Organometallics,
Journal Year:
2012,
Volume and Issue:
31(22), P. 7753 - 7808
Published: Nov. 14, 2012
The
C–N
cross-coupling
chemistry
intensely
developed
since
the
late
1990s
has
supplied
synthesists
with
an
overwhelming
number
of
methods
to
effectively
combine
carbon
and
nitrogen
residues.
This
new
relies
on
complexes
mainly
two
metals,
copper
palladium,
used
as
catalysts
or
stoichiometric
agents.
development
revealed
both
similarities
differences
in
principles
for
design
catalytic
systems
analysis
their
reactivity
selectivity.
discussion
these
metals
can
be
performed
within
a
common
mechanistic
paradigm,
helping
elucidate
key
factors
governing
behavior
transition-metal
involved.
Chemical Reviews,
Journal Year:
2018,
Volume and Issue:
119(4), P. 2192 - 2452
Published: Nov. 27, 2018
C–H
activation
has
surfaced
as
an
increasingly
powerful
tool
for
molecular
sciences,
with
notable
applications
to
material
crop
protection,
drug
discovery,
and
pharmaceutical
industries,
among
others.
Despite
major
advances,
the
vast
majority
of
these
functionalizations
required
precious
4d
or
5d
transition
metal
catalysts.
Given
cost-effective
sustainable
nature
earth-abundant
first
row
metals,
development
less
toxic,
inexpensive
3d
catalysts
gained
considerable
recent
momentum
a
significantly
more
environmentally-benign
economically-attractive
alternative.
Herein,
we
provide
comprehensive
overview
on
until
summer
2018.
Angewandte Chemie International Edition,
Journal Year:
2013,
Volume and Issue:
52(45), P. 11726 - 11743
Published: Sept. 17, 2013
C-H
bonds
are
ubiquitous
in
organic
compounds.
It
would,
therefore,
appear
that
direct
functionalization
of
substrates
by
activation
would
eliminate
the
multiple
steps
and
limitations
associated
with
preparation
functionalized
starting
materials.
Regioselectivity
is
an
important
issue
because
molecules
can
contain
a
wide
variety
bonds.
The
use
directing
group
largely
overcome
regiocontrol
allowing
catalyst
to
come
into
proximity
targeted
A
functional
groups
have
been
evaluated
for
as
transformation
In
2005,
Daugulis
reported
arylation
unactivated
C(sp(3))-H
using
8-aminoquinoline
picolinamide
bidentate
groups,
Pd(OAc)2
catalyst.
Encouraged
these
promising
results,
number
transformations
since
developed
systems
based
on
groups.
this
Review,
recent
advances
area
discussed.
Chemical Reviews,
Journal Year:
2017,
Volume and Issue:
117(13), P. 9247 - 9301
Published: Jan. 4, 2017
Catalytic
transformation
of
ubiquitous
C-H
bonds
into
valuable
C-N
offers
an
efficient
synthetic
approach
to
construct
N-functionalized
molecules.
Over
the
last
few
decades,
transition
metal
catalysis
has
been
repeatedly
proven
be
a
powerful
tool
for
direct
conversion
cheap
hydrocarbons
synthetically
versatile
amino-containing
compounds.
This
Review
comprehensively
highlights
recent
advances
in
intra-
and
intermolecular
amination
reactions
utilizing
late
metal-based
catalysts.
Initial
discovery,
mechanistic
study,
additional
applications
were
categorized
on
basis
scaffolds
types
reactions.
Reactivity
selectivity
novel
systems
are
discussed
three
sections,
with
each
being
defined
by
proposed
working
mode.
Chemical Society Reviews,
Journal Year:
2016,
Volume and Issue:
45(10), P. 2900 - 2936
Published: Jan. 1, 2016
C–H
Activation
reactions
that
proceed
under
mild
conditions
are
more
attractive
for
applications
in
complex
molecule
synthesis.
Mild
transformations
reported
since
2011
reviewed
and
the
different
concepts
strategies
have
enabled
their
mildness
discussed.
Chemical Society Reviews,
Journal Year:
2014,
Volume and Issue:
43(10), P. 3525 - 3550
Published: Jan. 1, 2014
Copper-catalysed
arylations
represent
valid
and
complementary
alternatives
to
Pd
catalysis.
This
review
discusses
the
different
mechanisms
suggested
for
these
reactions,
summarises
some
of
their
latest
applications
in
synthesis.
Chemical Society Reviews,
Journal Year:
2012,
Volume and Issue:
41(9), P. 3464 - 3464
Published: Jan. 1, 2012
Copper
salts
have
been
developed
as
versatile
catalysts
for
oxidative
coupling
reactions
in
organic
synthesis.
During
these
processes,
Cu-catalysts
are
often
proposed
to
serve
a
one-electron
oxidant
promote
the
single-electron
transfer
process.
Recently,
transition-metal
catalyzed
direct
dehydrogenative
transformation
has
attracted
considerable
attention.
This
tutorial
review
summarizes
recent
advances
copper-catalyzed
functionalization
via
single
electron
(SET)
process
achieving
C–C,
C–N,
C–O,
C–halogen
atoms,
C–P,
and
N–N
bond
formation.
Chemical Society Reviews,
Journal Year:
2018,
Volume and Issue:
47(15), P. 5786 - 5865
Published: Jan. 1, 2018
This
review
provides
an
overview
of
the
use
electrochemistry
as
appealing
platform
for
expediting
carbon–hydrogen
functionalization
and
carbon–nitrogen
bond
formation.
