Recent Progress of Modulating Pristine Metal–Organic Frameworks for Oxygen Reaction Revolution DOI
Guifu Zuo,

Hong Wang,

Yanzhong Wang

et al.

Langmuir, Journal Year: 2025, Volume and Issue: unknown

Published: April 22, 2025

Highly efficient and stable oxygen evolution reaction (OER) electrocatalysts are essential for electrochemical water splitting. Among non-noble metal-based catalysts, metal-organic frameworks (MOFs) have recently emerged as particularly promising candidates due to their exceptional surface areas, hierarchical porous structures, tunable morphologies compositions. The rational regulation of the morphology electronic structure pristine MOFs is considered a critical pathway enhancing active sites structural stability, thereby significantly boosting OER catalytic performance. This review systematically presents recent advancements in modulating via heterogeneous metal doping, ligand substitution, hybrid composite construction. With particular emphasis on synthetic methods, modification mechanisms, properties MOFs, we analyze fundamental relationships between modifications electrocatalytic Through systematic analysis existing research achievements, this provides holistic assessment current state-of-the-art developments, identifies challenges, proposes future directions with practical implications electrocatalyst design.

Language: Английский

Universal Synthesis of Single-Atom Electrocatalysts viaIn-Situ Fluoride Ion Etching for Hydrogen Evolution DOI Creative Commons
Peng Liu, Jiahui Ye,

Kuan Deng

et al.

Chemical Science, Journal Year: 2025, Volume and Issue: 16(10), P. 4402 - 4411

Published: Jan. 1, 2025

Single-atom catalysts (SACs) have attracted considerable interest in the field of electrocatalysis due to their high efficiency metal utilization and catalytic activity. However, traditional methods SACs fabrication are often complex time-consuming. Herein, F-Ru@TiO x N y was synthesized using a straightforward universal approach via situ surface etching heteroatoms immobilization on vacancies-rich hierarchical TiO nanorods array. The fluorine ion-etched could produce abundant oxygen vacancies F-Ti/F-C bonds, which capture stabilize Ru by strong host-guest electronic interactions. Due synergistic effect anchoring F-C bonds-assisted stabilization single atoms, revealed excellent electrocatalytic hydrogen evolution performance, low overpotential 20.8 mV at 10 mA cm-2, Tafel slope 59.9 dec-1 robust stability 100 cm-2 over 48 h. Furthermore, this strategy be applicable various heterometals (Pd, Ir, Pt), also exhibited dispersity HER activity/stability. This method is simple, easy-scalable versatile, showcasing significant potential for electrocatalysts design promising application prospects energy conversion.

Language: Английский

Citations

0
A Dual-Function Fe-Doped Co3O4 Nanosheet Array for Efficient OER and HER in an Alkaline Medium DOI Creative Commons
Yibo Su, Bo Liu,

Zijun Shi

et al.

Molecules, Journal Year: 2025, Volume and Issue: 30(5), P. 1046 - 1046

Published: Feb. 25, 2025

The electrocatalysts of heteroatom-doped non-precious metal oxide materials are great significance for efficient and low-cost electrochemical water-splitting systems. Herein, an innovative Fe-doped Co3O4 nanoflake (Fe-Co3O4/NF) on nickel foam has been developed, which exhibits excellent electrocatalytic activity both hydrogen evolution reactions (HERs) oxygen (OERs). Benefiting from the synergy charge redistribution d-band center shift caused by doping engineering, as-obtained Fe-Co3O4/NF shows HER (η10 = 196 mV) OER 290 activities with low Tafel slopes (109 mV dec-1 49 OER, respectively) stability. This work provides effective method designing synthesizing bifunctional high stability hybrids HER/OER.

Language: Английский

Citations

0
Advances in Atomically Dispersed Catalysts for Water Splitting DOI Open Access
Yuqiong Li, Yubin Liu,

Mengyao Guo

et al.

Advanced Functional Materials, Journal Year: 2025, Volume and Issue: unknown

Published: March 10, 2025

Abstract Currently, atomically dispersed catalysts (ADCs), including single‐atom (SACs), dual‐atom (DACs), and triple‐atom (TACs), have become the hot topic in heterogeneous catalysis field since they exceptional atomic efficiency catalytic performance various reactions. In this review, recent advances ADCs for overall water splitting are summarized, SACs, DACs, TACs. First, mechanisms of HER OER reactions electrocatalysis, photocatalysis, thermocatalysis presented. Second, (including OER) on with different supports systematically reviewed. Third, new novel proposed to design splitting, tandem catalysts, frustrated Lewis pairs (FLP), SAC+FLP, so on. Finally, prospective a summary as well challenges opportunities outlined, which provide insights into future development high‐performance clean sustainable energy production.

Language: Английский

Citations

0
Recent Progress of Modulating Pristine Metal–Organic Frameworks for Oxygen Reaction Revolution DOI
Guifu Zuo,

Hong Wang,

Yanzhong Wang

et al.

Langmuir, Journal Year: 2025, Volume and Issue: unknown

Published: April 22, 2025

Highly efficient and stable oxygen evolution reaction (OER) electrocatalysts are essential for electrochemical water splitting. Among non-noble metal-based catalysts, metal-organic frameworks (MOFs) have recently emerged as particularly promising candidates due to their exceptional surface areas, hierarchical porous structures, tunable morphologies compositions. The rational regulation of the morphology electronic structure pristine MOFs is considered a critical pathway enhancing active sites structural stability, thereby significantly boosting OER catalytic performance. This review systematically presents recent advancements in modulating via heterogeneous metal doping, ligand substitution, hybrid composite construction. With particular emphasis on synthetic methods, modification mechanisms, properties MOFs, we analyze fundamental relationships between modifications electrocatalytic Through systematic analysis existing research achievements, this provides holistic assessment current state-of-the-art developments, identifies challenges, proposes future directions with practical implications electrocatalyst design.

Language: Английский

Citations

0