Borane-Mediated Polyhedral Expansion to Access Metal-Free Neutral and Cationic Derivatives of closo-Heptaboranes DOI
Penglong Wang, Rei Kinjo

Journal of the American Chemical Society, Journal Year: 2024, Volume and Issue: unknown

Published: Oct. 2, 2024

Boranes with closed polyhedral structures feature peculiar bonding and structural characteristics, rendering them widely applicable in diverse research areas ranging from basic functionalization reactions to applications such as medicine, nanomaterials, molecular electronics, neutron capture therapy. Among the borane family, neutral cationic heptaborane B

Language: Английский

Activation of small molecules by ambiphilic NHC-stabilized phosphinoborenium cation: formation of boreniums with B-O-C, B-O-B, and B-O-P structural motifs DOI
Tomasz Wojnowski, Anna Ordyszewska,

Hanna Halenka

et al.

Dalton Transactions, Journal Year: 2024, Volume and Issue: unknown

Published: Jan. 1, 2024

NHC-stabilized phosphinoborenium cation acts as a synthon of boreniums with B–O–C(O)–P, B–O–B, B–O–P, and B–O–C structural motifs.

Language: Английский

Citations

2
Borane-Mediated Polyhedral Expansion to Access Metal-Free Neutral and Cationic Derivatives of closo-Heptaboranes DOI
Penglong Wang, Rei Kinjo

Journal of the American Chemical Society, Journal Year: 2024, Volume and Issue: unknown

Published: Oct. 2, 2024

Boranes with closed polyhedral structures feature peculiar bonding and structural characteristics, rendering them widely applicable in diverse research areas ranging from basic functionalization reactions to applications such as medicine, nanomaterials, molecular electronics, neutron capture therapy. Among the borane family, neutral cationic heptaborane B

Language: Английский

Citations

0