High yield porous carbon framework with co-active B N sites to promote polyiodide conversion for high performance Zn-I2 batteries DOI

Menghan Sun,

Lishan Wei,

Jinsong Peng

et al.

Journal of Colloid and Interface Science, Journal Year: 2025, Volume and Issue: unknown, P. 138070 - 138070

Published: June 1, 2025

Language: Английский

Future Long Cycling Life Cathodes for Aqueous Zinc‐Ion Batteries in Grid‐Scale Energy Storage DOI Creative Commons
Divyani Gupta, Sailin Liu, Ruizhi Zhang

et al.

Advanced Energy Materials, Journal Year: 2025, Volume and Issue: unknown

Published: Feb. 21, 2025

Abstract Developing sustainable energy storage systems is crucial for integrating renewable sources into the power grid. Aqueous zinc‐ion batteries (ZIBs) are becoming increasingly popular due to their safety, eco‐friendliness, and cost‐effectiveness. However, challenges remain in achieving realistic time per charge, long cycling life, high capacity practical conditions. Despite advancements cathode materials, issues such as dissolution side reactions limit performance. Optimizing architecture electrolyte composition essential address these challenges. Tailored formulations can stabilize electrode‐electrolyte interface (EEI enhance stability. This perspective reviews cathodes from past decades compares performance under different current densities. Emphasizing low density extended stability widespread adoption of ZIBs grid‐scale applications. By focusing on aspects, this aims bridge gap between research applications, offering insights optimizing material structure selecting matching electrolytes storage. work guides future developments ZIB technology, facilitating transition lab real‐world deployment.

Language: Английский

Citations

3

Membranes constructing with excellent performances for aqueous zinc-ion battery: A review DOI

Juan Wu,

Mengyao Li, Haoyu Li

et al.

Coordination Chemistry Reviews, Journal Year: 2025, Volume and Issue: 531, P. 216478 - 216478

Published: Feb. 8, 2025

Language: Английский

Citations

2

Advancements in metal-iodine batteries: progress and perspectives DOI
Zhigang Shen,

Dianheng Yu,

Hongye Ding

et al.

Rare Metals, Journal Year: 2025, Volume and Issue: unknown

Published: Feb. 17, 2025

Language: Английский

Citations

1

Recent Progress in Aqueous Zinc-ion Batteries Based on Conversion-type Cathodes DOI Creative Commons
Yanan Cao,

Shidi Ju,

Qian Zhang

et al.

Advanced Powder Materials, Journal Year: 2025, Volume and Issue: unknown, P. 100278 - 100278

Published: Feb. 1, 2025

Language: Английский

Citations

1

Thermodynamically and Dynamically Boosted Electrocatalytic Iodine Conversion with Hydroxyl Groups for High-Efficiency Zinc–Iodine Batteries DOI
Le Zhou, Xiang Li, Hui Chen

et al.

ACS Applied Materials & Interfaces, Journal Year: 2024, Volume and Issue: unknown

Published: Sept. 28, 2024

Rechargeable zinc-iodine (Zn-I

Language: Английский

Citations

6

Catalytic transfer hydrogenolysis of lignin derived aromatic ethers over MOF derived porous carbon spheres anchored by Ni species DOI

Fei Ge,

Haihong Xia,

Yanrong Wang

et al.

International Journal of Biological Macromolecules, Journal Year: 2024, Volume and Issue: 284, P. 138125 - 138125

Published: Nov. 30, 2024

Language: Английский

Citations

4

Trimetallic Atom‐Doped Functional Carbon Catalyst Enables Fast Redox Kinetics and Durable Cyclic Stability of Zinc‐Iodine Batteries DOI Open Access
Yating Gao, Yurong Liu,

Xun Guo

et al.

