[Cp*RhCl2]2catalyzed three-component coupling cyclization of 2,3-allenoic acids with 2,3-allenols in the presence of Cu(OAc)2·H2O DOI
Junjie Fan, Xiaoyan Wu,

Chunling Fu

et al.

Organic Chemistry Frontiers, Journal Year: 2023, Volume and Issue: 10(15), P. 3776 - 3780

Published: Jan. 1, 2023

A [Cp*RhCl 2 ] catalyzed three-component coupling cyclization of 2,3-allenols and 2,3-allenoic acids affording furanone derivatives with an acetate functionality was established. Isotopic labelling experiments unveiled a unique mechanism.

Language: Английский

Pd-Catalyzed Regioselective Cyclopropanation of 2-Substituted 1,3-Dienes DOI Creative Commons
Agonist Kastrati,

Vincent Jaquier,

Michele Garbo

et al.

ACS Organic & Inorganic Au, Journal Year: 2023, Volume and Issue: 3(5), P. 291 - 298

Published: July 25, 2023

A Pd-catalyzed 3,4-regioselective cyclopropanation of 2-substituted 1,3-dienes by decomposition diazo esters is reported. The vinylcyclopropanes generated are isolated in practical chemical yields with high levels regioselectivity but low diastereoselectivity. system operates under mild reaction conditions, scalable, and tolerates various sensitive functional groups. series original postcatalytic derivatizations presented to highlight the synthetic potential catalytic method.

Language: Английский

Citations

1
Addition of Organosilicon Reagents to Unsaturated Bonds DOI
Yasunori Minami

Elsevier eBooks, Journal Year: 2024, Volume and Issue: unknown

Published: Jan. 1, 2024

Language: Английский

Citations

0
Carboboration and Carbosilylation DOI
Yang Gao,

Madison F. Wagner,

Skyler D. Mendoza

et al.

Elsevier eBooks, Journal Year: 2024, Volume and Issue: unknown

Published: Jan. 1, 2024

Language: Английский

Citations

0
Facile electrochemical synthesis of silyl acetals: An air-stable precursor to formylsilane DOI
Masahiro Noji,

Sho Ishimaru,

Haruki Obata

et al.

Tetrahedron Letters, Journal Year: 2022, Volume and Issue: 104, P. 154026 - 154026

Published: July 19, 2022

Language: Английский

Citations

2
[Cp*RhCl2]2catalyzed three-component coupling cyclization of 2,3-allenoic acids with 2,3-allenols in the presence of Cu(OAc)2·H2O DOI
Junjie Fan, Xiaoyan Wu,

Chunling Fu

et al.

Organic Chemistry Frontiers, Journal Year: 2023, Volume and Issue: 10(15), P. 3776 - 3780

Published: Jan. 1, 2023

A [Cp*RhCl 2 ] catalyzed three-component coupling cyclization of 2,3-allenols and 2,3-allenoic acids affording furanone derivatives with an acetate functionality was established. Isotopic labelling experiments unveiled a unique mechanism.

Language: Английский

Citations

0