Promoted cycling performance of metallic phosphide cathode for Na O2 batteries DOI
Y. Huang, Min Gan,

Shaofeng Ni

et al.

Journal of Energy Storage, Journal Year: 2024, Volume and Issue: 103, P. 114389 - 114389

Published: Nov. 1, 2024

Language: Английский

Triphase Heterogeneous Electrocatalysts of Ni and Co for High‐Performing Li‐O2 Batteries DOI Creative Commons
Shadeepa Karunarathne, Chanaka Sandaruwan, Yasun Y. Kannangara

et al.

EcoMat, Journal Year: 2025, Volume and Issue: 7(3)

Published: Feb. 16, 2025

ABSTRACT The limited energy density of the current Li‐ion batteries restricts electrification transportation to small‐ and medium‐scale vehicles. On contrary, Li‐O 2 (LOBs), with their significantly higher theoretical density, can power heavy‐duty transportation, if sluggish electrode kinetics in these devices be substantially improved. use solid electrocatalysts at cathode is a viable strategy address this challenge, but fail provide sufficient discharge depths cyclability, primarily due formation film‐like product, Li₂O₂, on catalytic sites, which obstructs charge transport gas diffusion pathways. Here, we report that triphase heterogeneous catalyst comprising NiCoP, NiCo S 4 , O assembled into hierarchical hollow architecture (NC‐3@Ni), efficiently modulates morphology orientation facilitating sheet‐like growth Li perpendicular surface. These modifications enable LOB deliver high capacity 25 162 mAh g −1 400 mA along impressive cycling performance, achieving 270 cycles depth 1000 exceeding 1350 h continuous operation. This promising performance attributed presence individual electrophilic nucleophilic phases within microstructure catalyst, collectively promoting . image

Language: Английский

Citations

0
Defect mechanism of the BixSb2−xTe3 alloy catalyst for lithium–oxygen battery applications DOI

Songyan Liu,

Xujie Song,

Jianhua Zhou

et al.

Journal of Materials Chemistry C, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 1, 2025

The concentration of antisite defects and holes is modulated by adjusting the molar ratio Bi Sb in 2D layered x 2− Te 3 cathode material, which act as catalytic sites to enhance electrochemical performance LOBs.

Language: Английский

Citations

0
Defective Zn1-xCuxS nanosheet as efficient and durable cathode catalyst for photo-assisted Li-O2 batteries DOI
Chao Dang, Yiping Liu, Yuxin Huang

et al.

Chemical Engineering Journal, Journal Year: 2025, Volume and Issue: unknown, P. 161117 - 161117

Published: Feb. 1, 2025

Language: Английский

Citations

0
Coherent Single‐Atom Dipole–Dipole Coupling Mediates Holistic Regulation of K+ Migration for Superior Energy Storage and Dendrite‐Free Metal Deposition DOI Open Access
Yi‐Ju Tseng, Hsing‐Yu Tuan

Advanced Functional Materials, Journal Year: 2025, Volume and Issue: unknown

Published: March 5, 2025

Abstract Potassium‐based batteries, including potassium‐ion (PIBs) and potassium metal batteries (PMBs), are gaining attention as alternatives to lithium‐ion (LIBs). However, potassium's large ionic radius (1.38 Å) reduces charge density, weakens solvation, increases energy barriers for K + diffusion, leading slower reaction kinetics, thicker solid electrolyte interphase (SEI) layers, dendrite formation. To address these challenges, a novel single‐atom Fe‐N 4 dipole–dipole coupling (SA.Fe) is proposed. The unique coordination highly conductive Ketjen black (KB) substrate establish rapid horizontal electron transfer network, enhancing electrode interface reactions. Moreover, Fe‐N‐C generates short‐range polar electric field, improving affinity diffusion. This coherent effectively regulates migration, significantly kinetics lowering diffusion barriers. SA.Fe anode delivers high reversible capacities (446.3 mAh g −1 ) exceptional durability (10 000 cycles at 2.0 A in PIBs, alongside remarkable stability (600 0.5 mA cm −2 fast (K metal) deposition without formation PMBs. study highlights the potential of dipole efficient storage dendrite‐free offering promising pathway next‐generation potassium‐based systems.

