Design Principles of Metal Phthalocyanine for Electrochemical CO2 Reduction: From Targeted Molecular Structures to Atomic‐Level Active Sites DOI

Caiyue Wang,

Yingzheng Zhang,

Zhao Fang

et al.

Small, Journal Year: 2025, Volume and Issue: unknown

Published: May 26, 2025

Abstract The electrocatalytic reduction of carbon dioxide (CO 2 RR) to valuable chemical feedstocks using renewable electricity is a promising approach circumventing climate change due the overuse fossil energy. However, most critical mission design high active and economical electrocatalysts. Metal phthalocyanine (MPc)‐based electrocatalysts have attracted extensive research their well‐defined sites flexible structural tunability. Specifically, features MPcs are first introduced then summarize different catalytic mechanisms for CO RR products. Importantly, two main modification strategies axial horizontal modulation MPc‐based highlighted systematically summarized. Furthermore, selectivity products Finally, challenges expectations electrocatalyst selection proposed. This article aims present comprehensive overview electrocatalysts, expecting further inspire development provide new ideas rational efficient

Language: Английский

Design Principles of Metal Phthalocyanine for Electrochemical CO2 Reduction: From Targeted Molecular Structures to Atomic‐Level Active Sites DOI

Caiyue Wang,

Yingzheng Zhang,

Zhao Fang

et al.

Small, Journal Year: 2025, Volume and Issue: unknown

Published: May 26, 2025

Abstract The electrocatalytic reduction of carbon dioxide (CO 2 RR) to valuable chemical feedstocks using renewable electricity is a promising approach circumventing climate change due the overuse fossil energy. However, most critical mission design high active and economical electrocatalysts. Metal phthalocyanine (MPc)‐based electrocatalysts have attracted extensive research their well‐defined sites flexible structural tunability. Specifically, features MPcs are first introduced then summarize different catalytic mechanisms for CO RR products. Importantly, two main modification strategies axial horizontal modulation MPc‐based highlighted systematically summarized. Furthermore, selectivity products Finally, challenges expectations electrocatalyst selection proposed. This article aims present comprehensive overview electrocatalysts, expecting further inspire development provide new ideas rational efficient

Language: Английский

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