Advanced Synthesis & Catalysis,
Journal Year:
2023,
Volume and Issue:
365(14), P. 2299 - 2309
Published: June 12, 2023
Abstract
The
employing
visible
light
to
drive
organic
transformations
is
the
most
promising
choice
meet
needs
for
green
synthesis,
in
which
reactions
promoted
by
may
provide
a
more
efficient
and
greener
method.
Currently,
abundant
methods
activation
functionalization
of
reaction
substrates
have
relied
on
direct
single‐electron
transfer
(SET)
between
excited
photocatalyst
substrates,
these
wonderful
works
were
summarized
docoumented
many
reviews.
As
complement
above
reactions,
photoredox‐mediated
atom
(photocatalyst‐to‐HAT
catalyst‐to‐substrates)
generate
radical
species
are
showing
an
explosively
growing
trend.
In
this
review,
we
highlight
recent
significant
developments
rapidly
area,
mainly
focusing
photoinduced
base‐to‐substrates
charge
reactions.
Chemistry - A European Journal,
Journal Year:
2020,
Volume and Issue:
26(24), P. 5360 - 5364
Published: March 6, 2020
Abstract
The
use
of
gem
‐diborylalkenes
as
radical‐reactive
groups
is
explored
for
the
first
time.
These
reactions
provide
an
efficient
and
general
method
photochemical
conversion
to
rapidly
access
1,1‐bisborylalkanes.
This
exploits
a
novel
photoredox
decarboxylative
radical
addition
afford
α‐
‐diboryl
carbon‐centered
radicals,
which
benefit
from
additional
stability
by
virtue
interaction
with
empty
p‐orbitals
on
borons.
reaction
offers
highly
modular
regioselective
approach
γ‐amino
‐diborylalkanes.
Furthermore,
EPR
spectroscopy
DFT
calculations
have
provided
insight
into
mechanism
underlying
photochemistry
bis‐metalated
respectively.
European Journal of Organic Chemistry,
Journal Year:
2022,
Volume and Issue:
2022(9)
Published: Jan. 12, 2022
Abstract
Organoboronates
are
synthetically
useful
and
highly
valuable
building
blocks
in
synthetic
medicinal
chemistry.
Two‐electron
reactions
allow
for
the
rapid
construction
of
organoboronates
via
nucleophilic
1,2‐boron
shift
boron
ate
complexes
or
MIDA‐mediated
1,2‐boryl
migration.
Radical
approaches
through
neutral
boronic
esters
have
been
demonstrated
to
be
feasible,
providing
complementary
methods
access
these
privileged
scaffolds.
In
this
Review,
recent
achievements
highlighted
future
opportunities
discussed,
with
an
emphasis
on
different
operative
modes
catalysis
reaction
pathways.
Angewandte Chemie International Edition,
Journal Year:
2022,
Volume and Issue:
61(35)
Published: May 31, 2022
The
synthesis
of
molecules
bearing
two
or
more
contiguous,
quaternary
stereocenters
is
challenging,
owing
to
the
difficulty
in
controlling
stereochemistry
whilst
simultaneously
constructing
a
sterically
congested
motif.
Herein,
we
report
electrophile-induced
ring
contractive
1,2-metallate
rearrangement
6-membered
cyclic
alkenyl
boronate
complexes
for
cyclopentyl
boronic
esters
fully
substituted
with
high
levels
stereocontrol.
Remarkably,
simple
variation
reaction
solvent
enabled
their
diastereodivergent
construction
facile
access
complementary
diastereomeric
pairs.
utility
our
methodology
demonstrated
asymmetric
total
(+)-herbertene-1,14-diol.
Advanced Synthesis & Catalysis,
Journal Year:
2023,
Volume and Issue:
365(14), P. 2299 - 2309
Published: June 12, 2023
Abstract
The
employing
visible
light
to
drive
organic
transformations
is
the
most
promising
choice
meet
needs
for
green
synthesis,
in
which
reactions
promoted
by
may
provide
a
more
efficient
and
greener
method.
Currently,
abundant
methods
activation
functionalization
of
reaction
substrates
have
relied
on
direct
single‐electron
transfer
(SET)
between
excited
photocatalyst
substrates,
these
wonderful
works
were
summarized
docoumented
many
reviews.
As
complement
above
reactions,
photoredox‐mediated
atom
(photocatalyst‐to‐HAT
catalyst‐to‐substrates)
generate
radical
species
are
showing
an
explosively
growing
trend.
In
this
review,
we
highlight
recent
significant
developments
rapidly
area,
mainly
focusing
photoinduced
base‐to‐substrates
charge
reactions.
