stabilized PbI2 Film for High-Performance Perovskite Solar Cells DOI
Qin Cao, Yan Wang,

Xuwu Xiang

et al.

ACS Sustainable Chemistry & Engineering, Journal Year: 2025, Volume and Issue: unknown

Published: March 27, 2025

Language: Английский

Citations

0