Language: Английский

Citations

0
Recent advancements in hexacyanoferrate-based electrode materials for supercapacitor applications: A comprehensive review DOI
Rajangam Vinodh, V. Ramkumar, Chandu V.V. Muralee Gopi

et al.

Journal of Energy Storage, Journal Year: 2024, Volume and Issue: 103, P. 114160 - 114160

Published: Oct. 24, 2024

Language: Английский

Citations

3
Upcycling Spent Lithium‐Ion Batteries: Constructing Bifunctional Catalysts Featuring Long‐Range Order and Short‐Range Disorder for Lithium‐Oxygen Batteries DOI
Yu Tian, Yongbin Xu, Shan Guo

et al.

Advanced Materials, Journal Year: 2025, Volume and Issue: unknown

Published: April 25, 2025

Abstract Upcycling of high‐value metals (M = Ni, Co, Mn) from spent ternary lithium‐ion batteries to the field lithium‐oxygen is highly appealing, yet remains a huge challenge. In particular, alloying recovered M components with Pt and applied as cathode catalysts have not been reported. Herein, fresh L1 2 ‐type 3 medium‐entropy intermetallic nanoparticle first proposed, confined on N‐doped carbon matrix (L1 ‐Pt (Ni 1/3 Co Mn )@N‐C) based 111 typed LiNi 1‐x‐y x y O cathode. This well‐defined catalyst combines both features long‐range order face‐centered cubic structure short‐range disorder in sites. The former contributes enhancing structural stability, latter further facilitates deeply activating catalytic activity Experiments theoretical results demonstrate that local coordination environment electronic distribution are fundamentally modulated via surrounding disordered atoms, which greatly optimize affinity toward oxygen‐containing intermediates facilitate deposition/decomposition kinetics thin‐film Li discharge products. Specifically, 1/3) @N‐C exhibits an ultra‐low overpotential 0.48 V achieves 220 cycles at 400 mA g −1 under 1000 mAh . work provides important insights for recycling into advanced catalyst‐related applications.

Language: Английский

Citations

0
Construction of Co3O4@NiMoO4 core-shell structure for high-current density photo-assisted lithium-oxygen battery DOI

Weiyu Fang,

Yuxuan Shen,

Mei Bai

et al.

Applied Surface Science, Journal Year: 2024, Volume and Issue: 681, P. 161551 - 161551

Published: Oct. 18, 2024

Language: Английский

Citations

3
Optimizing polysulfides adsorption and conversion via crystal-strain modulation for performance-enhanced Li-S batteries DOI

Naomie Beolle Songwe Selabi,

Yingke Zhou,

Lukang Che

et al.

Chemical Engineering Journal, Journal Year: 2024, Volume and Issue: unknown, P. 157724 - 157724

Published: Nov. 1, 2024

Language: Английский

Citations

2
Graphene oxide/carbon fiber composite structural supercapacitor with stable electrochemical performance under surface load bearing DOI
Zheng Zhang, Laifa Shen, Xin Xu

et al.

Advanced Composites and Hybrid Materials, Journal Year: 2024, Volume and Issue: 8(1)

Published: Nov. 30, 2024

Language: Английский

Citations

2
Constructing hollow flower-like molybdenum disulfide nanospheres/carbon nanospheres as anode with enhanced diffusion kinetics for lithium storage DOI
Liyuan Liu, Wei Du, Qi Zhang

et al.

Advanced Composites and Hybrid Materials, Journal Year: 2024, Volume and Issue: 7(6)

Published: Oct. 23, 2024

Language: Английский

Citations

1