Separation and Purification Technology, Journal Year: 2024, Volume and Issue: unknown, P. 130150 - 130150
Published: Oct. 1, 2024
Language: Английский
Separation and Purification Technology, Journal Year: 2024, Volume and Issue: unknown, P. 130150 - 130150
Published: Oct. 1, 2024
Language: Английский
Chemical Engineering Journal, Journal Year: 2024, Volume and Issue: unknown, P. 156176 - 156176
Published: Sept. 1, 2024
Language: Английский
Citations
4Chemical Engineering Journal, Journal Year: 2025, Volume and Issue: 505, P. 159193 - 159193
Published: Jan. 5, 2025
Language: Английский
Citations
0Chemical Engineering Journal, Journal Year: 2025, Volume and Issue: unknown, P. 159467 - 159467
Published: Jan. 1, 2025
Language: Английский
Citations
0Fluid Phase Equilibria, Journal Year: 2025, Volume and Issue: unknown, P. 114386 - 114386
Published: Feb. 1, 2025
Language: Английский
Citations
0Journal of Molecular Liquids, Journal Year: 2025, Volume and Issue: unknown, P. 127649 - 127649
Published: April 1, 2025
Language: Английский
Citations
0Chemical Engineering Journal, Journal Year: 2025, Volume and Issue: unknown, P. 162746 - 162746
Published: April 1, 2025
Language: Английский
Citations
0Separation and Purification Technology, Journal Year: 2024, Volume and Issue: 354, P. 128443 - 128443
Published: June 15, 2024
Tetralkylphosphonium carboxylate ionic liquids are herein presented as efficient carbon dioxide chemisorbents in the presence of water. The tetrabutylphosphonium formate and acetate, tributylmethylphosphonium a series triethylalkylphosphonium formates acetates, have been prepared by various synthetic procedures either from hydroxide or methylcarbonate precursors, via multiple steps starting parent triethylphosphine. Their physicochemical properties, namely melting glass transition temperatures, thermal decomposition behaviour, densities viscosities determined. As dry substances, they viscous low-melting solids, whereas show little tendency to solidify their hydrated forms. They were used mostly monohydrates CO2 solubility measurements, exhibiting highest capacities (3 mol L−1, i.e. ≈ 0.9 molCO2 molIL−1, at 5 bar, 25 °C) equimolar H2O/ionic liquid ratios, approaching those commercial aqueous amine sorbents. Carbon chemisorption into hydrogencarbonate takes place, demonstrated infrared spectroscopy with isotopic labelling. absorption isotherms recorded temperatures data estimate heat according three different thermodynamic models adopted. Enthalpies depended heavily on model used. Rationalisation this was done grounds expected relevance physical chemical sorption processes. Average heats lie between − 40 45 kJ mol−1, accordance mild albeit significantly lower than for typical sorbents such amines. This reinforces feasibility capture technologies low regeneration energies.
Language: Английский
Citations
3Journal of Cleaner Production, Journal Year: 2024, Volume and Issue: 467, P. 143006 - 143006
Published: June 25, 2024
Language: Английский
Citations
3ChemSusChem, Journal Year: 2024, Volume and Issue: unknown
Published: July 2, 2024
Due to the active unstable nature of carbon anions, it is challenging develop carbanion-functionalized ionic liquids (ILs) for efficient and reversible dioxide (CO
Language: Английский
Citations
3Journal of Hazardous Materials, Journal Year: 2025, Volume and Issue: unknown, P. 137741 - 137741
Published: Feb. 1, 2025
Language: Английский
Citations
0