Small,
Journal Year:
2024,
Volume and Issue:
unknown
Published: Dec. 31, 2024
The
rapid
catalytic
conversion
toward
polysulfides
is
considered
to
be
an
advantageous
approach
boost
the
reaction
kinetics
and
inhibit
shuttle
effect
in
lithium-sulfur
(Li─S)
batteries.
However,
prediction
of
high
activity
Li─S
catalysts
has
become
challenging
given
carelessness
relationship
between
important
electronic
characteristics
activity.
Herein,
relationships
D-band
regulation
with
are
described.
Through
combination
experimental
theoretical
analysis,
opportune
upward
shift
center
results
a
favorable
interaction
polysulfides,
controlling
adsorption
behavior
polysulfides.
In
addition,
electron
achieved
by
moderately
moving
up
further
reduces
energy
barrier
through
hybridization
Based
on
this,
composite
catalyst
Mo
doped
VS
Small,
Journal Year:
2024,
Volume and Issue:
unknown
Published: Dec. 31, 2024
The
rapid
catalytic
conversion
toward
polysulfides
is
considered
to
be
an
advantageous
approach
boost
the
reaction
kinetics
and
inhibit
shuttle
effect
in
lithium-sulfur
(Li─S)
batteries.
However,
prediction
of
high
activity
Li─S
catalysts
has
become
challenging
given
carelessness
relationship
between
important
electronic
characteristics
activity.
Herein,
relationships
D-band
regulation
with
are
described.
Through
combination
experimental
theoretical
analysis,
opportune
upward
shift
center
results
a
favorable
interaction
polysulfides,
controlling
adsorption
behavior
polysulfides.
In
addition,
electron
achieved
by
moderately
moving
up
further
reduces
energy
barrier
through
hybridization
Based
on
this,
composite
catalyst
Mo
doped
VS