Advanced Functional Materials, Journal Year: 2024, Volume and Issue: unknown

Published: Dec. 15, 2024

Abstract Active iodine dissolution and polyiodide shuttle are two major obstacles hindering the application of zinc‐iodine batteries (ZIBs). Designing functional carriers with strong physisorption/chemisorption capability, abundant active sites, high catalytic activity for redox reaction kinetics, is considered an effective strategy to solve current problems ZIBs. In this work, Fe, Co, Ni‐doping porous carbon (FeCoNi) comprehensively investigated as carrier material prepare iodine‐loading cathode FeCoNi@I 2 . On basis experimental tests theoretical calculations, introduction FeCoNi trimetallic atoms effectively regulates electronic structure, charge distribution, conductivity substrate, promoting conversion kinetics well chemisorption capability species, which conducive inhibit dissolution. As expected, Zn//FeCoNi@I exhibit specific capacity self‐discharge resistance reversible stabilizes at 108.8 mAh g −1 after 13000 cycles 1 A , 94.7 14000 3 This work will open new horizons structural design catalyst‐type materials durable ZIBs, facilitate atom‐doped in high‐performance secondary batteries.

Language: Английский

Citations

3

Aqueous Zinc‐Based Batteries: Active Materials, Device Design, and Future Perspectives DOI Creative Commons
Ran Yan,

Fang Dong,

Shuhui Sun

et al.

Advanced Energy Materials, Journal Year: 2025, Volume and Issue: unknown

Published: March 5, 2025

Abstract Aqueous zinc‐based batteries (AZBs) are emerging as a compelling candidate for large‐scale energy storage systems due to their cost‐effectiveness, environmental friendliness, and inherent safety. The design development of high‐performance AZBs have thus been the focus considerable study efforts; yet, certain properties electrode materials electrolytes still limit development. Here, comprehensive overview evaluation current progress, existing limitations, potential solutions achieve long‐cycle stability fast kinetics in is provided. Detailed analyses structural design, electrochemical behavior, zinc‐ion mechanisms various presented. Additionally, key issues research directions related zinc anodes selection systematically discussed guide future with superior performance. Finally, this review provides outlook on AZBs, highlighting challenges opportunities, foster continued rapid advancement broader practical applications field.

Language: Английский

Citations

0

Plant derived multifunctional binders for shuttle-free zinc-iodine batteries DOI
Jiahao Zhu,

Shan Guo,

Yang Zhang

et al.

Nano Energy, Journal Year: 2025, Volume and Issue: unknown, P. 110876 - 110876

Published: March 1, 2025

Language: Английский

Citations

0

Dual-Additive Synergistic Complementation Electrolyte Engineering with “Job-Sharing” Modulation Mechanism for Long-Lifespan Zn-Iodine Batteries DOI

Haidan Lu,

Bo‐Wen Yin,

Tianyu Zhang

et al.

ACS Applied Materials & Interfaces, Journal Year: 2025, Volume and Issue: unknown

Published: March 25, 2025

The large-scale practical application of Zn-iodine batteries (ZIBs) with environmental benignity and cost-effectiveness is hindered by the challenges poor reversibility Zn anode serious polyiodide shuttling. Herein, a dual-additive synergistic complementation electrolyte engineering method proposed to promote Zn2+ transport, enhance deposition reversibility, improve iodine conversion kinetics introducing lactulose caffeine into 1 M ZnSO4. It revealed that can reduce desolvation barrier substituting coordinated water ions increase transference number hydrogen bond-assisted SO42–/H2O-locking. As bilateral interfacial stabilizer, high polar preferentially adsorbed on owing its p-π conjugated structure "push–pull electron" effect, which renders (002)-textured plating. Furthermore, system firmly immobilize I3–, further stabilizing I2/I– redox behavior. Consequently, Zn//Zn cells deliver dendrite-free stripping/plating cycling for 3500 h at mA cm–2/1 mAh cm–2, survive over 1300 even depth discharge 71.0%. This "job-sharing" modulation mechanism offers strategy development long-lifespan ZIBs.

Language: Английский

Citations

0