In Situ Electrochemical Polymerized Bipolar-Type Poly(1,5-diaminonaphthalene) Cathode for High-Performance Aqueous Zinc-Organic Batteries DOI
Yanrong Wang, Chenxi Zheng,

Mengfan Zhao

et al.

ACS Applied Polymer Materials, Journal Year: 2024, Volume and Issue: unknown

Published: Nov. 28, 2024

Language: Английский

Promoted de-solvation effect and dendrite-free Zn deposition enabled by in-situ formed interphase layer for high-performance zinc-ion batteries DOI Open Access

Binxin Song,

Qiongqiong Lu, Xinyu Wang

et al.

Energy Materials, Journal Year: 2025, Volume and Issue: 5(3)

Published: Jan. 11, 2025

The use of aqueous electrolytes and Zn metal anodes in Zn-based energy storage systems provides several benefits, including competitive density, excellent safety, low cost. However, dendrites growth slow ion transfer at the electrode/electrolyte interphase reduce cycle stability rate capability anode. Herein, V2O5-x interface layer was rationally controllably constructed on surface through situ spontaneous redox reaction between V2O5 layer, with an optimized thickness, plays a crucial role screening de-solvation, leading to uniform dispersion Zn2+ ions dendrite-free morphology. Moreover, as transports V element low-valence state allows oxygen anions bind more easily Zn2+. This interaction enables fast diffusion channel interfacial layer. Consequently, symmetric cells V@Zn achieve stable plating/stripping for than 1400 h 1 mA cm-2. In particular, full cell paired cathode exhibits capacity nearly 275.9 g-1 5 A after 2500 cycles without obvious deterioration, further highlighting potential practical applications.

Language: Английский

Citations

3
Orbital and Electrical Dual Function of Polymer Intercalant for Promoting NH4+ Storage in Vanadium Oxide Anode DOI Creative Commons
Yue Zhang, Zihang Huang, Lei Lei

et al.

Advanced Energy Materials, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 26, 2025

Abstract Polymer‐intercalated metal oxides have attracted considerable attention for ammonium ions (NH 4 + ) storage due to their enhanced interlayer space, which, through the pillar effect, facilitates rapid and efficient transport of NH . However, understanding remains limited regarding how polymer intercalants affect intrinsic structure host materials, especially variations in atomic orbital electronic structural induced by intercalants. Herein, a polyaniline‐intercalated vanadium oxide (P‐VO x is developed and, first time, its behavior validated as an anode material. Using various spectroscopy techniques combined with theoretical simulation, changes are analyzed intercalant. Spectroscopy studies reveal that insertion polyaniline optimizes V 2 O 5 , promoting transition electrons 3d xy state increasing occupation t 2g orbital, thereby enhancing electrical conductivity. Computational results confirm P‐VO lowers migration barrier, electron/NH transfer. As result, electrode demonstrates outstanding capacity unprecedented long‐term cycling stability. This study provides new insights into intercalant underscores advantages polymer‐intercalated VO high‐performance storage.

Language: Английский

Citations

2
A high-entropy zero-strain V-based cathode for high performance aqueous zinc-ion batteries DOI
Xiang Ding, Jiabo Le,

Yibing Yang

et al.

Energy storage materials, Journal Year: 2025, Volume and Issue: 76, P. 104098 - 104098

Published: Feb. 7, 2025

Language: Английский

Citations

2
Chromium-doped tunnel-structured VO2(B) nanorods as high-capacity and stable cathode materials for aqueous zinc-ion batteries DOI
Xiaohong Chen,

Xuezhen Zhai,

Yongqi Wu

et al.

Journal of Energy Storage, Journal Year: 2025, Volume and Issue: 114, P. 115826 - 115826

Published: Feb. 14, 2025

Language: Английский

Citations

2
Ultrafast Tailoring Amorphous Zn0.25V2O5 with Precision‐Engineered Artificial Atomic‐Layer 1T′‐MoS2 Cathode Electrolyte Interphase for Advanced Aqueous Zinc‐Ion Batteries DOI
Chen Hu, Binjie Li, Kunkun Nie

et al.

