Journal of Colloid and Interface Science, Journal Year: 2025, Volume and Issue: unknown, P. 138070 - 138070
Published: June 1, 2025
Language: Английский
Advanced Energy Materials, Journal Year: 2025, Volume and Issue: unknown
Published: Feb. 21, 2025
Abstract Developing sustainable energy storage systems is crucial for integrating renewable sources into the power grid. Aqueous zinc‐ion batteries (ZIBs) are becoming increasingly popular due to their safety, eco‐friendliness, and cost‐effectiveness. However, challenges remain in achieving realistic time per charge, long cycling life, high capacity practical conditions. Despite advancements cathode materials, issues such as dissolution side reactions limit performance. Optimizing architecture electrolyte composition essential address these challenges. Tailored formulations can stabilize electrode‐electrolyte interface (EEI enhance stability. This perspective reviews cathodes from past decades compares performance under different current densities. Emphasizing low density extended stability widespread adoption of ZIBs grid‐scale applications. By focusing on aspects, this aims bridge gap between research applications, offering insights optimizing material structure selecting matching electrolytes storage. work guides future developments ZIB technology, facilitating transition lab real‐world deployment.
Language: Английский
Citations
3
Coordination Chemistry Reviews, Journal Year: 2025, Volume and Issue: 531, P. 216478 - 216478
Published: Feb. 8, 2025
Language: Английский
Citations
2
Rare Metals, Journal Year: 2025, Volume and Issue: unknown
Published: Feb. 17, 2025
Language: Английский
Citations
1
Advanced Powder Materials, Journal Year: 2025, Volume and Issue: unknown, P. 100278 - 100278
Published: Feb. 1, 2025
Language: Английский
Citations
1
ACS Applied Materials & Interfaces, Journal Year: 2024, Volume and Issue: unknown
Published: Sept. 28, 2024
Rechargeable zinc-iodine (Zn-I
Language: Английский
Citations
6
International Journal of Biological Macromolecules, Journal Year: 2024, Volume and Issue: 284, P. 138125 - 138125
Published: Nov. 30, 2024
Language: Английский
Citations
4
Advanced Functional Materials, Journal Year: 2024, Volume and Issue: unknown
Published: Dec. 15, 2024
Abstract Active iodine dissolution and polyiodide shuttle are two major obstacles hindering the application of zinc‐iodine batteries (ZIBs). Designing functional carriers with strong physisorption/chemisorption capability, abundant active sites, high catalytic activity for redox reaction kinetics, is considered an effective strategy to solve current problems ZIBs. In this work, Fe, Co, Ni‐doping porous carbon (FeCoNi) comprehensively investigated as carrier material prepare iodine‐loading cathode FeCoNi@I 2 . On basis experimental tests theoretical calculations, introduction FeCoNi trimetallic atoms effectively regulates electronic structure, charge distribution, conductivity substrate, promoting conversion kinetics well chemisorption capability species, which conducive inhibit dissolution. As expected, Zn//FeCoNi@I exhibit specific capacity self‐discharge resistance reversible stabilizes at 108.8 mAh g −1 after 13000 cycles 1 A , 94.7 14000 3 This work will open new horizons structural design catalyst‐type materials durable ZIBs, facilitate atom‐doped in high‐performance secondary batteries.
Language: Английский
Citations
3
Advanced Energy Materials, Journal Year: 2025, Volume and Issue: unknown
Published: March 5, 2025
Abstract Aqueous zinc‐based batteries (AZBs) are emerging as a compelling candidate for large‐scale energy storage systems due to their cost‐effectiveness, environmental friendliness, and inherent safety. The design development of high‐performance AZBs have thus been the focus considerable study efforts; yet, certain properties electrode materials electrolytes still limit development. Here, comprehensive overview evaluation current progress, existing limitations, potential solutions achieve long‐cycle stability fast kinetics in is provided. Detailed analyses structural design, electrochemical behavior, zinc‐ion mechanisms various presented. Additionally, key issues research directions related zinc anodes selection systematically discussed guide future with superior performance. Finally, this review provides outlook on AZBs, highlighting challenges opportunities, foster continued rapid advancement broader practical applications field.
Language: Английский
Citations
0
Nano Energy, Journal Year: 2025, Volume and Issue: unknown, P. 110876 - 110876
Published: March 1, 2025
Language: Английский
Citations
0
ACS Applied Materials & Interfaces, Journal Year: 2025, Volume and Issue: unknown
Published: March 25, 2025
The large-scale practical application of Zn-iodine batteries (ZIBs) with environmental benignity and cost-effectiveness is hindered by the challenges poor reversibility Zn anode serious polyiodide shuttling. Herein, a dual-additive synergistic complementation electrolyte engineering method proposed to promote Zn2+ transport, enhance deposition reversibility, improve iodine conversion kinetics introducing lactulose caffeine into 1 M ZnSO4. It revealed that can reduce desolvation barrier substituting coordinated water ions increase transference number hydrogen bond-assisted SO42–/H2O-locking. As bilateral interfacial stabilizer, high polar preferentially adsorbed on owing its p-π conjugated structure "push–pull electron" effect, which renders (002)-textured plating. Furthermore, system firmly immobilize I3–, further stabilizing I2/I– redox behavior. Consequently, Zn//Zn cells deliver dendrite-free stripping/plating cycling for 3500 h at mA cm–2/1 mAh cm–2, survive over 1300 even depth discharge 71.0%. This "job-sharing" modulation mechanism offers strategy development long-lifespan ZIBs.
Language: Английский
Citations
0