Science for energy and environment.,
Journal Year:
2024,
Volume and Issue:
unknown, P. 10 - 10
Published: Dec. 10, 2024
Review
Recent
Progress
on
Layered
Double
Hydroxides
for
Electrocatalytic
Small
Molecules
Oxidation
to
Synthesize
High-Value
Chemicals
and
Degrade
Pollutants
Zi-Qi
Ge
1
Chao
Chu
2
Cong
Wang
3
Ruchun
Li
4,*
Jingwei
2,*
San
Ping
Jiang
Jilin
Joint
Technology
Innovation
Laboratory
of
Developing
Utilizing
Materials
Reducing
Pollution
Carbon
Emissions,
College
Engineering,
Normal
University,
Siping
136000,
China
National
Energy
Key
New
Hydrogen-Ammonia
Technologies,
Foshan
Xianhu
Laboratory,
528216,
Bingtuan
Development
Institute,
Shihezi
832000,
4
Faculty
Chemistry
Chemical
Yunnan
Kunming
650500,
*
Correspondence:
[email protected]
(S.
P.
J.);
[email protected]
(J.
L.);
[email protected]
(R.
L.)
Received:
25
October
2025;
Revised:
12
November
2024;
Accepted:
6
December
Published:
10
2024
Abstract:
Researchers
worldwide
are
developing
innovative
luminescent
systems
with
exceptional
features
like
high
sensitivity.
Luminescent
frameworks
based
aggregation-induced
emission
(AIE)
have
emerged
as
promising
candidates
various
applications.
Over
the
past
decade,
porous
materials
metal-organic
cages
(MOCs)
incorporating
AIE
luminogens
(AIEgens)
demonstrated
performance.
Chirality
plays
a
significant
role
in
specific
non-racemic
systems,
particularly
circularly
polarized
luminescence
(CPL).
Chiral
organic
coordinated
metals,
including
MOCs,
gained
importance
they
combine
ligands
coordination-bonded
metal
centers,
enabling
design
novel
structures
CPL.
These
shown
exciting
potential
applications
fields
CPL-OLED,
chiral
recognition,
sensing.
This
review
article
provides
an
overview
recent
progress
emissive
materials,
specifically
their
possible
Additionally,
focuses
AIEgen-based
cages,
CPL-active
non-AIEgen-based
practical
sensing
enantioselectivity,
future
prospects.
challenges
AIE-based
POCs
MOCs
include
limited
stability,
affecting
use
wide-surface
thin
films,
need
understand
molecular
structure
topology
impacts.
Future
efforts
should
enhance
efficiency
explore
sensing,
supramolecular
assemblies,
bioimaging,
optoelectronics,
driving
innovation
smart
materials.
ChemSusChem,
Journal Year:
2024,
Volume and Issue:
18(3)
Published: Sept. 16, 2024
Abstract
2,5‐Furandicarboxylic
acid
(FDCA)
is
a
class
of
valuable
biomass‐based
platform
compounds.
The
creation
FDCA
involves
the
catalytic
oxidation
5‐hydroxymethylfurfural
(HMF).
As
novel
method,
electrocatalysis
has
been
utilized
in
reaction
(HMFOR).
Common
noble
metal
catalysts
show
activity,
which
limited
by
price
and
conditions.
Non‐noble
catalyst
known
for
its
environmental
friendliness,
affordability
high
efficiency.
development
energy
efficient
non‐noble
plays
crucial
role
enhancing
HMFOR
process.
It
can
greatly
upgrade
demand
industrial
production,
important
research
significance
electrocatalytic
HMF.
In
this
paper,
mechanism
HMF
undergoes
to
produce
are
elaborately
summarized.
There
two
pathways
mechanisms
discussed
deeply.
addition,
speculation
on
response
electrode
potential
presented
paper.
main
electrocatalysts
currently
used
classified
summarized
targeting
element
species.
Finally,
paper
focus
mechanistic
effects
reaction,
provide
present
prospects
challenges
The Chemical Record,
Journal Year:
2025,
Volume and Issue:
unknown
Published: March 3, 2025
Abstract
The
electrocatalytic
upgrading
of
5‐hydroxymethylfurfural
(HMF,
5‐(Hydroxymethyl)
furan‐2‐carbaldehyde)
has
emerged
as
a
renewable
and
environmentally
friendly
means
for
the
production
high‐value
chemicals,
with
oxidation
product
furan‐2,5‐dicarboxylic
acid
(FDCA,
2,5‐furandicarboxylic
acid)
possessing
economic
viability
in
substituting
terephthalic
polymer
synthesis.
This
article
reviews
recent
advancements
selective
HMF
to
FDCA,
including
reaction
pathways,
mechanisms,
well
activity
descriptors
(HMFOR),
alongside
advanced
operando
characterization
techniques.
Subsequently,
representative
HMFOR
catalysts,
encompassing
noble
metal,
non‐noble
transition
metal‐based
catalysts
metal
free‐based
are
presented.
Then
strategies
regulating
longevity
were
introduced,
followed
by
an
exploration
future
prospects
development
catalysts.