Recent Progress on Layered Double Hydroxides for Electrocatalytic Small Molecules Oxidation to Synthesize High-Value Chemicals and Degrade Pollutants DOI Creative Commons
Z. W. Ge, Chao‐Hsien Chu, Cong Wang

et al.

Science for energy and environment., Journal Year: 2024, Volume and Issue: unknown, P. 10 - 10

Published: Dec. 10, 2024

Review Recent Progress on Layered Double Hydroxides for Electrocatalytic Small Molecules Oxidation to Synthesize High-Value Chemicals and Degrade Pollutants Zi-Qi Ge 1 Chao Chu 2 Cong Wang 3 Ruchun Li 4,* Jingwei 2,* San Ping Jiang Jilin Joint Technology Innovation Laboratory of Developing Utilizing Materials Reducing Pollution Carbon Emissions, College Engineering, Normal University, Siping 136000, China National Energy Key New Hydrogen-Ammonia Technologies, Foshan Xianhu Laboratory, 528216, Bingtuan Development Institute, Shihezi 832000, 4 Faculty Chemistry Chemical Yunnan Kunming 650500, * Correspondence: [email protected] (S. P. J.); [email protected] (J. L.); [email protected] (R. L.) Received: 25 October 2025; Revised: 12 November 2024; Accepted: 6 December Published: 10 2024 Abstract: Researchers worldwide are developing innovative luminescent systems with exceptional features like high sensitivity. Luminescent frameworks based aggregation-induced emission (AIE) have emerged as promising candidates various applications. Over the past decade, porous materials metal-organic cages (MOCs) incorporating AIE luminogens (AIEgens) demonstrated performance. Chirality plays a significant role in specific non-racemic systems, particularly circularly polarized luminescence (CPL). Chiral organic coordinated metals, including MOCs, gained importance they combine ligands coordination-bonded metal centers, enabling design novel structures CPL. These shown exciting potential applications fields CPL-OLED, chiral recognition, sensing. This review article provides an overview recent progress emissive materials, specifically their possible Additionally, focuses AIEgen-based cages, CPL-active non-AIEgen-based practical sensing enantioselectivity, future prospects. challenges AIE-based POCs MOCs include limited stability, affecting use wide-surface thin films, need understand molecular structure topology impacts. Future efforts should enhance efficiency explore sensing, supramolecular assemblies, bioimaging, optoelectronics, driving innovation smart materials.

Language: Английский

Advances in rare earth catalysts for small molecule electrosynthesis☆ DOI

Junfeng Du,

Jing Yu,

Chaohui Guan

et al.

Journal of Rare Earths, Journal Year: 2025, Volume and Issue: unknown

Published: Feb. 1, 2025

Language: Английский

Citations

1

Non‐noble metal catalysts for electrooxidation of 5‐hydroxymethylfurfural DOI

Yanfeng Duan,

Xuebin Lu, Fan Ouyang

et al.

ChemSusChem, Journal Year: 2024, Volume and Issue: 18(3)

Published: Sept. 16, 2024

Abstract 2,5‐Furandicarboxylic acid (FDCA) is a class of valuable biomass‐based platform compounds. The creation FDCA involves the catalytic oxidation 5‐hydroxymethylfurfural (HMF). As novel method, electrocatalysis has been utilized in reaction (HMFOR). Common noble metal catalysts show activity, which limited by price and conditions. Non‐noble catalyst known for its environmental friendliness, affordability high efficiency. development energy efficient non‐noble plays crucial role enhancing HMFOR process. It can greatly upgrade demand industrial production, important research significance electrocatalytic HMF. In this paper, mechanism HMF undergoes to produce are elaborately summarized. There two pathways mechanisms discussed deeply. addition, speculation on response electrode potential presented paper. main electrocatalysts currently used classified summarized targeting element species. Finally, paper focus mechanistic effects reaction, provide present prospects challenges

Language: Английский

Citations

5

Modulating Oxygen Defects in Co3O4 via Electrochemical Reduction for Efficient 5-Hydroxymethylfurfural Electrooxidation DOI
Chenyu Zhou, Zuyun He,

Sixian Yang

et al.

Energy & Fuels, Journal Year: 2025, Volume and Issue: unknown

Published: Feb. 11, 2025

Language: Английский

Citations

0

Formaldehyde oxidation reaction enhanced by interface engineering of Cu/Cu2O/Co(OH)2 composite electrocatalyst for bipolar hydrogen production DOI

Zi Qiang,

Chang Bao Han,

Wen Kang Zhao

et al.

Chemical Engineering Journal, Journal Year: 2025, Volume and Issue: unknown, P. 162568 - 162568

Published: April 1, 2025

Language: Английский

Citations

0

Reaction-induced reconstruction and redispersion of Ni@C catalyst for enhancing HMF electrooxidation DOI
Xinyu Liu, Yuhang Li, Mengli Zhou

et al.

Molecular Catalysis, Journal Year: 2025, Volume and Issue: 580, P. 115131 - 115131

Published: April 14, 2025

Language: Английский

Citations

0

Advances and Prospects of Selective Electrocatalytic Upgrading of 5‐Hydroxymethylfurfural to Furan‐2,5‐Dicarboxylic Acid DOI Open Access

Lianhua Chen,

Yang Liu

The Chemical Record, Journal Year: 2025, Volume and Issue: unknown

Published: March 3, 2025

Abstract The electrocatalytic upgrading of 5‐hydroxymethylfurfural (HMF, 5‐(Hydroxymethyl) furan‐2‐carbaldehyde) has emerged as a renewable and environmentally friendly means for the production high‐value chemicals, with oxidation product furan‐2,5‐dicarboxylic acid (FDCA, 2,5‐furandicarboxylic acid) possessing economic viability in substituting terephthalic polymer synthesis. This article reviews recent advancements selective HMF to FDCA, including reaction pathways, mechanisms, well activity descriptors (HMFOR), alongside advanced operando characterization techniques. Subsequently, representative HMFOR catalysts, encompassing noble metal, non‐noble transition metal‐based catalysts metal free‐based are presented. Then strategies regulating longevity were introduced, followed by an exploration future prospects development catalysts.

Language: Английский

Citations

0

Reaction-Induced Reconstruction and Redispersion of Ni@C Catalyst for Enhancing Hmf Electrooxidation DOI
Xinyu Liu, Yuhang Li, Mengli Zhou

et al.

Published: Jan. 1, 2025

Language: Английский

Citations

0

Interfacial molybdate-enabled electric field deconfinement to passivate water oxidation for wide-potential biomass electrooxidation DOI
Keping Wang, Mei Wu, Yan Zhang

et al.

Journal of Colloid and Interface Science, Journal Year: 2025, Volume and Issue: 691, P. 137390 - 137390

Published: March 20, 2025

Language: Английский

Citations

0

Refining Electrocatalyst Design for 5-Hydroxymethylfurfural Oxidation: Insights into Electrooxidation Mechanisms, Structure–Property Correlations, and Optimization Strategies DOI
Xupo Liu, Jianbo Tang, Ye Chen

et al.

ACS Catalysis, Journal Year: 2025, Volume and Issue: unknown, P. 7308 - 7339

Published: April 18, 2025

Language: Английский

Citations

0

Roles of oxygen vacancies in layered double hydroxides-based catalysts for wastewater remediation: fundamentals and prospects DOI
Xiufang He, Frank Marken, Alberto Vertova

et al.

Journal of Environmental Management, Journal Year: 2025, Volume and Issue: 385, P. 125583 - 125583

Published: May 6, 2025

Language: Английский

Citations

0