Photoredox-Catalyzed C–H Methylation of N-Heteroarenes Enabled by N,N-Dimethylethanolamine DOI
Jiayang Wang, Yun Wang, Wei-Yang Lin

et al.

The Journal of Organic Chemistry, Journal Year: 2024, Volume and Issue: unknown

Published: Nov. 21, 2024

A visible-light-driven radical C-H methylation of

Language: Английский

Multicomponent Construction of Tertiary Alkylamines by Photoredox/Nickel-Catalyzed Aminoalkylation of Organohalides DOI
Tao Yang,

Wenhui Xiong,

Guangyu Sun

et al.

Journal of the American Chemical Society, Journal Year: 2024, Volume and Issue: 146(42), P. 29177 - 29188

Published: Oct. 12, 2024

Tertiary alkylamines are privileged structural motifs widely present in natural products, pharmaceutical agents, and bioactive molecules, their efficient synthesis has been a longstanding goal organic chemistry. The functionalization of α-amino radicals derived from abundant precursors represents an emerging approach to accessing alkylamines, but application this strategy obtain tertiary remains challenging. Here, we show that dual photoredox/nickel catalysis enables aminoalkylation organohalides (sp

Language: Английский

Citations

6
Recent Progress in C–S Bond Formation via Electron Donor-Acceptor Photoactivation DOI
Sichang Wang, Liting Wang, Jin Cui

et al.

Organic & Biomolecular Chemistry, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 1, 2025

This review summarizes recent progress in EDA complex-promoted C–S bond formation using various sulfur-containing substrates under mild conditions via visible light irradiation.

Language: Английский

Citations

0
Visible Light-Mediated Selective Synthesis of β-Amino Sulfide Scaffolds via Dual Role of N-Iodosuccinimide DOI

Jaehee Sim,

K P Sujith,

Anna Lee

et al.

Organic Letters, Journal Year: 2025, Volume and Issue: unknown

Published: March 6, 2025

The synthesis of β-amino sulfides is significant in organic chemistry. However, challenges such as achieving regioselectivity and the limited availability starting materials remain unresolved. In this study, we present a visible light-mediated method for selective sulfide scaffolds. Remarkably, two distinct types were selectively synthesized through dual role N-iodosuccinimide, which functions either reactant or an activator construction target

Language: Английский

Citations

0
Photoredox-Catalyzed C–H Methylation of N-Heteroarenes Enabled by N,N-Dimethylethanolamine DOI
Jiayang Wang, Yun Wang, Wei-Yang Lin

et al.

The Journal of Organic Chemistry, Journal Year: 2024, Volume and Issue: unknown

Published: Nov. 21, 2024

A visible-light-driven radical C-H methylation of

Language: Английский

Citations

0