Initializing Compression Stress to Stabilize the Phase Homogeneity in Bifacial Semitransparent Perovskite Solar Cells DOI

Hangjuan Wu,

Ziyu Wang, Junjie Ma

et al.

Advanced Energy Materials, Journal Year: 2024, Volume and Issue: unknown

Published: Aug. 26, 2024

Abstract Semitransparent perovskite solar cells (ST‐PSCs) hold great promise for various commercial applications, including building integrated photovoltaics and tandem cells. The all‐inorganic perovskite, known its outstanding optical transparency thermal stability, emerges as a top contender ST‐PSCs. However, challenges persist due to phase segregation, which hampers charge carrier transport operational stability. In this study, an approach is proposed address these by employing strain engineering reconstruct the texture, eliminating inhomogeneities within film. crucial role of compressive in stabilizing lattice rigidity suppressing light‐induced ion migration demonstrated. Furthermore, transparent light‐harvesting architecture devised utilizing sandwiched layer gold embedded between MoO 3 . This design enhances power generation efficiently harnessing incident light from both front rear panel surfaces. Therefore, bifacial ST‐PSCs achieve equivalent efficiency ( η eq ) 13.97% with average visible transmittance 41.58%, yielding utilization up 5.8%. research not only advances understanding material phase‐segregation behavior but also introduces effective strategy enhancing gain without compromising semitransparent characteristics.

Language: Английский

Tailoring pyridine bridged chalcogen-concave molecules for defects passivation enables efficient and stable perovskite solar cells DOI Creative Commons
Muhammad Azam, Yao Ma, Boxue Zhang

et al.

Nature Communications, Journal Year: 2025, Volume and Issue: 16(1)

Published: Jan. 11, 2025

Suppressing deep-level defects at the perovskite bulk and surface is indispensable for reducing non-radiative recombination losses improving efficiency stability of solar cells (PSCs). In this study, two Lewis bases based on chalcogen-thiophene (n-Bu4S) selenophene (n-Bu4Se) having tetra-pyridine as bridge are developed to passivate in film. The uncoordinated Pb2+ iodine vacancy can interact with chalcogen-concave group pyridine through formation acid-base adduct, particularly both be surrounded by concave molecules, resulting effective suppression charge recombination. This approach enables a power conversion (PCE) high 25.37% (25.18% certified) n-i-p PSCs stable operation 65 °C 1-sun illumination 1300 hours N2 (ISOS-L-2 protocol), retaining 94% initial efficiency. Our work provides insight into bowl-shaped base passivation coordinated strategy high-performance photovoltaic devices.

Language: Английский

Citations

3

Wide Bandgap Perovskites: A Comprehensive Review of Recent Developments and Innovations DOI
Kyoung‐Tae Kim, Taeho Moon, Jinhyun Kim

et al.

Small, Journal Year: 2025, Volume and Issue: unknown

Published: April 1, 2025

Abstract Recent advances in wide‐bandgap (WBG) perovskite solar cells (PSCs) demonstrate a burgeoning potential to significantly enhance photovoltaic efficiencies beyond the Shockley–Queisser limit for single‐junction cells. This review explores multifaceted improvements WBG PSCs, focusing on novel compositions, halide substitution strategies, and innovative device architectures. The of iodine with bromine organic ions such as FA MA Cs lattice is emphasized its effectiveness achieving higher open‐circuit voltages reduced thermalization losses. Furthermore, integration advanced charge transport layers interface engineering techniques discussed critical minimizing voltage ( V OC ) deficits improving photo‐stability these utilization PSCs diverse applications semitransparent devices, indoor photovoltaics, multijunction tandem devices also explored, addressing both their current limitations solutions. culminates comprehensive assessment challenges impeding industrial scale‐up PSC technology offers perspective future research directions aimed at realizing highly efficient stable commercial applications.

Language: Английский

Citations

1

Structure-Dependent Photophysical and Thermal Properties of Lead-Free Antimony Perovskites DOI
Bhavna Sharma, Naveen Kumar Tailor,

Rahul Chauhan

et al.

