Synthesis and Characterization of Photocurable Difunctional Monomers for Medical Applications DOI Open Access
Gökhan Demirci, Agata Goszczyńska, Martyna Sokołowska

et al.

Polymers, Journal Year: 2024, Volume and Issue: 16(24), P. 3584 - 3584

Published: Dec. 21, 2024

Photocurable materials offer a rapid transition from liquid to solid state, and have recently received great interest in the medical field. However, while dental resins are very popular, only few been developed for soft tissue repair. This study aims synthesize difunctional methacrylate monomer using dibutyltin dilaurate which is suitable photocuring of materials. These were compared with PhotoBioCure® (Szczecin, Poland) material similar molecular weight, Mn ~7000 g/mol on average. Infrared spectroscopy was used monitor two-step synthesis catalyzed dilaurate, spectroscopic chromatographic methods determine chemical structure weight monomers. Photopolymerization kinetics under varying light intensities explored nitrogen atmosphere representative The mechanical testing resulting elastomeric films confirmed tensile strength modulus values consistent parameters range 3–4 MPa. 3D printability macromonomers also assessed. Additionally, cytotoxicity assessments cultured cells showed high cell viability (97%) all new Overall, we demonstrate that monomers converted flexible solids during photopolymerization show potential biomedical applications.

Language: Английский

Application of new photoinitiating systems based on BODIPY derivatives in long-wavelength photo-induced free radical polymerization DOI Creative Commons
Hui Deng, Jiansong Yin,

Yingzhu Sun

et al.

European Polymer Journal, Journal Year: 2025, Volume and Issue: unknown, P. 113833 - 113833

Published: Feb. 1, 2025

Language: Английский

Citations

1
Photopolymerization initiated by aggregation-induced emission (AIE) dyes: Towards design of fluorescent photocatalysts with hybridized excited state DOI
Ke Sun, Wenlong Tang, Mingyang Wu

et al.

European Polymer Journal, Journal Year: 2025, Volume and Issue: unknown, P. 113750 - 113750

Published: Jan. 1, 2025

Language: Английский

Citations

0
Recent advances on naphthoquinone-imidazolyl and naphthoquinone-thiazolyl derivatives as photoinitiators of photopolymerization DOI
Frédéric Dumur

European Polymer Journal, Journal Year: 2024, Volume and Issue: 219, P. 113401 - 113401

Published: Aug. 27, 2024

Language: Английский

Citations

3
Synthesis and Characterization of Photocurable Difunctional Monomers for Medical Applications DOI Open Access
Gökhan Demirci, Agata Goszczyńska, Martyna Sokołowska

et al.

Polymers, Journal Year: 2024, Volume and Issue: 16(24), P. 3584 - 3584

Published: Dec. 21, 2024

Photocurable materials offer a rapid transition from liquid to solid state, and have recently received great interest in the medical field. However, while dental resins are very popular, only few been developed for soft tissue repair. This study aims synthesize difunctional methacrylate monomer using dibutyltin dilaurate which is suitable photocuring of materials. These were compared with PhotoBioCure® (Szczecin, Poland) material similar molecular weight, Mn ~7000 g/mol on average. Infrared spectroscopy was used monitor two-step synthesis catalyzed dilaurate, spectroscopic chromatographic methods determine chemical structure weight monomers. Photopolymerization kinetics under varying light intensities explored nitrogen atmosphere representative The mechanical testing resulting elastomeric films confirmed tensile strength modulus values consistent parameters range 3–4 MPa. 3D printability macromonomers also assessed. Additionally, cytotoxicity assessments cultured cells showed high cell viability (97%) all new Overall, we demonstrate that monomers converted flexible solids during photopolymerization show potential biomedical applications.

Language: Английский

Citations

0