A phosphite derivative with stronger HF elimination ability as an additive for Li-rich based lithium-ion batteries at elevated temperatures DOI Creative Commons

Xiangzhen Zheng,

Tao Huang, Ying Pan

et al.

RSC Applied Interfaces, Journal Year: 2024, Volume and Issue: unknown

Published: Jan. 1, 2024

TMSPi, TMSPE, and TEP are comparatively evaluated as additives for high temperature application of a Li-rich lithium battery under voltage TMSPE shows the best electrochemical performance three phosphite-based additives.

Language: Английский

Triphase Heterogeneous Electrocatalysts of Ni and Co for High‐Performing Li‐O2 Batteries DOI Creative Commons
Shadeepa Karunarathne, Chanaka Sandaruwan, Yasun Y. Kannangara

et al.

EcoMat, Journal Year: 2025, Volume and Issue: 7(3)

Published: Feb. 16, 2025

ABSTRACT The limited energy density of the current Li‐ion batteries restricts electrification transportation to small‐ and medium‐scale vehicles. On contrary, Li‐O 2 (LOBs), with their significantly higher theoretical density, can power heavy‐duty transportation, if sluggish electrode kinetics in these devices be substantially improved. use solid electrocatalysts at cathode is a viable strategy address this challenge, but fail provide sufficient discharge depths cyclability, primarily due formation film‐like product, Li₂O₂, on catalytic sites, which obstructs charge transport gas diffusion pathways. Here, we report that triphase heterogeneous catalyst comprising NiCoP, NiCo S 4 , O assembled into hierarchical hollow architecture (NC‐3@Ni), efficiently modulates morphology orientation facilitating sheet‐like growth Li perpendicular surface. These modifications enable LOB deliver high capacity 25 162 mAh g −1 400 mA along impressive cycling performance, achieving 270 cycles depth 1000 exceeding 1350 h continuous operation. This promising performance attributed presence individual electrophilic nucleophilic phases within microstructure catalyst, collectively promoting . image

Language: Английский

Citations

0
Tuning anionic bands and lattice stability by short-range disorder at nanoscale for ultrastable Co-free Li-rich cathode DOI
Ruiqi Zhao, Xingchen Song, Ziheng Zhang

et al.

Science China Chemistry, Journal Year: 2025, Volume and Issue: unknown

Published: Feb. 24, 2025

Language: Английский

Citations

0
Fundamentals, Status and Promise of Li‐Rich Layered Oxides for Energy‐Dense Li‐Ion Batteries DOI Open Access
Xiaoqiong Li,

Shunli Yu,

Jiming Peng

et al.

Small, Journal Year: 2025, Volume and Issue: unknown

Published: March 17, 2025

Abstract Li‐ion batteries (LIBs) are the dominant electrochemical energy storage devices in global society, which cathode materials key components. As a requirement for higher energy‐dense LIBs, Li‐rich layered oxides (LLO) cathodes that can provide specific capacity urgently needed. However, LLO still face several significant challenges before bringing these to market. In this Review, fundamental understanding of is described, with focus on physical structure‐electrochemical property relationships. Specifically, various strategies toward reversible anionic redox discussed, highlighting approaches take basic structure battery into account. addition, application all‐solid‐state and consider prospects assessed.

Language: Английский

Citations

0
Ethylene Carbonate-Free Electrolytes for High Voltage Lithium-Ion Batteries: Progress and Perspectives DOI

Congyu Xu,

Liang Yuan, Ruochen Zhang

et al.

Energy & Fuels, Journal Year: 2024, Volume and Issue: unknown

Published: Sept. 17, 2024

Language: Английский

Citations

1
Advanced Methods for Characterizing Battery Interfaces: Towards a Comprehensive Understanding of Interfacial Evolution in Modern Batteries DOI
Israel Temprano, Javier Carrasco, Matthieu Bugnet

et al.

Energy storage materials, Journal Year: 2024, Volume and Issue: 73, P. 103794 - 103794

Published: Oct. 3, 2024

Language: Английский

Citations

1
The chiral nematic liquid crystal of hydroxypropyl methylcellulose coated on separator: Break through safety of LIBs with high electrochemical performances DOI
Xichang Wang, Xi Xu,

Silin Pu

et al.

Journal of Colloid and Interface Science, Journal Year: 2024, Volume and Issue: 682, P. 784 - 794

Published: Dec. 6, 2024

Language: Английский

Citations

1
Regulating Microcosmic Crystal Structure of Hpmc Coated on Separator: Break Through Safety of Libs with High Electrochemical Performances DOI
Xichang Wang, Xi Xu,

Shuping Pu

et al.

Published: Jan. 1, 2024

Language: Английский

Citations

0
Active–Inactive Molten Salt Synthesis of Li- and Mn-Rich Layered Oxide Single Crystals as Cathode Materials for All-Solid-State Batteries DOI
Sung Hee Choi,

Gawon Song,

Kyobin Park

et al.

Chemistry of Materials, Journal Year: 2024, Volume and Issue: 36(19), P. 9666 - 9676

Published: Sept. 27, 2024

Language: Английский

Citations

0
A phosphite derivative with stronger HF elimination ability as an additive for Li-rich based lithium-ion batteries at elevated temperatures DOI Creative Commons

Xiangzhen Zheng,

Tao Huang, Ying Pan

et al.

RSC Applied Interfaces, Journal Year: 2024, Volume and Issue: unknown

Published: Jan. 1, 2024

TMSPi, TMSPE, and TEP are comparatively evaluated as additives for high temperature application of a Li-rich lithium battery under voltage TMSPE shows the best electrochemical performance three phosphite-based additives.

Language: Английский

Citations

0