Photochemical cyclopropanation in aqueous micellar media – experimental and theoretical studies DOI Creative Commons
Joseph P. Milton, Adam Milanowski, Martin Andersson

et al.

Chemical Communications, Journal Year: 2024, Volume and Issue: 60(33), P. 4483 - 4486

Published: Jan. 1, 2024

While in nature, reactions occur water-based confined compartments, for a long time, water has been often regarded as an unsuitable medium organic reactions. We have, however, found that photochemical cyclopropanation of styrenes with diazo compounds or their precursors can be performed micellar systems. COSMO-RS studies revealed the reactivity correlates predicted critical micelle concentration (CMC), higher CMC values delivering yields.

Language: Английский

Photochemical cyclopropanation in aqueous micellar media – experimental and theoretical studies DOI Creative Commons
Joseph P. Milton, Adam Milanowski, Martin Andersson

et al.

Chemical Communications, Journal Year: 2024, Volume and Issue: 60(33), P. 4483 - 4486

Published: Jan. 1, 2024

While in nature, reactions occur water-based confined compartments, for a long time, water has been often regarded as an unsuitable medium organic reactions. We have, however, found that photochemical cyclopropanation of styrenes with diazo compounds or their precursors can be performed micellar systems. COSMO-RS studies revealed the reactivity correlates predicted critical micelle concentration (CMC), higher CMC values delivering yields.

Language: Английский

Citations

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