Energy & Fuels, Journal Year: 2025, Volume and Issue: unknown

Published: April 3, 2025

Language: Английский

Citations

1

Space-Charge-Limited Current Measurements: A Problematic Technique for Metal Halide Perovskites DOI
Vincent M. Le Corre

The Journal of Physical Chemistry Letters, Journal Year: 2024, Volume and Issue: unknown, P. 10001 - 10008

Published: Sept. 24, 2024

Space-charge-limited current (SCLC) measurements play a crucial role in the electrical characterization of semiconductors, particularly for metal halide perovskites. Accurate reporting and analysis SCLC are essential gaining meaningful insights into charge transport defect density these systems. Unfortunately, performing on perovskites is complicated by their mixed electronic-ionic conductivity. This complexity led to data often being incorrectly analyzed using simplified models unsuitable materials reported without information about how were performed. In light recently published data, common challenges perovskite addressed, solutions discussed this paper. The applicability often-used analytical models, overlooked issues related ionic-electronic conductivity perovskites, creating single-carrier devices investigated drift-diffusion simulations. Finally, guidelines more accurate improved provided.

Language: Английский

Citations

8

Device Performance of Emerging Photovoltaic Materials (Version 5) DOI Creative Commons
Osbel Almora, Guillermo C. Bazan, Carlos I. Cabrera

et al.

Advanced Energy Materials, Journal Year: 2024, Volume and Issue: unknown

Published: Nov. 26, 2024

Abstract This 5th annual “ Emerging PV Report” highlights the latest advancements in performance of emerging photovoltaic (e‐PV) devices across various e‐PV research areas, as documented peer‐reviewed articles published since August 2023. Updated graphs, tables, and analyses are provided, showcasing several key parameters, including power conversion efficiency, open‐circuit voltage, short‐circuit current, fill factor, light utilization stability test energy yield. These parameters presented functions bandgap average visible transmittance for each technology application contextualized using benchmarks such detailed balance efficiency limit.

Language: Английский

Citations

5

Enhanced Performance of Sn‐Based Perovskite Photodetectors Through Double‐Sided Passivation for Near‐Infrared Applications DOI Creative Commons

Yu Lai,

Chien Cheng Li, Yu Chuan Huang

et al.

Small, Journal Year: 2024, Volume and Issue: unknown

Published: Dec. 18, 2024

The development of high-performance Sn-based perovskite photodetectors is presented with double-sided passivation using large alkylammonium interlayers PEAI and BDAI₂. This dual strategy, applied to the top bottom FASnI₃ films, effectively improves film quality by reducing defect density, enhancing carrier mobility, minimizing non-radiative energy losses at interfaces. At 720 nm, demonstrate a responsivity 0.37 A W

Language: Английский

Citations

4

Opto-electro-thermal analysis of semi-transparent perovskite solar cells applied to BIPV DOI
Penghui Liu,

Longxiang Wang,

Jiapeng Wang

et al.

Energy and Buildings, Journal Year: 2025, Volume and Issue: unknown, P. 115585 - 115585

Published: March 1, 2025

Language: Английский

Citations

0

Versatile grain boundary trimming strategy for fabricating high-performance wide-bandgap perovskite solar cells DOI

Laijun Liang,

Weidong Zhu,

Wenming Chai

et al.

Materials Today Energy, Journal Year: 2025, Volume and Issue: 51, P. 101885 - 101885

Published: April 14, 2025

Language: Английский

Citations

0

Light Utilization Optimization of Semi-Transparent Perovskite Solar Modules via Constructing p-n Homojunction for Efficient Four-Terminal Tandem Devices DOI

Qian Feng,

Shihao Yuan, Lei Wang

et al.

Nano Energy, Journal Year: 2025, Volume and Issue: unknown, P. 111070 - 111070

Published: April 1, 2025

Language: Английский

Citations

0

Versatile Grain Boundary Trimming Strategy for Fabricating High-Performance Wide-Bandgap Perovskite Solar Cells DOI

Laijun Liang,

Weidong Zhu,

Wenming Chai

et al.

Published: Jan. 1, 2025

Language: Английский

Citations

0