Angewandte Chemie International Edition, Journal Year: 2024, Volume and Issue: 64(1)

Published: Sept. 30, 2024

Vanadium (V)-based oxides as cathode materials for aqueous zinc-ion batteries (AZIBs) still encounter challenges such sluggish Zn

Language: Английский

Citations

8
Advances on Defect Engineering of Niobium Pentoxide for Electrochemical Energy Storage DOI Open Access

Liaona She,

Dongye Liu,

Yin Zhao

et al.

Small, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 22, 2025

Abstract The reasonable design of advanced anode materials for electrochemical energy storage (EES) devices is crucial in expediting the progress renewable technologies. Nb 2 O 5 has attracted increasing research attention as an candidate. Defect engineering regarded a feasible approach to modulate local atomic configurations within . Therefore, introducing defects into considered be promising way enhance performance. However, there no systematic review on defect process. This systematically analyzes first crystal structures and mechanisms Subsequently, systematical summary latest advances EES presented, mainly focusing vacancy modulation, ion doping, planar defects, porosity, amorphization. Of particular note effects : improving electronic conductivity, accelerating diffusion, maintaining structural stability, active sites. further summarizes diverse methodologies inducing commonly used techniques characterization In conclusion, article proposes current challenges outlines future development prospects achieve high‐performance with both high power densities.

Language: Английский

Citations

1
Advancing aqueous zinc‐ion batteries with carbon dots: A comprehensive review DOI Creative Commons

Mingying Chen,

Junjie Ma,

Yanhong Feng

et al.

EcoEnergy, Journal Year: 2024, Volume and Issue: unknown

Published: Dec. 3, 2024

Abstract Recent years have witnessed a surge in research on aqueous zinc‐ion batteries (AZIBs) due to their low cost, stability, and exceptional electrochemical performance, among other advantages. However, practical manufacturing deployment of AZIBs been hindered by challenges such as energy density, significant precipitation‐related side reactions, slow ion migration, dendritic growth. Addressing these issues enhancing the application necessitates development novel materials. Carbon dots (CDs), with distinctive structure superior properties, represent an innovative class carbon‐based materials broad potential applications for optimizing AZIBs' performance. This study offers comprehensive review how CDs can address aforementioned AZIBs. It begins overview composition mechanism before delving into classification, preparation techniques, functionalization strategies CDs. The also thoroughly summarizes sophisticated roles modifiers electrolytes electrodes, both positive negative, briefly discusses membranes. Additionally, it provides summary current difficulties encountered utilizing aims provide insights guidance designing next generation high‐performance

Language: Английский

Citations

5
Electrochemical activation of vanadium-based cathodes in aqueous zinc-ion batteries: Advances, challenges and prospects DOI

Shile Liu,

Yanxin Liao,

Tianrui Liu

et al.

Energy storage materials, Journal Year: 2024, Volume and Issue: unknown, P. 103799 - 103799

Published: Sept. 1, 2024

Language: Английский

Citations

4
Ammonium ion storage in hydrated vanadium oxide for energy storage DOI
Konica Roy,

Ritupurna Baishya,

Deni Shidqi K.

et al.

Journal of Alloys and Compounds, Journal Year: 2024, Volume and Issue: unknown, P. 177915 - 177915

Published: Dec. 1, 2024

Language: Английский

Citations

3
Cationic Vacancy Modulation of Mn3O4 as a Superior Cathode for Durable Aqueous Zinc‐Ion Batteries DOI
Shenzhen Deng, Bingang Xu, Xinlong Liu

et al.

Advanced Functional Materials, Journal Year: 2024, Volume and Issue: 35(3)

Published: Sept. 26, 2024

Abstract Aqueous zinc‐ion batteries (AZIBs) have attracted more and attention owing to their high safety, low cost, environmental friendliness. Mn‐based materials are considered as one of the most promising cathode for AZIBs because output voltage, eco‐friendliness, abundance. However, electrochemical activity manganese dissolution Mn 3 O 4 lead specific capacity inferior cycling stability, hindering its practical applications. Herein, a facile low‐cost strategy is designed that combines cationic vacancy modulation with ion‐confinement effect in synergistic action boost zinc ion energy storage capability inert (designated V ‐Mn @C). The endows active sites, resulting an increased capacity. Meanwhile, inhibited via carbon framework, thereby improving stability cathode. Consequently, developed Zn/V @C deliver 280.9 mAh g −1 98.4% retention after 100 cycles at 0.1 A . More importantly, cathodes maintain superior 5000 nearly 100% 1

Language: Английский

Citations

3